uranyl selenate | 65508-00-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: uranyl selenate
• CAS: 65508-00-1
• 化学式: O₂U*O₄Se
• 分子量: 412.985
• InChiKey: IXCTWEIICUBSKL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -3.23
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  114.4
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  uranyl selenate 在 urea 作用下， 以 水 为溶剂， 生成
  参考文献：
  名称：

  Soldatkina, M. A.; Serezhkina, L. B.; Serezhkin, V. N., Russian Journal of Inorganic Chemistry, 1982, vol. 27, p. 995 - 997

  摘要：

  DOI：
• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 rubidium selenate 、 uranyl selenate 、 uranium(VI) trioxide
  参考文献：
  名称：

  Kuchumova, N. V.; Shtokova, I. P.; Serezhkina, L. B., Russian Journal of Inorganic Chemistry, 1989, vol. 34, p. 577 - 579

  摘要：

  DOI：

文献信息

• An X-ray diffraction study of Rb[UO2(SeO4)F]·H2O
  作者：L. B. Serezhkina、A. V. Vologzhanina、A. G. Verevkin、V. N. Serezhkin

  DOI：10.1134/s1066362211040023

  日期：2011.8

  An X-ray diffraction study of Rb[UO2(SeO4)F]center dot H2O (I) was performed. The compound crystallizes in the rhombic system with the following unit cell parameters: a = 8.4753(6), b = 13.5234(9), c = 13.5296(9) angstrom, space group Pnma, Z = 8, V = 1550.7(2) angstrom(3); R = 0.0248. The principal structural units of crystals of I are [UO2(SeO4)F](-) layers belonging to crystal-chemical group AT(3)M(2) (A = UO22+, T-3 = SeO42-, M-2 = F-) of uranyl complexes. The uranium-containing layered units are combined via electrostatic interaction with Rb cations and via a system of hydrogen bonds involving outer-sphere water molecules.
• Mit'kovskaya; Demchenko; Mikhailov, Russian Journal of Inorganic Chemistry, 2002, vol. 47, # 9, p. 1306 - 1310
  作者：Mit'kovskaya、Demchenko、Mikhailov、Gorbunova、Serezhkina、Serezhkin

  DOI：——

  日期：——
• Serezhkina, L. B.; Bakhmet'eva, L. M.; Serezhkin, V. N., Radiokhimiya, 1990, vol. 32, p. 432 - 436
  作者：Serezhkina, L. B.、Bakhmet'eva, L. M.、Serezhkin, V. N.

  DOI：——

  日期：——
• Synthesis and structure of M[UO2(C2O4)(NCS)] · 0.5H2O (M = Rb or Cs)
  作者：I. V. Medrish、E. V. Peresypkina、A. V. Virovets、L. B. Serezhkina

  DOI：10.1134/s0036023608070115

  日期：2008.7

  Single crystals of M[UO2(C2O4)(NCS)] center dot 0.5H(2)O (M = Rb (I) or Cs (II)) have been synthesized and studied by X-ray diffraction analysis. The compounds are isostructural, and their crystals are monoclinic with the space group C2/c, Z = 4, and unit cell parameters: a = 9.0624(5) angstrom, b = 13.1242(7) angstrom, c = 8.9204(5) angstrom, beta = 98.897(2)angstrom, R = 0.0226 (I); a = 9.3171(3) angstrom, b = 13.2987(5) angstrom, c = 9.1151(3) angstrom, beta = 101.0860(10)angstrom, R = 0.0214 (II). The main structural units of the crystals of I and II are the [[UO2(C2O4)(NCS)](-) chain belonging to the crystal-chemical group AK(02) M-1 (A = UO2 (2+,) K-02 = C2O42-, M-1 = NCS- of the uranyl complexes. The uranium-containing chains are joined into a three-dimensional framework through electrostatic interactions with the outer-sphere cations and hydrogen bonds involving the water molecules.
• Soldatkina, M. A.; Serezhkina, L. B.; Serezhkin, V. N., Russian Journal of Inorganic Chemistry, 1983, vol. 28, p. 709 - 711
  作者：Soldatkina, M. A.、Serezhkina, L. B.、Serezhkin, V. N.

  DOI：——

  日期：——