18,18,18',18'-Tetramethyl-16,16'-spirobi[2,7,12-trioxapentacyclo[11.7.0.03,11.05,9.015,19]icosa-1(13),3(11),4,9,14,19-hexaene]-6,6',8,8'-tetrone | 939797-02-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 18,18,18',18'-Tetramethyl-16,16'-spirobi[2,7,12-trioxapentacyclo[11.7.0.03,11.05,9.015,19]icosa-1(13),3(11),4,9,14,19-hexaene]-6,6',8,8'-tetrone
• CAS: 939797-02-1
• 化学式: C₃₇H₂₄O₁₀
• 分子量: 628.592
• InChiKey: ORMYLYWETBHZPZ-UHFFFAOYSA-N

物化性质

• 密度：
  1.63±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.6
• 重原子数：
  47
• 可旋转键数：
  0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.24
• 拓扑面积：
  124
• 氢给体数：
  0
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  18,18,18',18'-Tetramethyl-16,16'-spirobi[2,7,12-trioxapentacyclo[11.7.0.03,11.05,9.015,19]icosa-1(13),3(11),4,9,14,19-hexaene]-6,6',8,8'-tetrone 、 4-(2-丙炔基氧)苯胺 在 吡啶 、 乙酸酐 作用下， 以 N-甲基吡咯烷酮 为溶剂， 反应 7.0h， 以6.18 g的产率得到18,18,18',18'-Tetramethyl-7,7'-bis(4-prop-2-ynoxyphenyl)-16,16'-spirobi[2,12-dioxa-7-azapentacyclo[11.7.0.03,11.05,9.015,19]icosa-1(13),3(11),4,9,14,19-hexaene]-6,6',8,8'-tetrone
  参考文献：
  名称：

  MATERIAL FOR FORMING ORGANIC FILM, SUBSTRATE FOR MANUFACTURING SEMICONDUCTOR DEVICE, METHOD FOR FORMING ORGANIC FILM, PATTERNING PROCESS, AND COMPOUND FOR FORMING ORGANIC FILM

  摘要：

  本发明涉及一种用于形成有机薄膜的材料，包含：（A）用下列一般式（1A）表示的用于形成有机薄膜的化合物；以及（B）有机溶剂，其中W1表示四价有机基团，n1表示0或1的整数，n2表示1至3的整数，R1表示以下一般式（1B）中的任意一个或多个。这提供了一种酰亚胺化合物，该化合物不仅在空气下固化，而且在惰性气体的薄膜形成条件下也可以固化，并且可以形成具有优异的耐热性、填平和平整化衬底上形成的图案的性能以及对衬底的良好成膜性和附着性的有机底层薄膜，以及含有该化合物的用于形成有机薄膜的材料。

  公开号：

  US20220107566A1
• 作为产物：
  描述：

  4,5-二氯邻苯二甲酸酐 在 ammonium hydroxide 、 氯化亚砜 、 乙酸酐 、 potassium carbonate 、 formamide 、 potassium hydroxide 作用下， 以 乙醇 、 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 127.0h， 生成 18,18,18',18'-Tetramethyl-16,16'-spirobi[2,7,12-trioxapentacyclo[11.7.0.03,11.05,9.015,19]icosa-1(13),3(11),4,9,14,19-hexaene]-6,6',8,8'-tetrone
  参考文献：
  名称：

  A Facile Reprecipitation Method for the Preparation of Polyimide Hollow Spheres with Controllable Morphologies and Permeable Shell

  摘要：

  我们介绍了通过重沉淀法制备聚酰亚胺空心球体的初步工作。通过精细调整聚丙烯酰胺（PAA）的浓度，可以获得包括塌陷胶囊、碗状和酒窝状空心球等多种有趣的形状。向PAA溶液中添加盐有助于形成具有完整壳层的聚酰亚胺（PI）空心球。通过酰亚化可以固定形态，从而获得一种可控且可重复的方法，用于制备具有各种形态的高性能聚酰亚胺空心球。

  DOI：

  10.1246/cl.2010.1194

文献信息

• O-hydroxy-functionalized diamines, polyimides, methods of making each, and methods of use
  申请人：KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

  公开号：US10240001B2

  公开（公告）日：2019-03-26

  Embodiments of the present disclosure provide for an ortho (o)-hydroxy-functionalized diamine, a method of making an o-hydroxy-functionalized diamine, an o-hydroxy-functionalized diamine-based polyimide, a method of making an o-hydroxy-functionalized diamine imide, methods of gas separation, and the like.

  本公开的实施例提供了一种正（邻）羟基官能化二胺、邻羟基官能化二胺的制造方法、邻羟基官能化二胺基聚酰亚胺、邻羟基官能化二胺亚胺的制造方法、气体分离方法等。
• O-HYDROXY-FUNCTIONALIZED DIAMINES, POLYMIDES, METHODS OF MAKING EACH, AND METHODS OF USE
  申请人：King Abdullah University of Science and Technology

  公开号：EP3169661B1

  公开（公告）日：2019-06-19
• MICROPOROUS POLYMER MATERIAL
  申请人：McKeown Neil B.

  公开号：US20100304112A1

  公开（公告）日：2010-12-02

  The present invention relates to a microporous material which is a non-network polymer having a chain comprised of repeating units bonded to each other and each including a first generally planar species and a rigid linker, the linker having a point of contortion such that two adjacent first planar species connected by a rigid linker are held in a non-coplanar orientation, the rigid linker further being such that the polymer chain has a rigid contorted structure, and the polymer being such that said repeating units comprised of the first generally planar species and the rigid linker are bonded predominately to two other such repeating units.
• CROSSLINKED POLYMER, METHOD FOR PRODUCING THE SAME, MOLECULAR SIEVE COMPOSITION AND MATERIAL SEPARATION MEMBRANES
  申请人：KYOTO UNIVERSITY

  公开号：US20160367948A1

  公开（公告）日：2016-12-22

  The present invention provides a process for thermal crosslinking of polymers of intrinsic microporosity (PIMs) by heat treatment of PIMs under controlled oxygen concentration.
• O-HYDROXY-FUNCTIONALIZED DIAMINES, POLYIMIDES, METHODS OF MAKING EACH, AND METHODS OF USE
  申请人：KING ABDULLAH UNIVERSITY OF SCIENCE AND TECHNOLOGY

  公开号：US20170190842A1

  公开（公告）日：2017-07-06

  Embodiments of the present disclosure provide for an ortho (o)-hydroxy-functionalized diamine, a method of making an o-hydroxy-functionalized diamine, an o-hydroxy-functionalized diamine-based polyimide, a method of making an o-hydroxy-functionalized diamine imide, methods of gas separation, and the like.