3,6-bis(2-phenylethynyl)-9H-carbazole | 62913-24-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-bis(2-phenylethynyl)-9H-carbazole
• 英文别名: 3,6-Bis(phenylethynyl)-9H-carbazole
• CAS: 62913-24-0
• 化学式: C₂₈H₁₇N
• 分子量: 367.45
• InChiKey: WIKPDOWXNNICRF-UHFFFAOYSA-N

物化性质

• 熔点：
  240-241 °C(Solv: ethanol (64-17-5))
• 沸点：
  626.4±35.0 °C(Predicted)
• 密度：
  1.27±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  29
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  15.8
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3,6-bis(2-phenylethynyl)-9H-carbazole 在 potassium permanganate 作用下， 生成 3,6-bis(phenylglyoxalyl)carbazoles
  参考文献：
  名称：

  Kovaleva, L. F.; Reutova, O. I.; Sarycheva, T. A., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 3, p. 583 - 585

  摘要：

  DOI：
• 作为产物：
  描述：

  咔唑 在 bis-triphenylphosphine-palladium(II) chloride 、 potassium iodate 、 copper(l) iodide 、 溶剂黄146 、 三乙胺 、 potassium iodide 作用下， 以 四氢呋喃 为溶剂， 生成 3,6-bis(2-phenylethynyl)-9H-carbazole
  参考文献：
  名称：

  Easy accessible blue luminescent carbazole-based materials for organic light-emitting diodes

  摘要：

  The thermal, optical, electrochemical and charge transport properties of a series of nine straightforward carbazole-based compounds have been analysed and interpreted according to their molecular structure by means of the X-ray analysis of single crystals. A non-doped OLED device with low turn-on voltage and maximum luminance up to 1.4 x 10(4) cd m(-2) was achieved. DFT calculations have been performed to explain the high efficiency of radiative exciton production. (C) 2016 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2016.09.062

文献信息

• Controllable preparation of magnetic carbon nanocomposites by pyrolysis of organometallic precursors, similar molecular structure but very different morphology, composition and properties
  作者：Zhijun Ruan、Jingwen Ran、Shanshan Liu、Yanmei Chen、Xichao Wang、Jie Shi、Lihong Zhu、Shengfang Zhao、Junqi Lin

  DOI：10.1039/d0nj05699e

  日期：——

  phases has its special catalytic and magnetic properties. Thus, MCNs with very different morphologies, compositions and properties could be prepared by just altering one heteroatom in the precursors upon SSP. Uniform nanotubes were generated from pyrolysis of MC/MN, while nanospheres were generated from MO/MS. The obtained MCNs all show good magnetic properties with Ms ranging from 47.6 to 54.5 emu g−1

  合成了四种含钴的有机金属化合物进行固态热解（SSP），以研究前体与合成后的磁性碳纳米复合物（MCN）之间的结构-性质关系。在这项研究中，在仅饱和碳原子中号Ç用N，O或S原子代替，以产生前体中号Ñ，中号ö和中号小号，分别。结果发现，热解过程中生成的钴的结晶相取决于引入前体的杂原子的类型：对于M C / M N是fcc-Co，对于M O /是fcc / hcp-Co杂化物中号小号。具有不同晶相的金属钴具有特殊的催化和磁性。因此，可以通过仅改变SSP前体中的一个杂原子来制备具有非常不同的形态，组成和性质的MCN。M C / M N的热解产生均匀的纳米管，M O / M S产生纳米球。所获得的MCN均显示出良好的磁性能，M s为47.6至54.5emug -1。由于fcc-Co和hcp-Co之间的磁差，从M获得的MCN的M s值O /M S略低于M C /M N，但前者的M r和H c值是后者的2至5倍。
• Stable All-Organic Radicals with Ambipolar Charge Transport
  作者：Marta Reig、Cristian Gozálvez、Vygintas Jankauskas、Valentas Gaidelis、Juozas V. Grazulevicius、Lluís Fajarí、Luis Juliá、Dolores Velasco

  DOI：10.1002/chem.201603723

  日期：2016.12.19

  A series of neutral long‐lived purely organic radicals based on the stable [4‐(N‐carbazolyl)‐2,6‐dichlorophenyl]bis(2,4,6‐trichlorophenyl)methyl radical adduct (Cbz‐TTM) is reported herein. All compounds exhibit ambipolar charge‐transport properties under ambient conditions owing to their radical character. High electron and hole mobilities up to 10−2 and 10−3 cm2 V−1 s−1, respectively, were achieved

  本文报道了一系列基于稳定的[4-（N-咔唑基）-2,6-二氯苯基]双（2,4,6-三氯苯基）甲基自由基加合物（Cbz-TTM）的中性长寿命纯有机自由基。由于其自由基特性，所有化合物在环境条件下均表现出双极性电荷传输性质。实现了分别高达10 -2和10 -3  cm 2  V -1  s -1的高电子迁移率和空穴迁移率。静电复印单层感光器是由本文研究的自由基制成的，在可见光谱范围内表现出良好的静电复印光敏性。
• KOVALEVA, L. F.;REUTOVA, O. I.;SARYCHEVA, T. A.;SHELUDYAKOV, O. A.;NOVIKO+, ZH. ORGAN. XIMII, 24,(1988) N 3, 650-653
  作者：KOVALEVA, L. F.、REUTOVA, O. I.、SARYCHEVA, T. A.、SHELUDYAKOV, O. A.、NOVIKO+

  DOI：——

  日期：——
• Easy accessible blue luminescent carbazole-based materials for organic light-emitting diodes
  作者：Marta Reig、Cristian Gozálvez、Roger Bujaldón、Gintautas Bagdziunas、Khrystyna Ivaniuk、Nataliya Kostiv、Dmytro Volyniuk、Juozas V. Grazulevicius、Dolores Velasco

  DOI：10.1016/j.dyepig.2016.09.062

  日期：2017.2

  The thermal, optical, electrochemical and charge transport properties of a series of nine straightforward carbazole-based compounds have been analysed and interpreted according to their molecular structure by means of the X-ray analysis of single crystals. A non-doped OLED device with low turn-on voltage and maximum luminance up to 1.4 x 10(4) cd m(-2) was achieved. DFT calculations have been performed to explain the high efficiency of radiative exciton production. (C) 2016 Elsevier Ltd. All rights reserved.
• Kovaleva, L. F.; Reutova, O. I.; Sarycheva, T. A., Journal of Organic Chemistry USSR (English Translation), 1988, vol. 24, # 3, p. 583 - 585
  作者：Kovaleva, L. F.、Reutova, O. I.、Sarycheva, T. A.、Sheludyakov, O. A.、Novikov, A. N.、Filimonov, V. D.

  DOI：——

  日期：——