3,3'-(1,4-phenylene)bis(1-phenylpropane-1,3-dione) | 7488-30-4

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 3,3'-(1,4-phenylene)bis(1-phenylpropane-1,3-dione)
• 英文别名: 1,4-bis-(3-oxo-3-phenyl-propionyl)-benzene；1,4-Bis-(3-oxo-3-phenyl-propionyl)-benzol；1,3-Propanedione, 1,1'-(1,4-phenylene)bis[3-phenyl-；1-[4-(3-oxo-3-phenylpropanoyl)phenyl]-3-phenylpropane-1,3-dione
• CAS: 7488-30-4
• 化学式: C₂₄H₁₈O₄
• 分子量: 370.405
• InChiKey: AHMOUNNBSBYDFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  28
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  68.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,3'-(1,4-phenylene)bis(1-phenylpropane-1,3-dione) 在 一水合肼 作用下， 以 乙醇 为溶剂， 反应 3.0h， 以38%的产率得到3-phenyl-5-[4-(3-phenylpyrazol-5-yl)phenyl]pyrazole
  参考文献：
  名称：

  由芳基-和二甲苯基-连接的双（β-二酮）前体合成的新型双-吡唑衍生物

  摘要：

  摘要报道了六种新的芳基连接的双吡唑的合成和表征，其中一种是二甲苯基连接的双吡唑。还介绍了其中两种衍生物的 X 射线结构。

  DOI：

  10.1080/00397910500446845
• 作为产物：
  描述：

  对苯二甲酸二甲酯 、 苯乙酮 在 sodium amide 作用下， 生成 3,3'-(1,4-phenylene)bis(1-phenylpropane-1,3-dione)
  参考文献：
  名称：

  Bis-(β-Diketones). I. Synthesis of Compounds of the Type RCOCH₂CO-Y-COCH₂COR^1,2

  摘要：

  DOI：

  10.1021/ja01551a032

文献信息

• Dioxaborines as organic n-semiconductors, process for the production of semiconductors utilizing dioxaborines, and semiconductor component, field effect transistor, and diode having a dioxaborine
  申请人：Halik Marcus

  公开号：US20070179299A1

  公开（公告）日：2007-08-02

  Dioxaborines as organic n-semiconductors, a process for the production of semiconductors utilizing dioxaborines, and a semiconductor component, a field effect transistor, and a diode having a dioxaborine are provided. Dioxaborines have a conjugated π-system that carries two terminal six-membered dioxaborine heterocycles that are electronically linked to one another via the central π-system. The compounds have good electron mobility and very good reversibility of redox behavior and are therefore suitable as organic semiconductors in electronic semiconductor components. Processes for manufacturing the electronic semiconductor components utilize the dioxabroines.

  Dioxaborines作为有机n-半导体，提供了利用dioxaborines生产半导体的过程，以及具有dioxaborine的半导体组件、场效应晶体管和二极管。Dioxaborines具有一个共轭π-系统，其中携带两个末端的六元dioxaborine杂环，通过中心π-系统电子连接在一起。这些化合物具有良好的电子迁移率和非常好的氧化还原行为可逆性，因此适用于电子半导体组件中的有机半导体。制造电子半导体组件的过程利用了dioxabroines。
• Photographic recording material containing novel coordination polymer
  申请人：Fuji Photo Film Co., Ltd.

  公开号：US04506001A1

  公开（公告）日：1985-03-19

  A photographic recording material is disclosed. The material is comprised of a transparent support base and a number of layers positioned on that base. A dye ligand or a dye ligand-forming substance is positioned on the base and is associated with a light-sensitive silver halide emulsion. In addition, the material contains a mordant layer, an alkaline processing composition, and a means for releasing the composition throughout the photographic recording material in an integrated manner or as a different system. The mordant layer contains a coordination polymer composed of a ligand represented by a general formula (I) defined within the application and a metal ion. The invention makes it possible to immobilize a metal ion using inexpensive, easily available metal-chelatable ligands.

  本发明公开了一种摄影记录材料。该材料由透明支撑基底和若干层位于基底上的材料组成。染料配体或染料配体形成物质位于基底上，并与光敏银卤化物乳剂相关联。此外，该材料包含一层螯合剂，一种碱性处理组合物和一种释放组合物的手段，以整合方式或不同系统的形式在整个摄影记录材料中释放组合物。螯合剂层包含由申请中定义的通式（I）表示的配体和金属离子组成的配位聚合物。本发明使得使用廉价易得的金属螯合配体可以固定金属离子成为可能。
• Intramolecular Magnetic Interaction of Phenylene-Linked Bis-β-diketone Metal Complexes
  作者：Michio M. Matsushita、Tomohiro Yasuda、Ryuji Kawano、Tadashi Kawai、Tomokazu Iyoda

  DOI：10.1246/cl.2000.812

  日期：2000.7

  Dinuclear metal complexes of phenylene-linked bis-β-di-ketone ligands were prepared and the magnetic interactions between the complex units along the π-conjugated linkers were investigated. Both ferro- and antiferromagnetic interactions were observed for the m- and p-phenylene-linked dimers, respectively.

  制备了苯基连接的双-β-二酮配体的二核金属配合物，并研究了沿着π-共轭连接子的配合单元之间的磁相互作用。分别观察到m-和p-苯基连接二聚体的铁磁和反铁磁相互作用。
• Stabilized Polyvinylhalide resin
  申请人：PHOENIX CHEMICAL CORPORATION

  公开号：EP0046161A2

  公开（公告）日：1982-02-24

  1,3-Dicarbonyl compounds are provided having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COORl, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; one R1 and R2 may be linked together as an alkylene group to form a cyclic or ring structure; n is number from 1 to 3; and Z is a polyvalent linking radical selected from the group consisting of a direct linkage between the groups; polyvalent hydrocarbon R3; wherein: R3 is a polyvalent hydrocarbon group having from one to about eighteen carbon atoms; R4 and Rs are selected from the group consisting of hydrogen and hydrocarbon groups having from one to about eighteen carbon atoms; and R4 and R5 may be linked together as an alkylene to form a cyclic or ring structure; X is -O- od -S-; m is 0 or 1; and R6 is selected from the group consisting of hydrogen, hydrocarbon having from one to about eighteen carbon atoms, and -R3-; as well as metal and organotin enolate salts thereof. The compounds are effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.

  1,3-二羰基化合物的化学式如下 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COORl、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的此类基团组成的组，以及 R2 选自具有 1 至约 18 个碳原子的烃组成的组，以及被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基组成的组取代的此类基团； 一个 R1 和 R2 可作为亚烷基连接在一起，形成环状或环状结构； n 为 1 至 3；以及 Z 是多价连接基，选自由基团之间的直接连接、多价烃基 R3 组成的组； 其中 R3 是具有 1 至约 18 个碳原子的多价烃基； R4 和 Rs 选自氢和具有 1 至约 18 个碳原子的烃基；R4 和 R5 可作为亚烷基连接在一起，形成环状或环状结构； X 是-O- od -S- ； m 是 0 或 1；以及 R6选自由氢、具有一至十八个碳原子的烃和-R3-组成的组，以及它们的金属盐和有机锡烯醇盐。 这些化合物可有效提高聚乙烯卤化树脂的耐热和耐光劣化性能。
• Synthesis and X-ray structural analysis of an acyclic bifunctional vicinal triketone, its hydrate, and its ethanol-adduct
  作者：Morio Yonekawa、Yoshio Furusho、Yoshihisa Sei、Toshikazu Takata、Takeshi Endo

  DOI：10.1016/j.tet.2013.03.065

  日期：2013.5

  We have synthesized and fully characterized an acyclic bifunctional vicinal tricarbonyl compound, its hydrate, and its ethanol-adduct, which could be converted to one another by utilizing the reversible addition-elimination of water or ethanol. X-ray single crystal study revealed that the bistriketone expanded and contracted by 10-30% in length during the interconversion. (C) 2013 Elsevier Ltd. All rights reserved.