triphenylantimony di-iodide | 10167-90-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: triphenylantimony di-iodide
• 英文别名: triphenylantimony diiodide；triphenyl antimony (2+); diiodide；Triphenyl-antimon(2+); Dijodid；Diiodotriphenylantimony；diiodo(triphenyl)-λ5-stibane
• CAS: 10167-90-5；1538-60-9
• 化学式: C₁₈H₁₅I₂Sb
• 分子量: 606.876
• InChiKey: FHEXTGGNVNZKLY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  3.97
• 重原子数：
  21
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氯化锑(V) 、 triphenylantimony di-iodide 以 not given 为溶剂， 生成 triphenylantimony dichloride * antimony(III) chloride
  参考文献：
  名称：

  Hall, Michael; Sowerby, D. Bryan, Journal of the Chemical Society, Dalton Transactions, 1983, p. 1095 - 1100

  摘要：

  DOI：
• 作为产物：
  描述：

  三苯基锑 在 I₂ 作用下， 以 乙醚 为溶剂， 以>99的产率得到triphenylantimony di-iodide
  参考文献：
  名称：

  三芳基锑二卤化物的固态结构；Ph 3 SbI 2和[Ph 4 Sb] I 3的一些混合卤化物种类和晶体结构的分离

  摘要：

  合成了十五种化学计量为R 3 SbX 2的化合物（R = Ph或取代的芳基； X 2 = Br 2，I 2或IBr），并通过拉曼光谱法进行了研究。已经确定了Ph 3 SbI 2的晶体结构，表明它是扭曲的三角双锥体分子。可以通过朝向矩形金字塔的伪旋转过程来解释来自规则的三角双锥几何形状的变形。此外，在晶胞内有两个独立的分子，其扭曲的结构与已知的Ph 3 SbX 2直接相反。（X = Cl或Br）都采用规则的三角双锥几何形状。卤素间化合物R 3 SbIBr也具有三角-双锥体的几何形状。与在溶液中电离形成[Ph 3 EI] I的分子Ph 3 EI 2（E = P或As）形成鲜明对比的是，Ph 3 SbI 2在乙腈溶液中发生化学变化并形成离子型[Ph 4 Sb] I 3，没有[Ph 3 SbI] I的证据。还已经确定了[Ph 4 Sb] I 3的晶体结构。

  DOI：

  10.1039/dt9940001759
• 作为试剂：
  描述：

  9-十八烯 在 triphenylantimony di-iodide 、 2,3,4,5,6-五氯苯甲酸 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 生成 N-phenyl-8-octadecenyl-10-urethane
  参考文献：
  名称：

  由9,10-环氧十八烷和苯基异氰酸酯形成恶唑烷酮的研究

  摘要：

  AbstractThe formation of oxazolidone from 9,10‐epoxyoctadecane and phenylisocyanate was studied. One branch of epoxidized vegetable oil with one epoxy group per chain corresponds to 9,10‐epoxyoctadecane. This model could explain the probability of oxazolidone formation from natural oil‐derived epoxides. Epoxidized natural oils are TG consisting of glycerin and three FA with or without one to three epoxy groups in the middle of the chain. To study oxazolidone formation from an internal epoxy group without possible interference from the side reactions on the ester group, 9,10‐epoxyoctadecane was selected as the most appropriate model compound. Epoxy groups in the middle of allong aliphatic chain are of low reactivity toward isocyanates, and preparation of oxazolidones requires fairly harsh conditions such as high temperatures and catalysts, which also promote side reactions. The dominant side reaction is rearrangement of the epoxy groups. We found that the direction and magnitude of the rearrangement and the yield of any particular product depended on the catalyst used. Lithium chloride, aluminum trichloride, and zinc iodide catalyzed oxazolidone formation, along with the catalysis of side reactions such as ketone and carbonate formation. Aluminum trichloride showed the highest conversion of 9,10‐epoxyoctadecane to oxazolidone. Aluminum triisopropoxide, triphenylantimony iodide, and imidazole did not catalyze the formation of oxazolidone. They were effective as catalysts of epoxy group rearrangement and promoted the formation of hydroxyl, ketone, and carbonate compounds. Hydroxyl groups reacted with isocyanate to produce urethane.

  DOI：

  10.1007/s11746-003-0744-7

文献信息

• Organoantimony(V) Cyanoximates:  Synthesis, Spectra and Crystal Structures
  作者：Konstantin V. Domasevitch、Nikolay N. Gerasimchuk、Andrew Mokhir

  DOI：10.1021/ic9906048

  日期：2000.3.1

  anions are bound to the antimony(V) atoms in a monodentate fashion via the oxygen atoms of the oxime groups. The ligands adopt trans-anti configuration in these compounds. The coordination polyhedron in both complexes is a distorted trigonal bipyramid with the axial location of the cyanoxime ligand. A similar binding mode of other anions in synthesized organoantimony(V) complexes has been offered on

  合成了一系列25种新的有机锑（V）氰基肟酸酯，并使用红外，可见光和NMR光谱以及X射线分析进行了研究。确定了化合物（C6H5）4Sb [ONC（CN）C（O）NH2]（1）和（C6H5）4Sb [ONC（CN）C（O）N（CH3）2]（2）的晶体结构。两种配合物均在单斜空间群P2（1）/ c（Z = 4）中结晶，其晶胞参数（A，grad）为a = 14.921（3），b = 10.165（2），c = 17.571（7），对于化合物1，β= 113.26（6），对于化合物2，a = 16.415（4），b = 10.406（3），c = 17.152（3），β= 17.152（3），β= 117.79（2）。通过5438和5056独立反射，细化分别为1和2的结构产生R系数0.022和0.037。氰肟酸阴离子通过肟基团的氧原子以单齿方式与锑（V）原子结合。这些化合物中的配体采用反式构型。两种
• Extreme symbiosis: the facile one-step synthesis of the paramagnetic cobalt(III) complex of triphenylantimony, Col3(SbPh3)2, from the reaction of triphenylantimonydiiodine with unactivated coarse grain cobalt metal powder
  作者：Stephen M. Godfrey、Charles A. McAuliffe、Robin G. Pritchard

  DOI：10.1039/c39940000045

  日期：——

  Triphenylantimony diiodine (2 equiv.) reacts with unactivated cobalt powder to yield the unexpected cobalt(III) complex Col3(SbPh3)2; this five coordinate species represents a rare example of a paramagnetic cobalt(III) complex.

  三苯基锑二碘（2当量）与未活化的钴粉反应，生成意想不到的钴（III）络合物Col3（SbPh3）2；这种五配位物种是顺磁性钴（III）络合物的罕见例子。
• A new type of organostibonic molybdate. Synthesis and structure of a tetra-n-butylammonium salt of diphenylstibonomolybdate
  作者：Ben-yao Liu、Yih-tong Ku、Ming Wang、Bo-yi Wang、Pei-ju Zheng

  DOI：10.1039/c39890000651

  日期：——

  Reaction between Ph3SbI2 and (Bun4N)2MoO4 has led to the formation of (Bun4N)2[Ph2SbO (MoO4)]2 which is the first example of a crystalline organostibonic molybdate; it consists of two MoO4 tetrahedra bound to two octahedrally co-ordinated antimony atoms.

  Ph 3 SbI 2和（Bu n 4 N）2 MoO 4之间的反应导致形成（Bu n 4 N）2 [Ph 2 SbO（MoO 4）] 2，这是结晶有机stibonic钼酸盐的第一个例子；它由与两个八面体配位的锑原子结合的两个MoO 4四面体组成。
• Reactions of dihalogenotriorgano-phosphorus, -arsenic and -antimony compounds with [Fe₂(CO)₉]. Single-crystal structures of the iron(<scp>III</scp>) complexes [(Ph₃PO)₂H][FeBr₄] and [Ph₄Sb][Fel₄]·Ph₃Sbl₂and of [Fe(CO)₃(Ph₃P)₂]
  作者：Helen P. Lane、Stephen M. Godfrey、Charles A. McAuliffe、Robin G. Pritchard

  DOI：10.1039/dt9940003249

  日期：——

  The reaction of [Fe2(CO)9] with compounds of stoichiometry R3EX2 [R3E = Ph3P, (p-MeOC6H4)3P, Me2PhP, Me3As or Ph3Sb, X = I; R3E = Ph3P, Ph3As or Me3As, X = Br] has been investigated and shown to yield diverse products. A series of complexes with the ionic structure [R3EX][Fe(R3E)X3] [E = P, R3 = Ph3, Me2Ph or (p-MeOC6H4)3, X = I; R3E = Me3As; X = I or Br] has been obtained. The reaction of [Fe2(CO)9] with Ph3PBr2 and Ph3AsBr2, however, resulted in the formation of the iron(III) complexes [(Ph3E)2Br][FeBr4]. Hydrolysis of [(Ph3P)2Br][FeBr4] by trace quantities of water produces [(Ph3PO)2H][FeBr4], the crystal structure of which has been determined. Triphenylantimony diiodide reacted with [Fe2(CO)9] yielding the surprising ionic adduct [Ph4Sb][FeI4].Ph3SbI2, remarkable not only for the phenyl migration at the antimony atom, but also for the formation of the rare [FeI4]- anion from a zerovalent iron carbonyl complex. The reaction of [Fe2(CO)9] with the milder diphosphine tetraiodide, I2Ph2PCH2CH2PPh2I2, produced [Fe(CO)3(Ph2PCH2CH2PPh2)I][I3], a complex in which three CO ligands are retained.
• Raizada, Meenu Singh; Nigam, H. L., Journal of the Indian Chemical Society, 1986, vol. 63, p. 722 - 724
  作者：Raizada, Meenu Singh、Nigam, H. L.

  DOI：——

  日期：——