N-苯基-4-(9-苯基-9H-咔唑-3-基)苯胺 | 1072194-21-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 中文名称: N-苯基-4-(9-苯基-9H-咔唑-3-基)苯胺
• 英文名称: 4-(9-phenyl-9H-carbazol-3-yl)diphenylamine
• 英文别名: N-phenyl-N-[4-(9-phenylcarbazole-3-yl)phenyl]amine；3-[4-(N-phenylamino)phenyl]-9-phenylcarbazole；N-phenyl-4-(9-phenyl-9H-carbazol-3-yl)aniline；PCBA；N-phenyl-4-(9-phenylcarbazol-3-yl)aniline
• CAS: 1072194-21-8
• 化学式: C₃₀H₂₂N₂
• 分子量: 410.518
• InChiKey: ATKDFNSBYLLHRS-UHFFFAOYSA-N

物化性质

• 沸点：
  632.8±47.0 °C(Predicted)
• 密度：
  1.14±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  32
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-苯基-4-(9-苯基-9H-咔唑-3-基)苯胺 、 1,4-二碘苯 在 tris-(dibenzylideneacetone)dipalladium(0) 、 三叔丁基膦 、 potassium tert-butylate 作用下， 以 甲苯 为溶剂， 反应 6.0h， 以73%的产率得到N,N'-diphenyl-N,N'-bis(4-(9-phenylcarbazolyl)phenyl)-1,4-diaminobenzene
  参考文献：
  名称：

  KR101565039

  摘要：

  公开号：
• 作为产物：
  描述：

  N-苯基-3-咔唑硼酸 在 tris-(dibenzylideneacetone)dipalladium(0) 、 四(三苯基膦)钯 、 三叔丁基膦 、 potassium carbonate 、 sodium t-butanolate 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 29.0h， 生成 N-苯基-4-(9-苯基-9H-咔唑-3-基)苯胺
  参考文献：
  名称：

  유기전계발광소자의 캡핑층 형성용 유기화합물 및 그를 포함하는 유기전계발광소자

  摘要：

  本发明提供了一种用于形成有机发光器件的封装层的有机化合物，所述有机化合物选择自由化学式1所述的群体。此外，提供了具有由所述有机化合物形成的封装层（CPL）的有机发光器件：

  公开号：

  KR20150102733A

文献信息

• [EN] CARBAZOLE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING CARBAZOLE DERIVATIVE<br/>[FR] DÉRIVÉ CARBAZOLE, ET ÉLÉMENT ÉMETTANT DE LA LUMIÈRE, DISPOSITIF ÉMETTANT DE LA LUMIÈRE, ET DISPOSITIF ÉLECTRONIQUE UTILISANT LE DÉRIVÉ CARBAZOLE
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2009072587A1

  公开（公告）日：2009-06-11

  To provide a light-emitting element having high luminous efficiency and to provide a light-emitting device and an electronic device which consumes low power and is driven at low voltage, a carbazole derivative represented by the general formula (1) is provided. In the formula, α1, α2, α3, and α4 each represent an arylene group having less than or equal to 13 carbon atoms; Ar1 and Ar2 each represent an aryl group having less than or equal to 13 carbon atoms; R1 represents any of a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group; and R2 represents any of an alkyl group having 1 to 6 carbon atoms, a substituted or unsubstituted phenyl group, and a substituted or unsubstituted biphenyl group. In addition, l, m, and n are each independenly 0 or 1.

  为提供具有高发光效率的发光元件，并提供一种低功耗、低电压驱动的发光装置和电子设备，提供了由通式（1）表示的咔唑衍生物。在该式中，α1、α2、α3 和 α4 分别表示具有小于或等于 13 个碳原子的芳基基团；Ar1 和 Ar2 分别表示具有小于或等于 13 个碳原子的芳基基团；R1 表示氢原子、具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种；R2 表示具有 1 到 6 个碳原子的烷基基团、取代或未取代的苯基团，以及取代或未取代的联苯基团中的任意一种。此外，l、m 和 n 分别独立地为 0 或 1。
• ANTHRACENE DERIVATIVE AND LIGHT-EMITTING DEVICES, ELECTRONIC DEVICES, AND LIGHTING DEVICE USING THE ANTHRACENE DERIVATIVE
  申请人：Ogita Kaori

  公开号：US20100099890A1

  公开（公告）日：2010-04-22

  An anthracene derivative is disclosed, and a light-emitting element, a light-emitting device, an electronic device, and a lighting device using the anthracene derivatives are demonstrated. The structure of the anthracene derivative is described in detail in the specification. The use of the anthracene derivative enables the production of a blue emissive light-emitting element having high emission efficiency, excellent purity of emission color, and a long lifetime, which contributes to the production of a high-performance light-emitting device, electronic device, and lighting device.

  揭示了一种蒽衍生物，并展示了使用该蒽衍生物的发光元件、发光装置、电子设备和照明装置。蒽衍生物的结构在说明书中被详细描述。使用蒽衍生物可以生产具有高发射效率、发射颜色纯度优异和长寿命的蓝色发光元件，有助于生产高性能的发光装置、电子设备和照明装置。
• Carbazole Derivative and Method for Producing the Same
  申请人：Suzuki Hiroki

  公开号：US20100076201A1

  公开（公告）日：2010-03-25

  To provide a method for producing a wide variety of carbazole derivatives which have a simple and uncomplicated process and in which variations in the yield, purity, etc. of a desired substance which are caused by an aryl group introduced is reduced as much as possible. A method for producing a carbazole derivative represented by General Formula (1) is provided, in which 9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole having an active site at the 3-position of the carbazole skeleton and an aromatic compound having an active site are coupled. In the formula, Ar 1 represents an aryl group with 6 to 13 carbon atoms in a ring, and Ar 1 may have a substituent.

  提供一种生产多种各异的咔唑衍生物的方法，该方法具有简单和不复杂的过程，并尽量减少由引入的芳基团引起的所需物质的产量、纯度等变化。提供了一种生产由通用公式（1）表示的咔唑衍生物的方法，其中9-[4-(10-苯基-9-蒽基)苯基]-9H-咔唑在咔唑骨架的3位具有活性位点，并且与具有活性位点的芳香化合物偶联。在公式中，Ar1代表一个具有6到13个碳原子的环的芳基团，Ar1可能有取代基。
• [EN] CARBAZOLE DERIVATIVE, LIGHT-EMITTING ELEMENT MATERIAL, LIGHT-EMITTING ELEMENT, AND LIGHT-EMITTING DEVICE<br/>[FR] DÉRIVÉ DE CARBAZOLE, SUBSTANCE D'ÉLÉMENT ÉLECTROLUMINESCENT, ÉLÉMENT ÉLECTROLUMINESCENT, ET DISPOSITIF ÉLECTROLUMINESCENT
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2010005066A1

  公开（公告）日：2010-01-14

  ABSTRACT An object is to provide a carbazole derivative which has a wide band gap and with which excellent blue color purity is obtained. In addition, another object is to provide highly reliable light-emitting elements, light-emitting devices, lighting devices, and electronic devices in which the carbazole derivative is used. Carbazole derivatives represented by the general formulas (1), (P1), and (M1) are provided. Further, light-emitting elements, light-emitting devices, and electronic devices which are formed using the carbazole derivative represented any of the general formulas (1), (P1), and (M1) are provided.

  摘要：本文旨在提供一种具有宽带隙并具有优异蓝色纯度的咔唑衍生物。此外，另一个目标是提供使用该咔唑衍生物的高可靠性发光元件、发光装置、照明装置和电子装置。提供了由通用公式（1）、（P1）和（M1）表示的咔唑衍生物。此外，提供了使用由通用公式（1）、（P1）和（M1）表示的咔唑衍生物形成的发光元件、发光装置和电子装置。
• Carbazole Derivative with Heteroaromatic Ring, and Light-Emitting Element, Light-Emitting Device, and Electronic Device Using Carbazole Derivative with Heteroaromatic Ring
  申请人：Nomura Hiroko

  公开号：US20100237773A1

  公开（公告）日：2010-09-23

  Disclosed is a carbazole derivative and a light-emitting element, a light-emitting device, and an electronic device using thereof. The carbazole derivative possesses an oxadiazole moiety or a quinoxaline moiety as a heteroaromatic ring having an electron-transporting property and a carbazole moiety having a hole-transporting property. The ability of the carbazole derivative to transport both electrons and holes and its large excitation energy larger than a triplet excitation energy of a phosphorescent compound allow the formation of a phosphorescent light-emitting element having well-controlled carrier balance, which contributes to the formation of light-emitting devices and electronic devices that are capable of being driven at a low voltage, have a long lifetime, and consume low power. The detailed structure of the carbazole derivative is defined in the specification.

  本公开揭示了一种咔唑衍生物以及使用该衍生物的发光元件、发光装置和电子设备。该咔唑衍生物具有氧代二唑基团或喹啉基团作为具有电子传输性质的杂芳环，以及具有孔传输性质的咔唑基团。该咔唑衍生物传输电子和空穴的能力，以及其较磷光化合物的三重激发能量更大的激发能量，使得形成了一个具有良好控制载流子平衡的磷光发光元件，有助于形成能够在低电压下驱动、具有长寿命并且耗电低的发光装置和电子设备。该咔唑衍生物的详细结构在说明书中定义。