2,9-bis(5-tert-butyl-3-formyl-2-hydroxyphenyl)-1,10-phenanthroline | 241822-70-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,9-bis(5-tert-butyl-3-formyl-2-hydroxyphenyl)-1,10-phenanthroline
• 英文别名: 5-Tert-butyl-3-[9-(5-tert-butyl-3-formyl-2-hydroxyphenyl)-1,10-phenanthrolin-2-yl]-2-hydroxybenzaldehyde
• CAS: 241822-70-8
• 化学式: C₃₄H₃₂N₂O₄
• 分子量: 532.639
• InChiKey: BZQKRJDNDSBAAS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  100
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  2,9-bis(5-tert-butyl-3-formyl-2-hydroxyphenyl)-1,10-phenanthroline 在 sodium tetrahydroborate 作用下， 以 甲醇 为溶剂， 反应 2.0h， 以90%的产率得到2,9-bis(5-tert-butyl-3-hydroxymethyl-2-hydroxyphenyl)-1,10-phenanthroline
  参考文献：
  名称：

  Synthesis of dinucleating phenanthroline-based ligands

  摘要：

  The phenolic bridged dinucleating phenanthroline-pyridine, phenanthroline-phosphine, phenanthroline-alcohol, and phenanthroline-imine ligands have been synthesized from I,10-phenanthroline via key Stille and Suzuki cross couplings. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00428-7
• 作为产物：
  描述：

  2-溴-4-叔丁基 1-甲氧基苯 在 吡啶盐酸盐 、 lithium 、 三氟乙酸 作用下， 以 乙醚 为溶剂， 反应 58.0h， 生成 2,9-bis(5-tert-butyl-3-formyl-2-hydroxyphenyl)-1,10-phenanthroline
  参考文献：
  名称：

  Synthesis of dinucleating phenanthroline-based ligands

  摘要：

  The phenolic bridged dinucleating phenanthroline-pyridine, phenanthroline-phosphine, phenanthroline-alcohol, and phenanthroline-imine ligands have been synthesized from I,10-phenanthroline via key Stille and Suzuki cross couplings. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00428-7

文献信息

• METAL COMPLEX, AND USE THEREOF
  申请人：Matsunaga Tadafumi

  公开号：US20090318681A1

  公开（公告）日：2009-12-24

  Provided is a metal complex represented by the following formula (A-1) or (B-1) as a metal complex useful for a redox reaction catalyst or some other article that is excellent in heat resistance and acid resistance:

  以下是一种金属配合物，用以下公式(A-1)或(B-1)表示，该金属配合物可用作氧化还原反应催化剂或其他在耐热性和耐酸性方面表现出色的物品：
• CATHODE CATALYST FOR AIR SECONDARY BATTERY AND AIR SECONDARY BATTERY
  申请人：Koshino Nobuyoshi

  公开号：US20140066290A1

  公开（公告）日：2014-03-06

  The present invention provides a cathode catalyst for an air secondary cell having both excellent oxygen reduction activity and excellent water oxidation activity, and an air secondary cell that uses the catalyst. The present invention relates to a cathode catalyst for an air secondary cell in which the catalyst contains a polynuclear metal complex.

  本发明提供了一种空气二次电池的阴极催化剂，具有优异的氧还原活性和优异的水氧化活性，并且使用该催化剂的空气二次电池。本发明涉及一种空气二次电池的阴极催化剂，其中该催化剂包含多核金属配合物。
• EP2399918
  申请人：——

  公开号：——

  公开（公告）日：——
• RING COMPOUND
  申请人：Iwata Masatoshi

  公开号：US20120021897A1

  公开（公告）日：2012-01-26

  A compound represented by the following formula (1): wherein, Y 1 , Y 2 , Y 3 and Y 4 represent a group represented by any of the above formulae; P 1 , P 2 , P 3 and P 4 are an atomic group required for forming an aromatic heterocyclic ring; P 5 and P 6 are an atomic group required for forming an aromatic ring; Z 1 and Z 2 represent OR α , —SR α or —NR α 2 , wherein R α represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms; Q 1 and Q 2 represent a direct bond or a linking group; a P 1 -containing ring and a P 2 -containing ring are bonded to form Q 1 -containing fused structure; a P 3 -containing ring and a P 4 -containing ring are bonded to form Q 2 -containing fused structure; can be used as a ligand of a metal complex, and the metal complex is useful for a catalyst.