(perfluor n-propyl) ethyl methanol | 356-22-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代醇
• 英文名称: (perfluor n-propyl) ethyl methanol
• 英文别名: 4,4,5,5,6,6,6-heptafluoro-hexan-3-ol；4,4,5,5,6,6,6-Heptafluor-hexan-3-ol；1,1,1,2,2,3,3-Heptafluor-hexanol-(4)；4,4,5,5,6,6,6-Heptafluorohexan-3-ol
• CAS: 356-22-9
• 化学式: C₆H₇F₇O
• 分子量: 228.11
• InChiKey: HFGVNJOKJDTJSE-UHFFFAOYSA-N

物化性质

• 熔点：
  -14 °C
• 沸点：
  113.5 °C(Press: 745 Torr)
• 密度：
  1.439 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  14
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  (perfluor n-propyl) ethyl methanol 在 四氯化碳 、 氯 、 potassium carbonate 作用下， 生成 6,6,6,5,5,4,4-Heptafluor-1.3-hexandiol
  参考文献：
  名称：

  Chlorination of Fluorine—containing Alcohols¹

  摘要：

  DOI：

  10.1021/ja01103a027
• 作为产物：
  描述：

  2,2,3,3,4,4,4-七氟丁醛水合物 、 乙基锂 在 乙醚 作用下， 生成 (perfluor n-propyl) ethyl methanol
  参考文献：
  名称：

  1,2,3,4-Tetrachlorocyclopentadiene. I. The Preparation of the Diene and its Reaction with Aromatic Aldehydes and Dienophiles

  摘要：

  DOI：

  10.1021/ja01606a027

文献信息

• Estimation of hydrocarbon solubilities in hydrofluorocarbons
  作者：Michael Van Der Puy、Andrew J. Poss、Phillip J. Persichini、Lois A.S. Ellis

  DOI：10.1016/0022-1139(93)02960-m

  日期：1994.6

  A new solubility parameter, SP, for hydrofluorocarbons (HFCs) has been developed (SP=1.175 ln(np)+ 0.025H-0.063F-0.028α-0.018β where np depends on the molar volume and the molar refractivity; H and F are the number of hydrogens and fluorines, respectively, in the molecule; and α and β are the respective numbers of H-C-F and H-C-C-F connections). Values of SP have been used to predict if an HFC would

  已经开发出用于氢氟碳化合物（HFC）的新溶解度参数SP（SP = 1.175 ln（np）+ 0.025 H -0.063 F -0.028α-0.018β，其中np取决于摩尔体积和摩尔折射率；H和F分别是分子中氢和氟的数目；而α和β分别是HCF和HCCF连接的数目。SP的价值HFC已被用来预测HFC在25°C下对于各种碳氢化合物是否是良好的溶剂。在异构HFC族中，对烃具有最大溶解能力的单个HFC是那些氟与氢的分离度最大的HFC。将希尔德布兰德溶解度参数δ与半经验SP值进行比较。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.4, 2.2.4, page 68 - 115
  作者：

  DOI：——

  日期：——
• Haszeldine, R. N., Journal of the Chemical Society
  作者：Haszeldine, R. N.

  DOI：——

  日期：——
• A model of therapeutic intervention with Indigenous Australians
  作者：David Vicary、Henry Andrews

  DOI：10.1111/j.1467-842x.2001.tb00592.x

  日期：2001.8

  Many non-Aboriginal mental health practitioners are confronted by the lack of practical information pertaining to interventions with Aboriginal clientele. Subsequently, this may have engendered uncertainty in potential therapists and counsellors due to the lack of reliable, practical and culturally appropriate information. Those non-Aboriginal mental health practitioners working in the field with Aboriginal clients do so with varying degrees of success and build upon their knowledge base through personal experience and anecdotal information. Unfortunately, this information is often not made available to others working in the field through journal publication. This Practice Note examines a model of intervention aimed at developing relationships to enhance therapeutic interventions at the individual, family and systems level. As a way of clarification, the model is described via a case study involving a psychological intervention with a remote Aboriginal community.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: F: PerFHalOrg.4, 1.3.3.8, page 33 - 59
  作者：

  DOI：——

  日期：——