1,1-difluoroethylene-2-d1 | 563-60-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,1-difluoroethylene-2-d1
• 英文别名: 2-deuterio-1,1-difluoro-ethene；2-Deuterio-1,1-difluor-aethylen；2-Deuterio-1,1-difluor-aethen；2,2-difluoro-ethene-d；1,1-Difluor-2-deuterio-aethylen；1,1-Difluor-deuterio-aethylen
• CAS: 563-60-0
• 化学式: C₂H₂F₂
• 分子量: 65.0267
• InChiKey: BQCIDUSAKPWEOX-MICDWDOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  4.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  1,1-difluoroethylene-2-d1 、 3,3-二氟-3H-双吖丙啶 生成 1,1,2,2-tetrafluorocyclopropane-3-d1
  参考文献：
  名称：

  Microwave spectra, electric dipole moment, and molecular structure of 1,1,2,2-tetrafluorocyclopropane

  摘要：

  DOI：

  10.1021/ja00240a016
• 作为产物：
  描述：

  [1-D]-trifluoroethanol 生成 1,1-difluoroethylene-2-d1
  参考文献：
  名称：

  Vibrational Spectra of CF₂ = CHD and CF₂ = CD₂

  摘要：

  A method has been devised to prepare CF2 = CD2 and CF2 = CHD. The infrared spectra of the gaseous compounds and the Raman spectra of the liquids have been determined. The observed frequencies have been assigned to the fundamental modes of vibration and to overtones and combinations. The torsional frequency has been estimated as ca 720 and ca 520 cm—1 in CF2 = CH2 and CF2 = CD2, respectively. The overtone of the torsional frequency interacts with the CH2 or the CD2 deformation fundamental and this is the cause of the anomalous results with the product rule.

  DOI：

  10.1063/1.1739979

文献信息

• Vibrational Spectra of CF₂ = CHD and CF₂ = CD₂
  作者：Walter F. Edgell、Casper J. Ultee

  DOI：10.1063/1.1739979

  日期：1954.12

  A method has been devised to prepare CF2 = CD2 and CF2 = CHD. The infrared spectra of the gaseous compounds and the Raman spectra of the liquids have been determined. The observed frequencies have been assigned to the fundamental modes of vibration and to overtones and combinations. The torsional frequency has been estimated as ca 720 and ca 520 cm—1 in CF2 = CH2 and CF2 = CD2, respectively. The overtone of the torsional frequency interacts with the CH2 or the CD2 deformation fundamental and this is the cause of the anomalous results with the product rule.
• Microwave spectra, electric dipole moment, and molecular structure of 1,1,2,2-tetrafluorocyclopropane
  作者：R. N. Beauchamp、Charles W. Gillies、N. C. Craig

  DOI：10.1021/ja00240a016

  日期：1987.3