sebacic acid monoallyl ester | 56860-93-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: sebacic acid monoallyl ester
• 英文别名: decanedioic acid monoallyl ester；Decandisaeure-monoallylester；10-(Allyloxy)-10-oxodecanoic acid；10-oxo-10-prop-2-enoxydecanoic acid
• CAS: 56860-93-6
• 化学式: C₁₃H₂₂O₄
• 分子量: 242.315
• InChiKey: URCNJXHRGBIDHF-UHFFFAOYSA-N

物化性质

• 熔点：
  34-35 °C
• 沸点：
  205-208 °C(Press: 9 Torr)
• 密度：
  1.025±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  17
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  sebacic acid monoallyl ester 在 吗啉 、 4-二甲氨基吡啶 、 四(三苯基膦)钯 、 苯甲醚 、 盐酸-N-乙基-Nˊ-(3-二甲氨基丙基)碳二亚胺 、 三氟乙酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 72.0h， 生成 phorbol 12-sebacate-13-acetate
  参考文献：
  名称：

  Protein Kinase C Translocation by Modified Phorbol Esters with Functionalized Lipophilic Regions

  摘要：

  Several novel phorbol esters were prepared with polar functional groups terminating their C12 and/or C13 acyl chains. Designed to be inhibitory protein kinase C (PKC) ligands, these phorbol analogues contain various polar functional groups (amide, ester, carboxylic acid, or quaternary ammonium salt) to prevent membrane insertion of the PKC-phorbol ester complex. All phorbol derivatives were synthesized with use of diterpene starting materials obtained from croton oil, the seed oil of Croton tiglium. The ability of these derivatives to recruit PKC to the lipid bilayer-a usual requirement for enzyme activation-was determined by using a sucrose-loaded vesicle assay. Phorbol 12-octanoate-13-acetate derivatives translocate PKC-betaII to increasing degrees as the functionality on the C12 ester becomes more hydrophobic. Likewise, PKC translocation by carboxylic acid-containing phorbol esters was dependent upon length and saturation of the hydrocarbon tether. The most promising PKC inhibitors had short carboxylic acids capping their C12 and C13 acyl chains, since these compounds did not recruit PKC to any appreciable extent.

  DOI：

  10.1021/jo030029w
• 作为产物：
  描述：

  10-O-(3-methylbut-2-enyl) 1-O-prop-2-enyl decanedioate 在 碘 作用下， 以 环己烷 为溶剂， 反应 6.0h， 以85%的产率得到sebacic acid monoallyl ester
  参考文献：
  名称：

  A very useful and mild method for the protection and deprotection of carboxylic acids

  摘要：

  3-Methylbut-2-enoate carboxylic acid can be a good protecting group of carboxylic acids and can be removed easily by using iodine in cyclohexane at room temperature.

  DOI：

  10.1016/s0040-4039(00)76752-9

文献信息

• ORGANIC MIXTURE AND APPLICATION THEREOF IN ORGANIC ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200317646A1

  公开（公告）日：2020-10-08

  The present invention relates to an organic mixture and an application thereof in organic electronic devices. The organic mixture comprises a spirofluorene organic compound containing a fused heterocyclic ring and an aromatic fused heterocyclic organic compound containing an electron-donating group. A combination of the two materials may be used as a host material of a phosphorescent organic light-emitting diode (OLED), which may use the energy of excitons and balance the charge transport to the greatest extent and which may effectively reduce the concentration of excitons and the operating voltage of a corresponding device, thereby effectively improving the efficiency and service life of the related electronic device in order to provide an effective solution for improving the overall performance of an organic electronic device.

  本发明涉及一种有机混合物及其在有机电子器件中的应用。该有机混合物包括含有螺环异芳烃环的螺芴有机化合物和含有供电子给体基团的芳香融合杂环有机化合物。这两种材料的组合可用作磷光有机发光二极管（OLED）的主体材料，该二极管可以利用激子的能量并最大程度地平衡电荷传输，从而有效降低激子的浓度和相应器件的工作电压，从而有效提高相关电子器件的效率和使用寿命，为改善有机电子器件的整体性能提供有效解决方案。
• TERBENZOCYCLOPENTADIENE COMPOUND, HIGH POLYMER, MIXTURE, COMPOSITION AND ORGANIC ELECTRONIC DEVICE
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20180354934A1

  公开（公告）日：2018-12-13

  Disclosed are a terbenzocyclopentadiene compound of better solubility and film-forming property, and a high polymer, mixture, composition and organic electronic device comprising same. This terbenzocyclopentadiene compound contains a benzocyclopentadiene structure. The matching of energy level and the symmetry of the structure provide a possibility for increasing the chemical/environmental stability of terbenzocyclopentadiene compounds and photoelectric devices. This terbenzocyclopentadiene compound has a better solubility in an organic solvent, and also facilitates forming a high-quality film by a printing method due to a high molecular weight. After this terbenzocyclopentadiene compound is used in OLED, particularly as a luminescent layer material, a higher quantum efficiency, luminescence stability and device life time can be provided.

  揭示了一种溶解性和成膜性更好的苯并环戊二烯化合物，以及包括该化合物的高分子、混合物、组合物和有机电子器件。该苯并环戊二烯化合物含有苯并环戊二烯结构。能级匹配和结构的对称性为提高苯并环戊二烯化合物和光电器件的化学/环境稳定性提供了可能性。该苯并环戊二烯化合物在有机溶剂中具有更好的溶解性，且由于具有高分子量，通过印刷方法易于形成高质量的薄膜。在该苯并环戊二烯化合物用于OLED中，特别作为发光层材料时，可以提供更高的量子效率、发光稳定性和器件寿命。
• ORGANOMETALLIC COMPLEX AND APPLICATION THEREOF IN ELECTRONIC DEVICES
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20190241590A1

  公开（公告）日：2019-08-08

  Disclosed are an organometallic complex comprising a new six-membered N-heterocyclic ligand, and an application thereof in an organic electronic device, especially in a phosphorescent organic light-emitting diode. The present invention further relates to an organic electronic device comprising the organometallic complex according to the present invention, especially an organic light-emitting diode, and an application thereof in display and illumination technology. In the present invention, the device structure is optimized and the concentration of the metal complex in the substrate is changed, so that the device achieves the optimal performance, and an OLED device having high efficiency, high luminance and high stability is achieved, thereby providing a better choice of materials for full-colour display and illumination application.

  揭示了一种含有新的六元N-杂环配体的有机金属络合物，以及其在有机电子器件中的应用，特别是在磷光有机发光二极管中的应用。本发明还涉及一种含有根据本发明的有机金属络合物的有机电子器件，特别是有机发光二极管，以及其在显示和照明技术中的应用。在本发明中，优化了器件结构并改变了基板中金属络合物的浓度，使得器件实现了最佳性能，并实现了具有高效率、高亮度和高稳定性的OLED器件，从而为全彩显示和照明应用提供了更好的材料选择。
• NITROGEN-CONTAINING FUSED HETEROCYCLIC RING COMPOUND AND APPLICATION THEREOF
  申请人：GUANGZHOU CHINAPAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20200223857A1

  公开（公告）日：2020-07-16

  The present invention relates to a nitrogen-containing fused heterocyclic ring compound and application thereof. The compound has the structural formula (I): using the described compound, it is possible to fabricate a device having higher stability and a longer service life.

  本发明涉及一种含氮融合杂环环化合物及其应用。该化合物具有结构式（I）：利用所述化合物，可以制造具有更高稳定性和更长寿命的设备。
• SPIROCYCLIC DERIVATIVE, AND POLYMER, MIXTURE, FORMULATION AND ORGANIC ELECTRONIC DEVICE COMPRISING THE SAME
  申请人：GUANGZHOU CHINARAY OPTOELECTRONIC MATERIALS LTD.

  公开号：US20180354931A1

  公开（公告）日：2018-12-13

  Provided are a spirocyclic derivative, and a high polymer, a mixture, a composition and an organic electronic device containing same, wherein in the spirocyclic derivative, two spirocyclic units are directly or indirectly connected by a sp3 hybridized carbon atom, thus effectively adjusting the energy level of the compound, and being beneficial for improving the photoelectric performance of the compound and the stability of the device. An effective solution is provided for effectively reducing the manufacturing cost and improving the efficiency and lifetime of a light-emitting device.

  提供了一个螺环衍生物，以及包含该衍生物的高分子、混合物、组合物和有机电子器件，其中在螺环衍生物中，两个螺环单元直接或间接地通过一个sp3杂化碳原子连接，从而有效地调节化合物的能级，有利于提高化合物的光电性能和器件的稳定性。有效地提供了一种解决方案，可以有效地降低制造成本，提高发光器件的效率和寿命。