titanium-phenyl | 1544666-34-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: titanium-phenyl
• CAS: 1544666-34-3
• 化学式: C₆H₅Ti
• 分子量: 124.986
• InChiKey: VVFMKHRTYGDEPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.86
• 重原子数：
  7.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  benzenediazonium tetrafluoroborate 、 四氯化钛 在 sodium tetrahydroborate 作用下， 以 四氢呋喃 为溶剂， 生成 titanium-phenyl
  参考文献：
  名称：

  Ti–phenyl nanoparticles encapsulated in mesoporous silica as active and selective catalyst for the oxidation of alkenes

  摘要：

  Ti-phenyl nanoparticles encapsulated in mesoporous silica (Ti-phenyl@SiO2) were synthesized and used as catalysts in the oxidation of styrene by aqueous H2O2. The Ti-phenyl@SiO2(2) with Si/Ti mol ratio of two exhibited the best catalytic performance for the oxidation of styrene with 92% conversion and 99% selectivity towards benzaldehyde. This superior catalytic activity shown Ti-phenyl@SiO2 catalyst was attributed to the presence of phenyl-group and SiO2 on Ti and the ease in accessibility to the active sites by the porous SiO2. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2013.12.012
• 作为试剂：
  描述：

  苯乙烯 在 titanium-phenyl 、 双氧水 作用下， 以 水 为溶剂， 生成 苯甲醛
  参考文献：
  名称：

  Ti–phenyl nanoparticles encapsulated in mesoporous silica as active and selective catalyst for the oxidation of alkenes

  摘要：

  Ti-phenyl nanoparticles encapsulated in mesoporous silica (Ti-phenyl@SiO2) were synthesized and used as catalysts in the oxidation of styrene by aqueous H2O2. The Ti-phenyl@SiO2(2) with Si/Ti mol ratio of two exhibited the best catalytic performance for the oxidation of styrene with 92% conversion and 99% selectivity towards benzaldehyde. This superior catalytic activity shown Ti-phenyl@SiO2 catalyst was attributed to the presence of phenyl-group and SiO2 on Ti and the ease in accessibility to the active sites by the porous SiO2. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.catcom.2013.12.012

文献信息

• Ti–phenyl nanoparticles encapsulated in mesoporous silica as active and selective catalyst for the oxidation of alkenes
  作者：Syamsi Aini、Jon Efendi、Hendrik Oktendy Lintang、Sheela Chandren、Hadi Nur

  DOI：10.1016/j.catcom.2013.12.012

  日期：2014.2

  Ti-phenyl nanoparticles encapsulated in mesoporous silica (Ti-phenyl@SiO2) were synthesized and used as catalysts in the oxidation of styrene by aqueous H2O2. The Ti-phenyl@SiO2(2) with Si/Ti mol ratio of two exhibited the best catalytic performance for the oxidation of styrene with 92% conversion and 99% selectivity towards benzaldehyde. This superior catalytic activity shown Ti-phenyl@SiO2 catalyst was attributed to the presence of phenyl-group and SiO2 on Ti and the ease in accessibility to the active sites by the porous SiO2. (C) 2013 Elsevier B.V. All rights reserved.