9,10-dihydro-2-phenanthrenamine | 76302-58-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9,10-dihydro-2-phenanthrenamine
• 英文别名: 9,10-dihydro-[2]phenanthrylamine；2-Amino-9.10-dihydro-phenanthren；9,10-Dihydro-[2]phenanthrylamin；2-Amino-9,10-dihydrophenanthrene；9,10-dihydrophenanthren-2-amine
• CAS: 76302-58-4
• 化学式: C₁₄H₁₃N
• 分子量: 195.264
• InChiKey: BGBZGVMOWSGRTE-UHFFFAOYSA-N

物化性质

• 熔点：
  49-52 °C
• 沸点：
  387.8±21.0 °C(Predicted)
• 密度：
  1.159±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9,10-dihydro-2-phenanthrenamine 在 sulfur 作用下， 生成 2-菲基胺
  参考文献：
  名称：

  A Method for the Synthesis of Certain 2-Substituted Phenanthrenes

  摘要：

  DOI：

  10.1021/ja01261a053
• 作为产物：
  描述：

  N-(9,10-二氢菲-2-基)乙酰胺 在 盐酸 、 溶剂黄146 作用下， 生成 9,10-dihydro-2-phenanthrenamine
  参考文献：
  名称：

  Studies in the Phenanthrene Series. XV. Observations on Substitution in 9,10-Dihydrophenanthrene: Tetracyclic Compounds Derived from It¹

  摘要：

  DOI：

  10.1021/ja01286a042

文献信息

• The 9,10-dihydrophenanthrene structure as a source of liquid crystals: mesogenic behaviour and spectroscopic properties of 2-benzylideneamino-9,10-dihydrophenanthrenes
  作者：Basil A. Behnam、D. Muriel Hall

  DOI：10.1039/p29820000465

  日期：——

  13 Azomethines have been prepared from 2-amino-9,10-dihydrophenanthrene by reaction with aromatic aldehydes. Those with p-alkoxy, p-cyano or p-phenyl substituents in the aldehydic ring have a nematic mesophase. U.v. spectra, 1 H and 13C n.m.r. spectra, and mass spectra of the series are discussed. Mass spectra show that ortho-substituents in the aldehydic ring substantially modify the fragmentation

  由2-氨基-9,10-二氢菲与芳族醛反应制得了13种甲亚胺。那些具有p -烷氧基，p -氰基或p在醛环苯基取代基具有的向列型中间相。讨论了Uv光谱，1 H和13 C nmr光谱以及该系列的质谱。质谱表明，醛环中的邻位取代基实质上改变了片段化模式。
• ANTHRACENE DERIVATIVES, LUMINESCENT MATERIALS AND ORGANIC ELECTROLUMINESCENT DEVICES
  申请人：Kawamura Masahiro

  公开号：US20110068683A1

  公开（公告）日：2011-03-24

  Anthracene derivatives each having a structure including an anthracene skeleton, a phenanthrene skeleton selected from among various phenanthrene skeletons different in bonding site which is bonded to the 9-position of the anthracene skeleton and a group selected from among various aryl groups and so on which is bonded to the 10-position of the anthracene skeleton. Organic EL devices made by using the derivatives exhibit high light emission efficiency and a long life.

  这段话的意思是：含有蒽骨架的衍生物，每个衍生物的结构都包括蒽骨架、苯并蒽骨架（从各种不同的苯并蒽骨架中选择，其键合位置与蒽骨架的9位相连）和从各种芳基基团中选择的基团等（其键合位置与蒽骨架的10位相连）。使用这些衍生物制造的有机电致发光器件具有高的发光效率和长寿命。
• Anthracene derivatives, luminescent materials and organic electroluminescent devices
  申请人：Kawamura Masahiro

  公开号：US08822041B2

  公开（公告）日：2014-09-02

  Anthracene derivatives each having a structure including an anthracene skeleton, a phenanthrene skeleton selected from among various phenanthrene skeletons different in bonding site which is bonded to the 9-position of the anthracene skeleton and a group selected from among various aryl groups and so on which is bonded to the 10-position of the anthracene skeleton. Organic EL devices made by using the derivatives exhibit high light emission efficiency and a long life.

  这段话的意思是：各种蒽衍生物都包括一个蒽骨架，一个从各种不同的菲骨架中选择的与蒽骨架的9位键合的菲骨架，以及一个从各种芳基族等中选择的与蒽骨架的10位键合的基团。使用这些衍生物制成的有机EL器件具有高的发光效率和长寿命。
• Organic light-emitting device
  申请人：Samsung Display Co., Ltd.

  公开号：US11056651B2

  公开（公告）日：2021-07-06

  An organic light-emitting device having high efficiency and improved lifespan is provided. The organic light-emitting device of the present disclosure includes: a first electrode; a second electrode facing the first electrode; an emission layer between the first electrode and the second electrode, the emission layer including a first compound; and an electron transport region between the emission layer and the second electrode, the electron transport region including an electron transport layer including a second compound and an electron control layer including a third compound, wherein the electron control layer is between the emission layer and the electron transport layer. The first compound may be represented by Formula 1, the second compound may be represented by Formula 2, and the third compound may be selected from compounds represented by Formula 1 and/or Formula 2:

  本发明提供了一种具有高效率和更长使用寿命的有机发光器件。本公开的有机发光器件包括：第一电极；面向第一电极的第二电极；位于第一电极和第二电极之间的发射层，发射层包括第一化合物；以及位于发射层和第二电极之间的电子传输区域，电子传输区域包括包括第二化合物的电子传输层和包括第三化合物的电子控制层，其中电子控制层位于发射层和电子传输层之间。第一种化合物可以用式 1 表示，第二种化合物可以用式 2 表示，第三种化合物可以从式 1 和/或式 2 表示的化合物中选择：
• STUDIES IN THE PHENANTHRENE SERIES. XX. NITRATION OF 9,10-DIHYDROPHENANTHRENE^*
  作者：JOHN W. KRUEGER、ERICH MOSETTIG

  DOI：10.1021/jo01221a006

  日期：1938.9