4,4’-(1,10-癸二氧基)二苯胺 | 38324-63-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 4,4’-(1,10-癸二氧基)二苯胺
• 中文别名: 4,4'-(1,10-癸二氧基)双苯胺
• 英文名称: 1.10-Bis-(p-aminophenoxy)decan
• 英文别名: 4,4'-(decane-1,10-diylbis(oxy))dianiline；4,4'-decanediyldioxy-di-aniline；1,10-Bis-[4-amino-phenoxy)-decan；4,4'-Decandiyldioxy-di-anilin；1,10-bis(4-aminophenoxy)decane；4,4'-(1,10-Decanediyl)dioxydianiline；4-[10-(4-aminophenoxy)decoxy]aniline
• CAS: 38324-63-9
• 化学式: C₂₂H₃₂N₂O₂
• 分子量: 356.508
• InChiKey: NGMJQNYIDZLGFP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  26
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  70.5
• 氢给体数：
  2
• 氢受体数：
  4

安全信息

• 海关编码：
  2922299090

反应信息

• 作为反应物：
  描述：

  4,4’-(1,10-癸二氧基)二苯胺 、 (p-formylphenyl)trimethylammonium bromide 在 溶剂黄146 作用下， 生成
  参考文献：
  名称：

  Formation of stable monolayer membranes and related structures in dilute aqueous solution from two-headed ammonium amphiphiles

  摘要：

  DOI：

  10.1021/ja00512a020
• 作为产物：
  描述：

  4-nitrophenol sodium salt 在 palladium on activated charcoal 氢气 作用下， 以 四氢呋喃 、 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 10.0h， 生成 4,4’-(1,10-癸二氧基)二苯胺
  参考文献：
  名称：

  Novel bis[1,6-dihydro-6,6-dimethyl-1,3,5-triazine-2,4-diamines] as antitrypanosomal agents

  摘要：

  A series of novel 1,1'-(4,1-phenylene)bis [1,6-dihydro-6,6-dimethyl-1,3,5-triazine-2,4-diamines] was prepared and evaluated for activity against Trypanosoma rhodesiense in mice. The importance of the bis structure and the nature of the spacer between the two phenyl rings for optimal activity have been revealed. The potent parenteral activity of several analogues within this series as well as preliminary indication of oral activity lends encouragement to further development of this structural class.

  DOI：

  10.1021/jm00149a032

文献信息

• NOVEL DIAMINE, POLYAMIC ACID, AND POLYIMIDE
  申请人：NISSAN CHEMICAL INDUSTRIES. LTD.

  公开号：US20160264520A1

  公开（公告）日：2016-09-15

  To provide a novel diamine, and a polyimide precursor and a polyimide using it. A diamine represented by the formula (1): wherein each of X 1 and X 5 which are independent of each other, is a single bond or the like; each of X 2 and X 4 which are independent of each other, is —CH 2 — or the like; X 3 is a C 1-6 alkylene or the like; each of Y 1 and Y 2 which are independent of each other, is a single bond or the like; R is a C 1-20 linear, branched or cyclic hydrocarbon group; and a is 0 or 1).

  提供一种新颖的二胺，以及使用它的聚酰亚胺前体和聚酰亚胺。一种由式（1）表示的二胺：其中X1和X5中的每一个独立的，是单键或类似物；X2和X4中的每一个独立的，是—CH2—或类似物；X3是C1-6烷基或类似物；Y1和Y2中的每一个独立的，是单键或类似物；R是C1-20线性、支链或环烃基；a为0或1。
• Design and characterization of novel bis -benzamide liquid crystalline materials
  作者：Asma Iqbal、Humaira Masood Siddiqi、Zareen Akhter、Muhammad Qaiser Fatmi

  DOI：10.1016/j.molstruc.2017.08.106

  日期：2018.1

  with theoretical studies and relationship between molecular structure and mesogenic behavior has been established. The mesomorphic properties of the resultant dimers were characterized by differential scanning calorimetry (DSC) and polarized optical microscopy (POM) equipped with a hot stage. Change in mesomorphic properties with change of methylene spacers was observed. Enantiotropic mesogenic behavior

  摘要 已经制备了一个新的同源系列的对称、弯曲形状的双苯甲酰胺二聚体。几个 1,n-双 (对氨基苯氧基) 烷烃 (n = 3, 5, 9,10,11) 被用作间隔物，并且对己氧基尾部已经合成并通过酰胺连接基团附加到间隔物上。使用半经验方法的计算分析探索了不同的重要参数。实验结果与理论研究相关，并建立了分子结构与介晶行为之间的关系。所得二聚体的介晶性质通过差示扫描量热法 (DSC) 和配备热台的偏光显微镜 (POM) 进行表征。观察到介晶性质随着亚甲基间隔基的变化而变化。D 3 A 6 表现出对映性介晶行为，观察到D 10 A 6 和D 11 A 6 以及针状和模糊的纹饰纹理。观察到增加的亚甲基间隔链长度降低了熔融温度。热重分析显示二聚体的热稳定性高达 360 °C。
• A photoswitchable methylene-spaced fluorinated aryl azobenzene monolayer grafted on silicon
  作者：Misook Min、Gyeong Sook Bang、Hyoyoung Lee、Byung-Chan Yu

  DOI：10.1039/c0cc00521e

  日期：——

  Aryldiazonium-terminated methylene-spaced trifluoromethylazobenzene derivatives have been synthesized. Their self-assembled monolayers (SAMs) on a silicon surface allow for a stable and reversible molecular photoswitch.

  我们合成了芳基偶氮端亚甲基间隔三氟甲基偶氮苯衍生物。它们在硅表面的自组装单分子层（SAM）可实现稳定、可逆的分子光开关。
• Process for preparing substituted bis-ethers
  申请人：The Dow Chemical Company

  公开号：US04683333A1

  公开（公告）日：1987-07-28

  Substituted bis-ethers, such as .alpha.,107 -bis-(4-aminophenoxy)-alkyls, are prepared in process which involves sequential addition of reactants, reagents or neutralizing compounds without recovery of intermediate products such as diamides and diamine acid salts. When water is used as the solvent, the process is simplified and product yields in excess of about 70% are obtained.

  替代双醚，例如.alpha.，107-双-(4-氨基苯氧基)-烷基，是通过顺序添加反应物，试剂或中和化合物，而无需恢复二酰胺和二胺酸盐等中间产物而制备的。当水被用作溶剂时，该过程变得简化，并且可以获得超过70％的产量。
• Molecular aggregate having an ordered structure
  申请人：Asahi Kasei Kogyo Kabushiki Kaisha

  公开号：US04469621A1

  公开（公告）日：1984-09-04

  A stable molecular aggregate having an ordered structure comprising a surfactant containing a hydrophilic moiety and hydrophobic moiety and having in the hydrophobic moiety or between the hydrophobic moiety and the hydrophilic moiety a rigid moiety at least 10 .ANG. long is disclosed. The structure, unlike the spherical micelle formed by an ordinary surfactant in water or the loose lamellar micelle formed by a soap in a high concentration, is stable and durable in low concentrations, keeping a high degree of regularity. The structure has primarily a bilayer structure as a basic structural unit.

  揭示了一种具有有序结构的稳定分子聚集体，包含具有亲水基团和疏水基团的表面活性剂，并在疏水基团或疏水基团和亲水基团之间具有至少10个. ANG.长的刚性基团。与普通表面活性剂在水中形成的球形胶束或肥皂在高浓度下形成的松散层状胶束不同，该结构在低浓度下稳定耐用，保持高度规则性。该结构主要具有双层结构作为基本结构单元。