8-Methyl-benzo[b]naphtho[2,1-d]furan

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并呋喃类
• 英文名称: 8-Methyl-benzo[b]naphtho[2,1-d]furan
• 英文别名: 8-Methylnaphtho[1,2-b][1]benzofuran
• 化学式: C₁₇H₁₂O
• 分子量: 232.282
• InChiKey: LRJGUXGKHWHHQQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  18
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  13.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  乙酸对甲酚酯 在 aluminum (III) chloride 、 溴 、 sodium carbonate 、 potassium carbonate 、 三乙胺 作用下， 以 乙醚 、 水 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 22.0h， 生成 8-Methyl-benzo[b]naphtho[2,1-d]furan 、 10-Methyl-benzo[b]naphtho[1,2-d]furan
  参考文献：
  名称：

  产生苯并吡喃酮和苯并呋喃的新气相多米诺工艺

  摘要：

  一种通过气相热解含有 2-甲氧基苯基的 β,γ-二氧磷叶立德来制备黄酮的新多米诺骨牌方法因中间体黄酮-3-基自由基的意外和新颖的脱羰反应而受挫，导致 2-苯基苯并呋喃。基于二氧戊环保护一个羰基或选择性消除 β,β'-二氧代或 β-氧代-β'-硫代叶立德的替代方法并不成功，但 β-氧代-β'-苯基亚氨基叶立德的热解确实给出了所需的多米诺骨牌反应导致中等收率的受保护的苯并吡喃酮。

  DOI：

  10.3987/com-15-s(t)14

文献信息

• HETEROCYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20180019406A1

  公开（公告）日：2018-01-18

  A heterocyclic compound is represented by Formula 1: wherein, in Formula 1, R 1 ro R 4 , R 11 , ring A 1 , L 1 , Ar 1 , c11, a1, and b1 are as defined in the specification.

  一个杂环化合物由Formula 1表示：其中，在Formula 1中，R1至R4，R11，环A1，L1，Ar1，c11，a1和b1的定义如规范中所述。
• CONDENSED CYCLIC COMPOUND AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20180083196A1

  公开（公告）日：2018-03-22

  A condensed cyclic compound and an organic light-emitting device including the same, the condensed cyclic compound being represented by Formula 1:

  一种紧凑的环状化合物以及包括该化合物的有机发光器件，所述紧凑的环状化合物由公式1表示：
• Organic Compound, Light-Emitting Device, Light-Emitting Apparatus, Electronic Device, Display Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20210139445A1

  公开（公告）日：2021-05-13

  A novel organic compound is provided. Alternatively, an organic compound that exhibits light emission with favorable chromaticity is provided. Alternatively, an organic compound that exhibits blue light emission with favorable chromaticity is provided. Alternatively, a light-emitting device with favorable emission efficiency is provided. Alternatively, an organic compound having a high carrier-transport property is provided. Alternatively, an organic compound with favorable reliability is provided. An organic compound having at least one amino group in which any one of a substituted or unsubstituted dibenzofuranyl group, a substituted or unsubstituted dibenzothiophenyl group, and a substituted or unsubstituted carbazolyl group is bonded to any one of a substituted or unsubstituted naphthobisbenzofuran skeleton, a substituted or unsubstituted naphthobisbenzothiophene skeleton, and a substituted or unsubstituted naphthobenzothienobenzofuran skeleton is provided.

  提供了一种新型有机化合物。或者提供一种表现出有利色度的光发射的有机化合物。或者提供一种表现出有利色度的蓝光发射的有机化合物。或者提供一种具有良好发射效率的发光装置。或者提供一种具有高载流子传输性能的有机化合物。或者提供一种具有良好可靠性的有机化合物。提供了一种有机化合物，其中任何一种取代或未取代的二苯并呋喃基团，取代或未取代的二苯并噻吩基团和取代或未取代的咔唑基团中的至少一个氨基与取代或未取代的萘并苯并呋喃骨架、取代或未取代的萘并苯并噻吩骨架和取代或未取代的萘苯并噻吩苯并呋喃骨架中的任何一个键合。
• [EN] ORGANIC ELECTROLUMINESCENT COMPOUND AND ORGANIC ELECTROLUMINESCENT DEVICE COMPRISING THE SAME<br/>[FR] COMPOSÉ ÉLECTROLUMINESCENT ORGANIQUE ET DISPOSITIF ÉLECTROLUMINESCENT ORGANIQUE LE COMPRENANT
  申请人：ROHM & HAAS ELECT MATERIALS KOREA LTD

  公开号：WO2020032574A1

  公开（公告）日：2020-02-13

  The present disclosure relates to an organic electroluminescent compound represented by formula 1 and an organic electroluminescent device comprising the same. By comprising the organic electroluminescent compound of the present disclosure, an organic electroluminescent device having improved driving voltage, luminous efficiency, and/or lifespan characteristics can be provided.

  本公开涉及一种由式1表示的有机电致发光化合物和包含其的有机电致发光器件。通过包含本公开的有机电致发光化合物，可以提供具有改善驱动电压、发光效率和/或寿命特性的有机电致发光器件。
• AROMATIC AMINE DERIVATIVE AND ORGANIC ELECTROLUMINESCENT DEVICE USING THE SAME
  申请人：Idemitsu Kosan Co., Ltd.

  公开号：EP2295421A1

  公开（公告）日：2011-03-16

  An aromatic amine derivative having a specific structure. An organic electroluminescence device which is composed of one or more organic thin film layers sandwiched between a cathode and an anode, wherein at least one of the organic thin film layers especially a hole transporting layer, contains the aromatic amine derivative. The aromatic amine derivative has at least one substituted or unsubstituted dibenzofuran skeleton and at least one substituted or unsubstituted terphenylene skeleton. Because the molecules in the aromatic amine derivative hardly crystallize, organic electroluminescence devices improving their production yield and having prolonged lifetime are provided.

  具有特定结构的芳香胺衍生物。一种有机电致发光器件，由夹在阴极和阳极之间的一个或多个有机薄膜层组成，其中至少一个有机薄膜层，特别是空穴传输层，含有芳香族胺衍生物。芳香胺衍生物至少有一个取代或未取代的二苯并呋喃骨架和至少一个取代或未取代的三联苯骨架。由于芳香胺衍生物中的分子几乎不会结晶，因此可以提供提高产量和延长使用寿命的有机电致发光器件。