3,6-Tridecanedione | 110743-58-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,6-Tridecanedione
• 英文别名: tridecane-3,6-dione
• CAS: 110743-58-3
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: ZZZPQZKLTSGLBP-UHFFFAOYSA-N

物化性质

• 沸点：
  315.3±15.0 °C(Predicted)
• 密度：
  0.894±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  15
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-壬酮 在 三氟化硼乙醚 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 生成 3,6-Tridecanedione
  参考文献：
  名称：

  乙酸乙酸酐的新合成方面

  摘要：

  从脂肪族硝基烯烃和酮酸锂烯醇化物轻松便捷地合成乙酸硝基酸酐，并将这些酸酐有效转化为1,4-二酮，烷基吡咯，二酮一肟，二氢-1,2-恶嗪，吡咯烷，2-羟基吡咯烷和记录1-吡咯啉。

  DOI：

  10.1016/s0040-4020(01)89068-2

文献信息

• Borohydride-Mediated Radical Addition Reactions of Organic Iodides to Electron-Deficient Alkenes
  作者：Takuji Kawamoto、Shohei Uehara、Hidefumi Hirao、Takahide Fukuyama、Hiroshi Matsubara、Ilhyong Ryu

  DOI：10.1021/jo500464q

  日期：2014.5.2

  Cyanoborohydrides are efficient reagents in the reductive addition reactions of alkyl iodides and electron-deficient olefins. In contrast to using tin reagents, the reaction took place chemoselectively at the carbon–iodine bond but not at the carbon–bromine or carbon–chlorine bond. The reaction system was successfully applied to three-component reactions, including radical carbonylation. The rate constant

  氰基硼氢化物是烷基碘化物和缺电子烯烃的还原加成反应中的有效试剂。与使用锡试剂相反，该反应在碳碘键上发生化学选择，而在碳溴或碳氯键上没有发生。该反应体系已成功应用于三组分反应，包括自由基羰基化。通过动力学竞争法，在25°C下从氰基硼氢化四丁基铵中伯烷基脱氢的速率常数估计为<1×10 4 M –1 s –1。该值比氢化三丁基锡的值小3个数量级。
• FUSED HETEROCYCLIC COMPOUNDS USEFUL AS MODULATORS OF NUCLEAR HORMONE RECEPTOR FUNCTION
  申请人：Norris Derek J.

  公开号：US20100331324A1

  公开（公告）日：2010-12-30

  Disclosed are fused heterocyclic compounds of Formula (I) or pharmaceutically-acceptable salts or stereoisomers thereof. Also disclosed are methods of using such compounds in the treatment of at least one androgen receptor-associated condition, such as, for example, cancer, and pharmaceutical compositions comprising such compounds.

  本发明公开了式（I）的融合杂环化合物或其药学上可接受的盐或立体异构体。本发明还公开了使用这种化合物治疗至少一种雄激素受体相关疾病的方法，例如癌症，并且还公开了包含这种化合物的制药组合物。
• METHOD FOR PRODUCING PURIFIED POLYTETRAFLUOROETHYLENE AQUEOUS DISPERSION LIQUID, METHOD FOR PRODUCING MODIFIED POLYTETRAFLUOROETHYLENE POWDER, METHOD FOR PRODUCING POLYTETRAFLUOROETHYLENE MOLDED BODY, AND COMPOSITION
  申请人：Daikin Industries, Ltd.

  公开号：EP3666802A1

  公开（公告）日：2020-06-17

  An object of the present invention is to obtain an aqueous dispersion of polytetrafluoroethylene in which compounds containing fluorine are removed or reduced. The present invention is a method for producing an aqueous dispersion of purified polytetrafluoroethylene, the method including: removing or reducing a compound represented by Formula (1) or (2) below from an aqueous dispersion of polytetrafluoroethylene obtained using a hydrocarbon surfactant:         Formula (1):     (H-(CF2)m-COO)pM1; or         Formula (2):     (H-(CF2)n-SO3)qM2.

  本发明的目的是获得一种聚四氟乙烯水分散液，其中含氟化合物被去除或还原。本发明是一种生产纯化聚四氟乙烯水分散液的方法，该方法包括：从使用烃类表面活性剂获得的聚四氟乙烯水分散液中除去或还原下式（1）或（2）所代表的化合物： 式 (1)：(H-(CF2)m-COO)pM1；或 式 (2)：(H-(CF2)n-SO3)qM2。
• Facile synthesis of 1,4-diketones via palladium complex catalyzed isomerization of alkynediols
  作者：Xiyan Lu、Jianguo Ji、Dawei Ma、Wei Shen

  DOI：10.1021/jo00020a015

  日期：1991.9

  Alkynediols isomerized under the catalysis of Pd2(dba)3.CHCl3 + 2n-Bu3P in acetonitrile at 80-degrees-C to give 1,4-diketones in high yields. This experimentally simple and economically synthetic method is illustrated with examples including substituents such as alkyl, alkenyl, and aryl groups. The order of reactivity of the substituents in this reaction is aryl greater-than-or-equal-to alkenyl > alkyl. Alkenyl-substituted alkynediols chemoselectively isomerized to the corresponding alpha,beta-unsaturated 1,4-diketones. The usefulness of this novel method is exemplified by the synthesis of dihydrojasmone.
• Tamaru, Yoshinao; Ochiai, Hirofumi; Nakamura, Tatsuya, Angewandte Chemie, 1987, vol. 99, # 11, p. 1193 - 1195
  作者：Tamaru, Yoshinao、Ochiai, Hirofumi、Nakamura, Tatsuya、Yoshida, Zen-ichi

  DOI：——

  日期：——