3-pentadecylcyclohexanone | 1589-19-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-pentadecylcyclohexanone
• 英文别名: 3-pentdecylcyclohexanone；3-Pentadecyl-cyclohexanon；3-pentadecylcyclohexan-1-one
• CAS: 1589-19-1
• 化学式: C₂₁H₄₀O
• 分子量: 308.548
• InChiKey: WHOBFGJNSZKKOY-UHFFFAOYSA-N

物化性质

• 熔点：
  43 °C(Solv: ligroine (8032-32-4))
• 沸点：
  384.5±10.0 °C(Predicted)
• 密度：
  0.868±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  22
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.95
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  3-pentadecylcyclohexanone 在 盐酸羟胺 、 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 以94%的产率得到3-pentadecylcyclohexanone oxime
  参考文献：
  名称：

  Valorization of Madagascar’s CNSL via the synthesis of one advanced intermediate (3-Pentadecylcyclohexanone)

  摘要：

  A unique advanced intermediate: 3-Pentadecylcyclohexanone was synthetized from the crude product which contained a mixture of cardanol, cardol and 2-methylcardol, which was hydrogenated onto Pd/C at 80 degrees C. From this alkylated cyclohexanone: C15 alkylated adipic acid, caprolactam, caprolactone, were synthetized in high yields, such products may have many potentially applications in polymer chemistry. The condensation of the 3-pentadecyl-cyclohexanone and triethylene glycol in oxidative or reductive conditions gave aryl ether and cyclohexyl ether, this may be a way to prepare intermediate for surfactant chemistry. Therefore we show that Cashew Nut Shell Liquid (CNSL) may lead to numerous useful compounds thank to the preparation of a unique advanced intermediate. (C) 2017 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2017.04.093
• 作为产物：
  描述：

  3-十五烷基苯酚 生成 3-pentadecylcyclohexanone
  参考文献：
  名称：

  Sethi,S.C.; Rao,B.C.S., Indian Journal of Chemistry, 1964, vol. 2, p. 178 - 181

  摘要：

  DOI：

文献信息

• Synthesis of bio-based surfactants from cashew nutshell liquid in water
  作者：Valentina Bragoni、Raja K. Rit、Robin Kirchmann、A. Stefania Trita、Lukas J. Gooßen

  DOI：10.1039/c8gc01686k

  日期：——

  3-Pentadecylcyclohexylamines were synthesised via Pd/C-catalysed reductive amination of crude cashew nutshell liquid, an underused waste product, with hydrogen in water. The short, modular, and waste-minimised synthetic approach enables access to structurally diverse neutral, cationic, and zwitterionic tenside derivatives.

  3-Pentadecylcyclohexylamines是通过Pd / C催化的粗腰果壳液（一种未充分利用的废品）与水中的氢进行还原胺化而合成的。简短，模块化且浪费最少的合成方法使得能够获得结构多样的中性，阳离子和两性离子表面活性剂衍生物。
• 1,1-bis(4-aminophenyl)-3-alkylcyclohexanes and method of preparation thereof
  申请人：Council of Scientific and Industrial Research

  公开号：US06790993B1

  公开（公告）日：2004-09-14

  The present invention relates to new aromatic diamines. More particularly, the present invention relates to new aromatic diamines prepared from cashew nut shell liquid (CNSL), which is a renewable resource material. The present invention particularly relates to novel 1,1-bis(4-aminophenyl)-3-alkylcyclohexanes and to a method for their preparation.

  本发明涉及新的芳香族二胺。更具体地说，本发明涉及从腰果壳液（CNSL）制备的新的芳香族二胺，该液体是一种可再生资源材料。本发明特别涉及新型1,1-双（4-氨基苯基）-3-烷基环己烷和其制备方法。
• 1,1-Bis(4-hydroxyphenyl)-3-alkylcyclohexanes, method for their preparation and polycarbonates prepared therefrom
  申请人：General Electric Company

  公开号：US06255439B1

  公开（公告）日：2001-07-03

  1,1 -Bis(4-hydroxyphenyl)-3-alkylcyclohexanes, as illustrated by 1,1-bis (4-hydroxyphenyl)-3-pentadecylcyclohexane, are prepared by hydrogenating a composition comprising 3-alkylphenols to the corresponding cyclohexanol, oxidizing the cyclohexanol to a cyclohexanone and contacting the cyclohexanone with phenol in the presence of an acidic catalyst. The preferred 3-alkylphenols are those derived from cashew nut shell liquid. The products can be used to prepare polycarbonates.

  1,1-双(4-羟基苯基)-3-烷基环己烷，例如1,1-双(4-羟基苯基)-3-十五烷基环己烷，是通过氢化含有3-烷基苯酚的混合物得到相应的环己醇，将环己醇氧化为环己酮，并在酸性催化剂的存在下将环己酮与苯酚接触而制备的。首选的3-烷基苯酚是来源于腰果壳液的。该产品可用于制备聚碳酸酯。
• 1,1-BIS(4-HYDROXYPHENYL)-3-ALKYLCYCLOHEXANES, METHOD FOR THEIR PREPARATION AND POLYCARBONATES PREPARED THEREFROM
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP1315692A1

  公开（公告）日：2003-06-04
• US4555537A
  申请人：——

  公开号：US4555537A

  公开（公告）日：1985-11-26