8-[9,10-di(naphthalen-2-yl)-anthracen-2-yl]-5-phenyl-5H-pyrido[4,3-b]indole | 1303503-73-2

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 8-[9,10-di(naphthalen-2-yl)-anthracen-2-yl]-5-phenyl-5H-pyrido[4,3-b]indole
• 英文别名: 8-(9,10-Dinaphthalen-2-ylanthracen-2-yl)-5-phenylpyrido[4,3-b]indole；8-(9,10-dinaphthalen-2-ylanthracen-2-yl)-5-phenylpyrido[4,3-b]indole
• CAS: 1303503-73-2
• 化学式: C₅₁H₃₂N₂
• 分子量: 672.828
• InChiKey: IJVYZIORZFIROI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.8
• 重原子数：
  53
• 可旋转键数：
  4
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  17.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  8-[9,10-di(naphthalen-2-yl)-anthracen-2-yl]-5-phenyl-5H-pyrido[4,3-b]indole 、 苯基锂 在 氯化铵 作用下， 以 四氢呋喃 、 水 为溶剂， 反应 3.0h， 以22%的产率得到8-[9,10-di(naphthalen-2-yl)-anthracen-2-yl)-1,5-diphenyl-5H-pyrido[4,3-b]indole
  参考文献：
  名称：

  COMPOUND HAVING A SUBSTITUTED ANTHRACENE RING STRUCTURE AND PYRIDOINDOLE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE

  摘要：

  公开号：

  EP2500346B1
• 作为产物：
  描述：

  5H-吡啶并[4,3-b]吲哚 在 四(三苯基膦)钯 、 铜 N-溴代丁二酰亚胺(NBS) 、 potassium carbonate 作用下， 以 乙醇 、 水 、 二甲基亚砜 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 19.5h， 生成 8-[9,10-di(naphthalen-2-yl)-anthracen-2-yl]-5-phenyl-5H-pyrido[4,3-b]indole
  参考文献：
  名称：

  COMPOUND HAVING A SUBSTITUTED ANTHRACENE RING STRUCTURE AND PYRIDOINDOLE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT DEVICE

  摘要：

  公开号：

  EP2500346B1

文献信息

• Organic electroluminescent device
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：US11158811B2

  公开（公告）日：2021-10-26

  In the organic electroluminescent device having at least an anode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and a cathode in this order, the hole injection layer includes an arylamine compound of the following general formula (1) and an electron acceptor. In the formula, Ar1 to Ar4 may be the same or different, and represent a substituted or unsubstituted aromatic hydrocarbon group, a substituted or unsubstituted aromatic heterocyclic group, or a substituted or unsubstituted condensed polycyclic aromatic group.

  在具有至少一个阳极、一个空穴注入层、一个空穴传输层、一个发光层、一个电子传输层和一个阴极的有机电致发光器件中，空穴注入层包括以下通式（1）的芳胺化合物和一个电子受体。在该式中，Ar1至Ar4可以相同或不同，表示取代或未取代的芳香烃基、取代或未取代的芳香杂环基或取代或未取代的紧密多环芳香基。
• COMPOUND HAVING A SUBSTITUTED ANTHRACENE RING STRUCTURE AND PYRIDOINDOLE RING STRUCTURE, AND ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2500346A1

  公开（公告）日：2012-09-19

  The present invention relates to a compound having a substituted anthracene ring structure and a pyridoindole ring structure, which is represented by the following general formula (1) or the following general formula (2); and an organic electroluminescent device having a pair of electrodes and at least one organic layer interposed therebetween, in which the compound having a substituted anthracene ring structure and a pyridoindole ring structure, which is represented by the following general formula (1) or the following general formula (2), is used as a constituent material of the aforementioned at least one organic layer.

  本发明涉及一种具有取代的蒽环结构和吡啶吲哚环结构的化合物，该化合物由以下通式(1)或以下通式(2)表示；以及一种有机电致发光装置，该装置具有一对电极和至少一个夹在其间的有机层，其中具有取代的蒽环结构和吡啶吲哚环结构的化合物由以下通式(1)或以下通式(2)表示，用作上述至少一个有机层的组成材料。
• ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2704225A1

  公开（公告）日：2014-03-05

  An organic electroluminescent device comprises, between an anode and a cathode, a hole injection layer, a hole-transporting layer, a luminous layer and an electron-transporting layer, wherein the hole injection layer contains an arylamine compound (α) having three or more triphenylamine skeletons, the hole-transporting layer contains an arylamine compound (β) having two triphenylamine skeletons, and the electron-transporting layer contains an electron-transporting compound having an anthracene ring skeleton and a pyridoindole ring skeleton. The organic EL device emits light highly efficiently, drives on a low voltage, and features excellent durability and long life.

  一种有机电致发光器件包括阳极和阴极之间的空穴注入层、空穴传输层、发光层和电子传输层，其中空穴注入层包含具有三个或三个以上三苯胺骨架的芳胺化合物（α），空穴传输层包含具有两个三苯胺骨架的芳胺化合物（β），电子传输层包含具有蒽环骨架和吡啶吲哚环骨架的电子传输化合物。这种有机电致发光器件发光效率高，驱动电压低，具有出色的耐用性和长使用寿命。
• ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：Hodogaya Chemical Co., Ltd.

  公开号：EP2757860A1

  公开（公告）日：2014-07-23

  An organic electroluminescent device having a capping layer composed of material having a high refractive index, excelling in thin film stability and durability and having no absorption in the respective wavelength ranges of blue, green, and red is provided to improve device characteristics of the organic electroluminescent device, particularly to greatly improve light extraction efficiency. The organic electroluminescent device has at least an anode electrode, a hole transport layer, a light emitting layer, an electron transport layer, a cathode electrode, and the capping layer in this order, wherein the capping layer contains an arylamine compound (X) having a structure in which two triphenylamine structures are joined within a molecule via a single bond or a divalent group that does not contain a heteroatom.

  本发明提供了一种有机电致发光器件，其封盖层由具有高折射率的材料构成，薄膜稳定性和耐久性优异，并且在蓝、绿、红各自的波长范围内无吸收，从而改善了有机电致发光器件的器件特性，特别是极大地提高了光提取效率。 该有机电致发光器件至少依次具有阳极电极、空穴传输层、发光层、电子传输层、阴极电极和封盖层，其中封盖层包含芳基胺化合物（X），该化合物具有在一个分子内通过单键或不含杂原子的二价基团连接两个三苯胺结构的结构。
• Organic electroluminescence device
  申请人：HODOGAYA CHEMICAL CO., LTD.

  公开号：US10505119B2

  公开（公告）日：2019-12-10

  The organic EL device of the present invention has an anode, a hole transport layer, a luminous layer, an electron transport layer, and a cathode in the order of description. The hole transport layer includes an arylamine compound represented by the following general formula (1): in the formula, Ar1 to Ar4 each represent a monovalent aromatic hydrocarbon group or a monovalent aromatic heterocyclic group, and the luminous layer includes an N-aromatic substituted nitrogen-containing heterocyclic compound.

  本发明的有机电致发光器件依次具有阳极、空穴传输层、发光层、电子传输层和阴极。空穴传输层包括由以下通式（1）表示的芳基胺化合物： 式中 Ar1 至 Ar4 各代表一个一价芳香烃基团或一个一价芳香杂环基团，发光层包括一个 N-芳香取代的含氮杂环化合物。