2-(1,1-Dimethyl-prop-2-ynylperoxy)-2-methyl-pentane | 98406-40-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(1,1-Dimethyl-prop-2-ynylperoxy)-2-methyl-pentane
• 英文别名: 2-Methyl-2-[(2-methylbut-3-yn-2-yl)peroxy]pentane；2-methyl-2-(2-methylbut-3-yn-2-ylperoxy)pentane
• CAS: 98406-40-7
• 化学式: C₁₁H₂₀O₂
• 分子量: 184.279
• InChiKey: NNQFSYHMPOCVEA-UHFFFAOYSA-N

物化性质

• 沸点：
  58-59 °C(Press: 15 Torr)
• 密度：
  0.8538 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(1,1-Dimethyl-prop-2-ynylperoxy)-2-methyl-pentane 在 正丁基锂 作用下， 以 乙醚 、 正己烷 为溶剂， 反应 38.5h， 生成 2,9-dimethyl-2-(2-methyl-2-pentylperoxy)-5-methylene-11-(2,6,6-trimethylcyclohex-1-enyl)undeca-6,8-dien-3-yne
  参考文献：
  名称：

  摘要：

  A method was developed for preparation of alkynyl peroxides from terpene and steroid aldehydes and ketones by reaction of lithium peroxyacetylides with the corresponding aldehydes and ketones followed by treating the intermediate lithium alcoholates with acyl chlorides.

  DOI：

  10.1023/a:1013175911137
• 作为产物：
  描述：

  3-methyl-3-hydroperoxy-1-butyne 、 2-甲基-2-戊醇 、 硫酸 以81%的产率得到
  参考文献：
  名称：

  YUVCHENKO, A. P.;MOJSEJCHUK, K. L.;DIKUSAR, E. A.;OLDEKOP, YU. A., VESTSI. AN BSSR. CEP. XIM. N., 1985, N 2, 65-70

  摘要：

  DOI：

文献信息

• Polymerization of styrene initiated by acetylenic peroxides
  作者：S. G. Stepin、E. A. Dikusar

  DOI：10.1134/s1070427209010248

  日期：2009.1

  The initiating activity of acetylenic peroxides in polymerization of styrene was studied. The kinetic parameters of the polymerization and its initiation were calculated. The effect exerted by the structure of radicals on the initiating activity of peroxides was evaluated.

  研究了炔属过氧化物在苯乙烯聚合反应中的引发活性。计算了聚合反应及其引发的动力学参数。评估了自由基的结构对过氧化物引发活性的影响。
• Acetylenic Peroxides Derived from 4,4'-Biphenyldicarboxylic Acids
  作者：A. P. Yuvchenko、E. A. Dikusar、V. K. Ol'khovik

  DOI：10.1023/b:rugc.0000015990.86981.1e

  日期：2003.9

  Lithium peroxyacetylides were reacted with Paraform to obtain lithium peroxyalcoholates. The latter react with 4,4'-biphenyldicarboxylic and 2,2'-sulfonyl-4,4'-biphenyldicarboxylic dichlorides, yielding peroxy-contaming esters. Lithium peroxyacetylides react with 4,4'-biphenyldicarboxylic and 2-methoxy- and ;2.2'-sulfonyl-4,4'-biphenyldicarboxylic acids to form acetylenic biphenyldihydroxytetraperoxides.
• Dikusar; Shirokii; Yuvchenko, Russian Journal of General Chemistry, 1999, vol. 69, # 8, p. 1266 - 1272
  作者：Dikusar、Shirokii、Yuvchenko、Bazhanov、Moiseichuk、Khrustalev、Antipin

  DOI：——

  日期：——
• Dikusar; Yuvchenko; Zhukovskaya, Russian Journal of General Chemistry, 1997, vol. 67, # 9, p. 1463 - 1466
  作者：Dikusar、Yuvchenko、Zhukovskaya、Murashko、Moiseichuk

  DOI：——

  日期：——
• Peroxy-containing Tertiary Acetylenic Alcohols Derived from Cycloheptanone, Cyclododecanone, and (-)-R-Carvone
  作者：E. A. Dikusar、N. G. Kozlov、V. M. Zelenkovskii、N. A. Zhukovskaya、V. L. Murashko、E. G. Zalesskaya、K. L. Moiseichuk、A. P. Yuvchenko

  DOI：10.1023/b:rugc.0000007657.56215.a3

  日期：2003.8

  A series of peroxy-containing tertiary acetylenic alcohols were obtained by reactions of lithium peroxyacetylides with cycloheptanone, cyclododecanone, and (-)-R-carvone. Thermal stability of the products was estimated by thermal analysis and quantum-chemical calculations.