(E)-N-hydroxy-N-phenylcinnamamide | 128917-47-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: (E)-N-hydroxy-N-phenylcinnamamide
• 英文别名: N-cinnamoylphenylhydroxylamine；(E)-N-hydroxy-N-phenyl-cinnamamide；N-Cinnamoyl-phenylhydroxylamin；N-Hydroxy-N,3-diphenylacrylamide；(E)-N-hydroxy-N,3-diphenylprop-2-enamide
• CAS: 128917-47-5
• 化学式: C₁₅H₁₃NO₂
• 分子量: 239.274
• InChiKey: TUJGSRKTSYNGAW-VAWYXSNFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-N-hydroxy-N-phenylcinnamamide 生成 bis[(N-[(E)-3-phenylprop-2-enoyl]anilino)oxy]lead
  参考文献：
  名称：

  SHEINA, N. M.;SHVEDENE, N. V.;KULAKOVA, L. B., ZH. ANAL. XIMII, 45,(1990) N, S. 113-118

  摘要：

  DOI：
• 作为产物：
  描述：

  (E)-N-methoxy-N-phenylcinnamamide 在 三氯化铝 、 二甲基硫 作用下， 反应 0.5h， 以79%的产率得到(E)-N-hydroxy-N-phenylcinnamamide
  参考文献：
  名称：

  Kawase, Masami; Kitamura, Takahiro; Shimada, Masahiro, Synthetic Communications, 1990, vol. 20, # 6, p. 887 - 892

  摘要：

  DOI：

文献信息

• Organic-inorganic hybrid material, composition for synthesizing the same, and manufacturing method of the same
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20040265253A1

  公开（公告）日：2004-12-30

  An organic-inorganic hybrid material chelating a metal atom of a metal oxide matrix 103 in a pendant shape is synthesized, where the organic compound (the functional chelating agent) 104 is able to develop a function of a coloring property, a light-emitting property, or semiconductivity by chelating a metal atom. As a synthesis method, sol (a composition for coating application) including a metal alkoxide and/or a metal salt and a functional chelating agent may be prepared and the organic-inorganic hybrid material may be synthesized by sol-gel method. Due to the above-mentioned structure, it is possible to synthesize an organic-inorganic hybrid material that has an organic group directly bonded to a metal oxide matrix and is able to develop a different function from that of a mere metal oxide. In other words, it is possible to realize a functional organic-inorganic hybrid material that develops a coloring property, a light-emitting property, or semiconductivity due to the organic group directly bonded to the metal oxide matrix.

  合成一种有机-无机混合材料，其中有机化合物（功能螯合剂）能够通过螯合金属原子来发展一种着色特性、发光特性或半导体性能。作为一种合成方法，可以准备包含金属烷氧化物和/或金属盐以及功能螯合剂的溶胶（用于涂层应用的组合物），并通过溶胶-凝胶方法合成有机-无机混合材料。由于上述结构，可以合成一种有机-无机混合材料，其中有机基直接与金属氧化物基质结合，并能够发展出与单纯金属氧化物不同的功能。换句话说，由于有机基直接与金属氧化物基质结合，可以实现一种具有着色特性、发光特性或半导体性能的功能性有机-无机混合材料。
• Di- and triorganotin(IV) derivatives of N,N-substituted hydroxylamines
  作者：Mrinal K. Das、Matilal Nath、J.J. Zuckerman

  DOI：10.1016/s0020-1693(00)83637-3

  日期：1983.1

  Twenty-four organotin(IV) N,N-disubstituted hydroxylamines of the formula R2SnL2 (R = n-C4H9 and C6H5; LH = N,N-disubstituted hydroxylamines) and (C6H5)3SnL (LH = as above) have been synthesized by the reaction of organotin(IV) chlorides and hydroxylamines in presence of triethylamine in benzene medium. UV, IR, NMR and Mossbauer spectroscopic techniques have been utilized for the characterization and elucidation

  摘要合成了二十四个分子式为R2SnL2的有机锡（IV）N，N-二取代羟胺（R = n-C4H9和C6H5; LH = N，N-二取代羟胺）和（ ）3SnL（LH =如上所述）在三乙胺存在下，在苯介质中，使有机锡（IV）氯化物与羟胺反应。UV，IR，NMR和Mossbauer光谱技术已用于表征和阐明化合物的结构和键合方面。结果表明，二正丁基锡（IV）双（羟基层压板）扭曲了反八面体结构，而二苯基锡（IV）双（羟基层压板）和三苯基锡（IV）羟基酰胺为顺八面体和三角联双锥体，赤道三苯基锡组。
• N-HETEROCYCLIC CARBENE CATALYZED SYNTHESIS OF N-PHENYLISOXAZOLIDIN-5-ONE DERIVATIVE AND SYNTHESIS OF β-AMINO ACID ESTER DERIVATIVE
  申请人：Zhang Yugen

  公开号：US20100099886A1

  公开（公告）日：2010-04-22

  A process for preparing a N-phenylisoxazolidin-5-one derivative is provided. The process for preparing the N-phenylisoxazolidin-5-one derivative comprises reacting an α,β-unsaturated aldehyde with nitrosobenzene in the presence of a N-heterocyclic carbene (NHC) catalyst. A process for preparing an N-alkoxyphenyl protected β-amino acid ester derivative is further provided. The process for preparing the N-alkoxyphenyl protected β-amino acid ester derivative comprises reacting an α,β-unsaturated aldehyde with nitrosobenzene in the presence of a N-heterocyclic carbene (NHC) catalyst to form a N-phenylisoxazolidin-5-one derivative, and then treating the N-phenylisoxazolidin-5-one derivative with an alcohol in the presence of an acid catalyst. A process for preparing an N-alkoxyphenyl protected β-amino acid ester derivative, comprising treating a N-phenylisoxazolidin-5-one derivative with an alcohol in the presence of an acid catalyst, is also provided.

  提供一种制备N-苯基异噁唑烷-5-酮衍生物的方法。制备N-苯基异噁唑烷-5-酮衍生物的方法包括在N-杂环卡宾（NHC）催化剂的存在下，将α，β-不饱和醛与亚硝基苯反应。进一步提供一种制备N-烷氧基苯基保护的β-氨基酸酯衍生物的方法。制备N-烷氧基苯基保护的β-氨基酸酯衍生物的方法包括在N-杂环卡宾（NHC）催化剂的存在下，将α，β-不饱和醛与亚硝基苯反应以形成N-苯基异噁唑烷-5-酮衍生物，然后在酸催化剂的存在下用醇处理N-苯基异噁唑烷-5-酮衍生物。还提供了一种制备N-烷氧基苯基保护的β-氨基酸酯衍生物的方法，包括在酸催化剂的存在下用醇处理N-苯基异噁唑烷-5-酮衍生物。
• N-HETEROCYCLIC CARBENE (NHC) CATALYZED SYNTHESIS OF HYDROXAMIC ACIDS
  申请人：Zhang Yugen

  公开号：US20100105921A1

  公开（公告）日：2010-04-29

  A process for preparing hydroxamic acids is provided. The process comprises reacting an aldehyde with a nitroso compound in the presence of a N-heterocyclic carbene (NHC) catalyst.

  提供了一种制备羟肟酸的过程。该过程包括在N-杂环卡宾（NHC）催化剂的存在下将醛与亚硝基化合物反应。
• N-heterocyclic carbene (NHC) catalyzed synthesis of hydroxamic acids
  申请人：Agency for Science, Technology and Research

  公开号：US08143423B2

  公开（公告）日：2012-03-27

  A process for preparing hydroxamic acids is provided. The process comprises reacting an aldehyde with a nitroso compound in the presence of a N-heterocyclic carbene (NHC) catalyst.

  提供了一种制备羟肟酸的方法。该方法包括在N-杂环卡宾（NHC）催化剂的存在下，将醛与亚硝基化合物反应。