1,5-bis(8-quinolylsulfanyl)-3-oxapentane | 162708-47-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 1,5-bis(8-quinolylsulfanyl)-3-oxapentane
• 英文别名: 8-[2-(2-Quinolin-8-ylsulfanylethoxy)ethylsulfanyl]quinoline
• CAS: 162708-47-6
• 化学式: C₂₂H₂₀N₂OS₂
• 分子量: 392.546
• InChiKey: IDANCOABTKFMNI-UHFFFAOYSA-N

物化性质

• 沸点：
  602.6±50.0 °C(Predicted)
• 密度：
  1.29±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  27
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  85.6
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,5-bis(8-quinolylsulfanyl)-3-oxapentane 、 copper(II) perchlorate 以 乙醇 为溶剂， 以40-60的产率得到
  参考文献：
  名称：

  Yatsimirskii, K. B.; Pavlishchuk, V. V.; Strizhak, P. E., Journal of general chemistry of the USSR, 1989, vol. 59, p. 1303 - 1307

  摘要：

  DOI：
• 作为产物：
  描述：

  8-巯基喹啉钾盐 、 二氯乙醚 以 乙醇 为溶剂， 反应 3.0h， 生成 1,5-bis(8-quinolylsulfanyl)-3-oxapentane
  参考文献：
  名称：

  Yatsimirskii, K. B.; Pavlishchuk, V. V.; Strizhak, P. E., Journal of general chemistry of the USSR, 1989, vol. 59, p. 1303 - 1307

  摘要：

  DOI：

文献信息

• Solvent Extraction of Transition Metal Ions with Acyclic Polyethers Incorporating Several Heteroatoms and Bearing Heterocyclic Moieties as End Groups
  作者：Hidefumi Sakamoto、Shigeki Ito、Makoto Otomo

  DOI：10.1246/cl.1995.37

  日期：1995.1

  Nine acyclic polyethers incorporating oxygen, nitrogen and/or sulfur atoms were synthesized, which possess two heterocyclic groups at both ends of an ether chain, and metal ion extractabilities of these compounds were estimated using 1,2-dichloroethane - H2O system. On the solvent extraction of some transition metal ions as the nitrates, Ag+, Cu+ and Hg2+ were more effectively extracted with most of the reagents than the other metal ions. Addition of picrate ion into the aqueous phase of AgNO3 increased Ag+ extractability remarkably.

  利用 1,2 二氯乙烷 - H2O 系统估算了这些化合物的金属离子萃取率。在溶剂萃取某些过渡金属离子（如硝酸盐）时，与其他金属离子相比，大多数试剂都能更有效地萃取 Ag+、Cu+ 和 Hg2+。在 AgNO3 水相中加入苦味酸根离子可显著提高 Ag+ 的萃取率。
• The copper(i)/copper(ii) transition in complexes with 8-alkylthioquinoline based multidentate ligandsElectronic supplementary information (ESI) available. Schemes S1 and S2, Figs. S1–S7, selected bond lengths and angles and preparation of complexes. See http://www.rsc.org/suppdata/dt/b2/b208120m/
  作者：Cheng-Yong Su、Sen Liao、Matthias Wanner、Jan Fiedler、Cheng Zhang、Bei-Sheng Kang、Wolfgang Kaim

  DOI：10.1039/b208120m

  日期：2003.1.8

  three corners of the basal plane and the apical position, the fourth corner being completed by a DMF, H2O, DMSO or NO3− ligand, respectively. In the copper(I) complexes 3, 9 and 23 the metal centre is distorted tetrahedrally coordinated with two sulfur and two nitrogen donor atoms. The solution structures have been explored by UV–vis and EPR spectroscopy, the copper(II)/copper(I) transition and further

  三个线性多齿 配体结合了末端8-硫代喹啉环和柔性聚乙二醇或半刚性邻二甲苯基间隔基：五齿1,5-双（8-喹啉基硫烷基）-3-氧杂戊烷 （OESQ），六齿 1,8-双（8-喹啉基硫烷基）-3,6-二氧杂辛烷 （ODSQ）和四齿 1,2-双（喹啉-8-基硫烷基甲基）苯（OBSQ）。这些反应配体用各种铜盐可制得三族通式为[Cu（L 1）（L 2）]的铜（I）和铜（II）配合物X m：L 1 = OESQ和L 2 / X m =高氧2/（BF 4 - ）2 4，DMF /（BF 4 - ）2 5，高氧2/（CLO 4 -）2 6，NO 3 - / NO 3 - 7，NO 3 - / CLO 4 - 8，无/ BF 4 - 9 ; 大号1 = ODSQ和L 2 / X米 =无/（BF 4 - ）2 10，无/（CLO 4 - ）2 11，无/（NO 3 - ）2 12，无/铜（NO 3）4 2 - 13，无/
• Silver(I) complexes with quinoline based linear multidentate ligands: self-assembly of sulfur-bridged tetrametallotricyclic boxes †
  作者：Cheng-Yong Su、Sen Liao、Hai-Liang Zhu、Bei-Sheng Kang、Xiao-Ming Chen、Han-Qin Liu

  DOI：10.1039/b001723j

  日期：——

  The flexible linear multidentate ligands 1,5-bis(8-quinolylsulfanyl)-3-oxapentane (OESQ) and 1,8-bis(8-quinolylsulfanyl)-3,6-dioxaoctane (ODSQ) reacted with silver(I) perchlorate affording the simple mononuclear complexes [Ag(OESQ)]ClO41 and [Ag(ODSQ)]ClO42, respectively. However, with silver(I) nitrate, novel metallosupramolecular complexes [Ag4(ODSQ)2(η1-NO3)2(η2-NO3)2] 3 and [Ag4(OESQ)(ODSQ)(η1-NO3)2(η2-NO3)2]·H2O 4 were obtained, in which the co-ordination motifs [Ag(OESQ)]+ and [Ag(ODSQ)]+ are spontaneously self-assembled by sulfur-bridged silver(I) ions into tetrametallotricyclic molecules containing the same or mixed building blocks. All four complexes have been characterized by elemental analyses, IR and 1H NMR spectroscopy, and single crystal X-ray diffraction methods. The possible self-assembly process has been discussed with the aid of electrospray mass spectrometry.

  柔性线性多叉配体 1,5-双（8-喹啉硫酰）-3-氧杂戊烷（OESQ）和 1,8-双（8-喹啉硫酰）-3,6-二氧杂辛烷（ODSQ）与高氯酸银（I）反应，分别生成简单的单核络合物 [Ag(OESQ)]ClO41 和 [Ag(ODSQ)]ClO42。然而，在硝酸银（I）的作用下，得到了新型金属超分子配合物[Ag4(ODSQ)2(η1-NO3)2(η2- )2] 3 和[Ag4(OESQ)(ODSQ)(η1- )2(η2- )2]-H2O 4、其中[Ag(OESQ)]+ 和[Ag(ODSQ)]+ 配位基团是由硫桥银（I）离子自发地自组装到含有相同或混合构筑基块的四元三环分子中的。这四种复合物都通过元素分析、红外和 1H NMR 光谱以及单晶 X 射线衍射方法进行了表征。借助电喷雾质谱法讨论了可能的自组装过程。