6-(丙烯酰氧基)己酸 | 93365-33-4

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 中文名称: 6-(丙烯酰氧基)己酸
• 英文名称: 6-acryloyloxyhexanoic acid
• 英文别名: 6-(Acryloyloxy)hexanoic acid；6-prop-2-enoyloxyhexanoic acid
• CAS: 93365-33-4
• 化学式: C₉H₁₄O₄
• 分子量: 186.208
• InChiKey: JSZCJJRQCFZXCI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  6-(丙烯酰氧基)己酸 在 草酰氯 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 生成 6-acryloyloxyhexanoic acid chloride
  参考文献：
  名称：

  [EN] LIQUID CRYSTAL COMPOUND COMPRISING TWO CONDENSED AND SUBSTITUTED RINGS
  [FR] COMPOSÉ DE CRISTAUX LIQUIDES COMPRENANT DEUX CYCLES CONDENSÉS ET SUBSTITUÉS

  摘要：

  一种新的液晶化合物包括两个凝缩和取代的环。该环最好是一个五元杂环。该杂环最好与苯环或芳香六元杂环凝缩。苯环或芳香六元杂环最好取代为一个包含环结构和链结构的基团。该液晶化合物有利地用于制备薄相位延迟器，如宽范围的1/4波片，其提供反向波长分布。根据使用新的液晶化合物可以通过简单的工艺容易地生产相位延迟器。

  公开号：

  WO2005085222A1
• 作为产物：
  描述：

  6-己内酯 在 甲醇 、 2,6-二叔丁基-4-甲基苯酚 、 potassium hydroxide 作用下， 以 四氢呋喃 、 N,N-二甲基乙酰胺 为溶剂， 反应 5.5h， 生成 6-(丙烯酰氧基)己酸
  参考文献：
  名称：

  Liquid crystal compositions, polymer networks derived therefrom and process for making the same

  摘要：

  该发明涉及公式（I）的化合物。该发明还涉及包含公式（I）化合物的液晶组合物；进一步包含一种或多种手性化合物的组合物；以及由液晶组合物的聚合物化得到的聚合物网络。另一种实施方式涉及提供公式（I）化合物的方法。

  公开号：

  US08344175B2

文献信息

• ALKALOID MONOMERS, LIQUID CRYSTAL COMPOSITIONS AND POLYMER NETWORKS DERIVED THEREFROM
  申请人：Goldfinger Marc B.

  公开号：US20110193019A1

  公开（公告）日：2011-08-11

  Disclosed is the chemical synthesis of chiral alkaloid monomers, liquid crystal compositions comprising the chiral alkaloid monomers, and polymerization of the liquid crystal compositions to provide polymer networks with useful cholesteric optical properties and stability.

  公开了手性生物碱单体的化学合成、包含手性生物碱单体的液晶组合物，以及液晶组合物的聚合，以提供具有有用的胆甾光学性能和稳定性的聚合物网络。
• Liquid crystal compositions and polymer networks derived therefrom
  申请人：Goldfinger B. Marc

  公开号：US20070267599A1

  公开（公告）日：2007-11-22

  The invention relates to compounds of formula (I): wherein R 1 and R 2 are each independently selected from the group: H, F, Cl and CH 3 ; n1 and n2 are each independently integers 3 to 20; q and r are each independently integers 0, 1 or 2, with the proviso that q+r is ≧1; D is a divalent chiral radical selected from the group: wherein R 3 is a C1 to C6 straight or branched chain alkyl group; and each B 1 and B 2 is a divalent radical independently selected from the group: R 4 -substituted-1,4-phenyl, wherein R 4 is H, —CH 3 or —OCH 3 ; 2,6-naphthyl; and 4,4′-biphenyl; with the provisos that when q+r=3, at least one of B 1 and B 2 is R 4 -substituted-1,4-phenyl; and when q+r=4, at least two of B 1 and B 2 are R 4 -substituted-1,4-phenyl. The invention further relates to liquid crystal compositions comprising compounds of formula (I) and polymer networks derived from the polymerization of the liquid crystal compositions.

  本发明涉及化合物的公式(I)：其中，R1和R2各自独立地选自组：H、F、Cl和CH3；n1和n2各自独立地为整数3至20；q和r各自独立地为整数0、1或2，但须满足q+r≧1；D是从组中选择的二价手性基团：其中，R3是C1至C6直链或支链烷基；每个B1和B2是从组中独立选择的二价基团：R4-取代-1,4-苯基，其中R4为H、— 或—O ；2,6-萘基；和4,4'-联苯基；但须满足当q+r=3时，至少一个B1和B2是R4-取代-1,4-苯基；当q+r=4时，至少两个B1和B2是R4-取代-1,4-苯基。本发明还涉及包含公式(I)化合物的液晶组合物和由液晶组合物聚合得到的聚合物网络。
• CHIRAL COMPOUNDS, LIQUID CRYSTAL COMPOSITIONS AND POLYMER NETWORKS DERIVED THEREFROM
  申请人：Goldfinger Marc B.

  公开号：US20110042614A1

  公开（公告）日：2011-02-24

  Isomannide-based compounds having chiral properties are provided, in addition to liquid crystal compositions and polymer networks derived therefrom.

  提供了具有手性性质的异麦芽酰胺基化合物，以及由此衍生的液晶组合物和聚合物网络。
• HEAT-EXPANDABLE REMOVABLE ACRYLIC PRESSURE-SENSITIVE ADHESIVE TAPE OR SHEET
  申请人：Higuchi Naoaki

  公开号：US20120034447A1

  公开（公告）日：2012-02-09

  Provided is a heat-expandable removable acrylic pressure-sensitive adhesive tape that has high normal-state adhesive power when bonded independently of whether the adherend has or does not have irregular surface and permits easy separation when the bonded region is separated and disassembled by lowering the adhesive power by heating, that permits easily separation-decomposition, even after long-term storage at high temperature. The heat-expandable removable acrylic pressure-sensitive adhesive tape or sheet according to the present invention includes at least a heat expanding agent-containing pressure-sensitive adhesive layer, and the tape or sheet has an initial 90° peel adhesive strength to a polycarbonate plate as adherend of 10 N/25 mm or more and a 90° peel adhesive strength after storage in an atmosphere at 80° C. for 2 months as bonded to the polycarbonate adherend and after heat expansion treatment of less than 10 N/25 mm.

  提供的是一种热膨胀可拆卸丙烯酸压敏胶粘带，无论粘接的基材表面是否不规则，都具有高粘接力，并且在通过加热降低粘接力进行分离时，可以轻松分离粘接区域，即使在高温长期储存后也可以轻松分离分解。本发明的热膨胀可拆卸丙烯酸压敏胶粘带或薄片至少包括含有热膨胀剂的压敏胶层，该带或薄片在初次粘接到聚碳酸酯基材时的90°剥离粘接强度为10 N/25 mm或更高，并且在80℃环境下储存2个月后进行热膨胀处理后，与聚碳酸酯基材粘接的90°剥离粘接强度小于10 N/25 mm。
• CHIRAL COMPOUNDS AND LIQUID CRYSTAL COMPOSITIONS AND POLYMER NETWORKS DERIVED THEREFROM
  申请人：GOLDFINGER Marc B.

  公开号：US20110163267A1

  公开（公告）日：2011-07-07

  The invention relates to compounds of formula (I): wherein R 1 and R 2 are each independently selected from the group: H, F, Cl and CH 3 ; n1 and n2 are each independently integers 3 to 20; q and r are each independently integers 0, 1 or 2, with the proviso that q+r is ≧1; D is a divalent chiral radical selected from the group: wherein R 3 is a C1 to C6 straight or branched chain alkyl group; and each B 1 and B 2 is a divalent radical independently selected from the group: R 4 -substituted-1,4-phenyl, wherein R 4 is H, —CH 3 or —OCH 3 ; 2,6-naphthyl; and 4,4′-biphenyl; with the provisos that when q+r=3, at least one of B 1 and B 2 is R 4 -substituted-1,4-phenyl; and when q+r=4, at least two of B 1 and B 2 are R 4 -substituted-1,4-phenyl. The invention further relates to liquid crystal compositions comprising compounds of formula (I) and polymer networks derived from the polymerization of the liquid crystal compositions.

  本发明涉及式（I）的化合物：其中R1和R2各自独立地选自以下组：H，F，Cl和CH3; n1和n2各自独立地为3至20的整数; q和r各自独立地为0、1或2的整数，但需满足q+r≧1; D是选自以下组的二价手性基团：其中R3是C1至C6的直链或支链烷基; 每个B1和B2是独立地选自以下组的二价基团：R4-取代-1,4-苯基，其中R4是H，— 或—O ; 2,6-萘基; 和4,4'-联苯基; 但需满足当q+r=3时，至少有一个B1和B2是R4-取代-1,4-苯基; 当q+r=4时，至少有两个B1和B2是R4-取代-1,4-苯基。本发明还涉及包含式（I）的液晶组分和由液晶组分的聚合物网络衍生的聚合物网络。