6-Amino-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazine | 103362-13-6

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 6-Amino-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazine
• 英文别名: 6-amino-4-(2-propynyl)-2H-1,4-benzoxazin-3(4H)-one；6-amino-4-propargyl-2H-1,4-benzoxazin-3(4H)-one；6-amino-4-proparagyl-2H-1,4-benzoxazin-3(4H)-one；6-amino-4-prop-2-ynyl-1,4-benzoxazin-3-one
• CAS: 103362-13-6
• 化学式: C₁₁H₁₀N₂O₂
• 分子量: 202.213
• InChiKey: XHWXEJORPOKDLM-UHFFFAOYSA-N

物化性质

• 熔点：
  260.1 °C
• 沸点：
  504.5±50.0 °C(Predicted)
• 密度：
  1.304±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  55.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  6-Amino-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazine 、 3,4,5,6-四氢邻苯二甲酰亚胺 生成 N-(3,4-dihydro-3-oxo-4-prop-2-ynyl-2H-1,4-benzoxazin-6-yl)cyclohex-1-ene-1,2-dicarboxamide
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  6-nitro-4-propargyl-2H-1,4-benzoxazin-3(4H)-one 在 铁粉 铁粉 、 乙酸乙酯 、 碳酸氢钠 、 magnesium sulfate 、 水 作用下， 以 溶剂黄146 、 乙酸乙酯 、 水 为溶剂， 反应 1.0h， 以to yield 2.55 g (75% yield) of 6-amino-4-propargyl-2H-1,4-benzoxazin-3 (4H)-one的产率得到6-Amino-3,4-dihydro-3-oxo-4-(2-propynyl)-2H-1,4-benzoxazine
  参考文献：
  名称：

  Herbicidal glutaramic acids and derivatives

  摘要：

  本发明涉及具有除草活性的谷氨酸和衍生物，其结构式为##STR1##其中A是羧酸或其衍生物，D是CH或N，R、R.sup.1、R.sup.2、T、X、Y和Z的定义如内部所定义，包含这些化合物的组合物以及使用这些化合物控制杂草的方法。

  公开号：

  US05238908A1

文献信息

• Heterocyclic substituted uracil derivatives
  申请人：Ciba-Geigy Corporation

  公开号：US05232898A1

  公开（公告）日：1993-08-03

  The invention is concerned with compounds of the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, n and X have the significances given in the description, as well as enol ethers and salts thereof and their manufacture. The compounds have herbicidal properties and are accordingly suitable as active ingredients of weed control compositions. The invention is also concerned with weed control compositions containing one or more of such substances as well as the use of the substances or compositions for the control of weeds. Certain starting materials, which also have herbicidal activity, and their production are also described.

  这项发明涉及以下结构的化合物##STR1##其中R.sup.1、R.sup.2、R.sup.3、R.sup.4、R.sup.5、R.sup.6、R.sup.7、n和X的含义如描述中所示，以及烯醚及其盐和制备方法。这些化合物具有除草特性，因此适用作为除草剂配方的活性成分。该发明还涉及含有一种或多种这类物质的除草剂配方，以及利用这些物质或配方控制杂草。还描述了具有除草活性的某些起始材料及其生产。
• Tetrahydrophthalimides and their herbicidal use
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：US04640707A1

  公开（公告）日：1987-02-03

  A compound of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group, a C.sub.3 -C.sub.4 alkenyl group, a C.sub.3 -C.sub.4 alkynyl group, a C.sub.1 -C.sub.4 haloalkyl group, a C.sub.3 -C.sub.4 haloalkenyl group, a C.sub.3 -C.sub.4 haloalkynyl group, a C.sub.1 -C.sub.2 alkoxy(C.sub.1 -C.sub.2)alkyl group or a C.sub.1 -C.sub.2 alkoxy(C.sub.1 -C.sub.2)alkoxy(C.sub.1 -C.sub.2)alkyl group, R.sub.2 and R.sub.3 are, the same or different, each a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.3 alkyl group or a phenyl group, X is a hydrogen atom, a chlorine atom or a fluorine atom and n is an integer of 0 or 1, which is useful as a herbicide.

  一种具有以下结构式的化合物：##STR1## 其中R.sub.1是氢原子，C.sub.1 -C.sub.5烷基，C.sub.3 -C.sub.4烯基，C.sub.3 -C.sub.4炔基，C.sub.1 -C.sub.4卤代烷基，C.sub.3 -C.sub.4卤代烯基，C.sub.3 -C.sub.4卤代炔基，C.sub.1 -C.sub.2烷氧(C.sub.1 -C.sub.2)烷基或C.sub.1 -C.sub.2烷氧(C.sub.1 -C.sub.2)烷氧(C.sub.1 -C.sub.2)烷基，R.sub.2和R.sub.3是相同或不同的氢原子，卤素原子，C.sub.1 -C.sub.3烷基或苯基，X是氢原子，氯原子或氟原子，n是0或1的整数，可用作除草剂。
• Herbicidal glutarimides
  申请人：Rohm and Haas Company

  公开号：US05393735A1

  公开（公告）日：1995-02-28

  This invention relates to glutarimide compounds exhibiting herbicidal activity having the structure ##STR1## wherein A is carbonyl, thiocarbonyl or methylene, A.sup.1 is carbonyl or methylene, Q is O or (CH.sub.2).sub.n where n is 0 or 1, D is CH or N and R, R.sup.1, R.sup.2, T, X, Y and Z are as defined within, compositions containing these compounds and methods of using these compounds as herbicides and algicides.

  本发明涉及一种具有除草活性的戊二酰亚胺化合物，其结构为##STR1##其中A为羰基、硫代羰基或亚甲基，A.sup.1为羰基或亚甲基，Q为O或(CH.sub.2).sub.n，其中n为0或1，D为CH或N，R、R.sup.1、R.sup.2、T、X、Y和Z的定义如下，包含这些化合物的组合物以及使用这些化合物作为除草剂和藻类杀灭剂的方法。
• 1,4-benzoxazin-3-one-6-(amino or nitro) intermediates
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：US04792605A1

  公开（公告）日：1988-12-20

  A compound of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group, a C.sub.3 -C.sub.4 alkenyl group, a C.sub.3 -C.sub.4 alkynyl group, a C.sub.1 -C.sub.4 haloalkyl group, a C.sub.3 -C.sub.4 haloalkenyl group, a C.sub.3 -C.sub.4 haloalkynyl group a C.sub.1 -C.sub.2 alkoxy(C.sub.1 -C.sub.2)alkyl group or a C.sub.1 -C.sub.2 alkoxy(C.sub.1 -C.sub.2)alkoxy(C.sub.1 -C.sub.2)alkyl group, R.sub.2 and R.sub.3 are, the same or different, each a hydrogen atom, a halogen atoms, a C.sub.1 -C.sub.3 alkyl group or a phenyl group, X is a hydrogen atom, a chlorine atom or a fluorine atom and n is an interger of 0 or 1, which is useful as a herbicide.

  该化合物的化学式为：##STR1## 其中R.sub.1是氢原子、C.sub.1-C.sub.5烷基、C.sub.3-C.sub.4烯基、C.sub.3-C.sub.4炔基、C.sub.1-C.sub.4卤代烷基、C.sub.3-C.sub.4卤代烯基、C.sub.3-C.sub.4卤代炔基、C.sub.1-C.sub.2烷氧基(C.sub.1-C.sub.2)烷基或C.sub.1-C.sub.2烷氧基(C.sub.1-C.sub.2)烷氧基(C.sub.1-C.sub.2)烷基，R.sub.2和R.sub.3是相同或不同的氢原子、卤素原子、C.sub.1-C.sub.3烷基或苯基，X是氢原子、氯原子或氟原子，n是0或1的整数，它可用作除草剂。
• Intermediates for the production of tetrahydrophthalimides
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：US04880925A1

  公开（公告）日：1989-11-14

  A compound of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.5 alkyl group, a C.sub.3 -C.sub.4 alkenyl group, a C.sub.3 -C.sub.4 alkynyl group, a C.sub.1 -C.sub.4 haloalkyl group, a C.sub.3 -C.sub.4 haloalkenyl group, a C.sub.3 -C.sub.4 haloalkynyl group, a C.sub.1 -C.sub.2 alkoxy(C.sub.1 -C.sub.2)alkyl group or a C.sub.1 -C.sub.2 alkoxy(C.sub.1 -C.sub.2)alkoxy(C.sub.1 -C.sub.2)alkyl group, R.sub.2 and R.sub.3 are, the same or different, each a hydrogen atom, a halogen atom, a C.sub.1 -C.sub.3 alkyl group or a phenyl group, X is a hydrogen atom, a chlorine atom or a fluorine atom and n is an integer of 0 or 1, which is useful as a herbicide.

  该化合物的化学式为：##STR1## 其中R.sub.1是氢原子，C.sub.1-C.sub.5烷基，C.sub.3-C.sub.4烯基基团，C.sub.3-C.sub.4炔基团，C.sub.1-C.sub.4卤代烷基，C.sub.3-C.sub.4卤代烯基基团，C.sub.3-C.sub.4卤代炔基团，C.sub.1-C.sub.2烷氧基(C.sub.1-C.sub.2)烷基团或C.sub.1-C.sub.2烷氧基(C.sub.1-C.sub.2)烷氧基(C.sub.1-C.sub.2)烷基团，R.sub.2和R.sub.3是相同或不同的氢原子，卤素原子，C.sub.1-C.sub.3烷基或苯基，X是氢原子，氯原子或氟原子，n是0或1的整数，该化合物可用作除草剂。