(3aR^*,4S^*,7R^*,7aS^*)-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene | 2826-19-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 多环烃
• 英文名称: (3aR^*,4S^*,7R^*,7aS^*)-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene
• 英文别名: endo-tricyclo<5.2.1.0^2,6>dec-8-ene；1H,2H-dicyclopentadiene；(3ac,7ac)-2,3,3a,4,7,7a-hexahydro-4r,7-methano-indene；(3ac,7ac)-2,3,3a,4,7,7a-Hexahydro-4r,7-methano-inden；(3arH.7acH)-3a.4.7.7a-Tetrahydro-4c.7c-methano-indan；endo-tricyclo(5.2.1.0^2,6)dec-8-ene；4,7-Methano-1H-indene, 2,3,3a,4,7,7a-hexahydro-, (3aR,4S,7R,7aS)-rel-；(1R,2S,6R,7S)-tricyclo[5.2.1.02,6]dec-8-ene
• CAS: 2826-19-9
• 化学式: C₁₀H₁₄
• 分子量: 134.221
• InChiKey: WHNYVDJJCTVMGO-YNFQOJQRSA-N

物化性质

• 沸点：
  90-92 °C(Press: 40 Torr)
• 密度：
  1.011±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  (3aR^*,4S^*,7R^*,7aS^*)-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene 在 磷酸 作用下， 生成 exo-tricyclo[5.2.1.0^2.6]dec-3-ene
  参考文献：
  名称：

  1,2-Dihydro-endo-dicyclopentadiene¹

  摘要：

  DOI：

  10.1021/ja01512a037
• 作为产物：
  描述：

  二聚环戊二烯 在 palladium on activated charcoal potassium tert-butylate 、 氢溴酸 、 氢气 作用下， 以 四氢呋喃 、 叔丁醇 为溶剂， 反应 24.0h， 生成 (3aR^*,4S^*,7R^*,7aS^*)-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene
  参考文献：
  名称：

  Fused and bridged tetracyclic C13 and C14 adamantanes. Synthesis of methyl-2,4-ethano-, 1,2-trimethylene-, 2,4-trimethylene-, and 1,2-tetramethyleneadamantane

  摘要：

  DOI：

  10.1021/jo00349a019

文献信息

• Ethnopsychological Method and the Psychological Assessment of Mexican Americans
  作者：Guadalupe Gutierrez

  DOI：10.1177/0739986302024003001

  日期：2002.8

  This article reviews the theoretical and methodological development of ethnopsychology, which is founded on the principle that distinct cultural groups share basic common beliefs and values that differentiate them psychologically from other cultural groups. The distinctness of a cultural group is rooted in a series of historical, sociocultural experiences and perceptions of oneself and the group as a whole. The development of ethnopsychology is summarized through the contributions of Rogelio Diaz-Guerrero and his early exploration of the fundamental premises and tenets that guide ethnopsychological theory and method. The contributions of other theorists, focusing on the uniqueness of bicultural/bilingual groups such as Mexican Americans, are also summarized. The author supports the application of ethnopsychological theory and method to enhance psychologists’ understanding of bilingual/bicultural groups in the United States. Specifically, she reviews current psychological assessment methods and their ethnopsychological adaptation for Mexican Americans.

  本文回顾了民族心理学的理论和方法论发展，该学科基于这样一个原则：不同文化群体共享基本的共同信仰和价值观，这些共同点在心理上将他们与其他文化群体区分开来。文化群体的独特性根植于一系列历史、社会文化经验以及个人和整个群体对自己的认知。民族心理学的发展通过Rogelio Diaz-Guerrero的贡献进行了总结，他早期探索了指导民族心理学理论和方法的基本前提和原则。还总结了其他理论家的贡献，重点关注了墨西哥裔美国人等双文化/双语群体的独特性。作者支持将民族心理学理论和方法应用于增进心理学家对美国双文化/双语群体的理解。具体来说，她回顾了当前的心理评估方法及其在墨西哥裔美国人中的民族心理学适应性。
• Linearly fused vs bridged regioselection in the intramolecular 1,3-diyl trapping reaction
  作者：Mohammad R. Masjedizadeh、Ingeborg Dannecker-Doerig、R. Daniel Little

  DOI：10.1021/jo00296a035

  日期：1990.4
• Regioselective Semihydrogenation of Dienes
  作者：Thomas J. A. Graham、Thomas H. Poole、Charles N. Reese、Brian C. Goess

  DOI：10.1021/jo200262r

  日期：2011.5.20

  A one-pot, three-step strategy for the regioselective semihydrogenation of dienes is described. This procedure uses 9-BBN-H as a temporary protective group for alkenes. Yields range from 55% to 95%, and the reaction is tolerant of a variety of common functional groups. Additionally, the final elimination step of the sequence can be replaced with a peroxide-mediated alkylborane oxidation, generating regioselectively semihydrogenated product alcohols.
• <b>Bridged Polycyclic Compounds. XIX. Some Addition and Solvolysis Reactions in Norbornane Systems</b>
  作者：Stanley J. Cristol、Wolfgang K. Seifert、Donald W. Johnson、J. Byrne. Jurale

  DOI：10.1021/ja00879a023

  日期：1962.10
• Bridged Polycyclic Compounds. X. The Synthesis of endo and exo-1,2-Dihydrodicyclopentadienes and Related Compounds¹
  作者：Stanley J. Cristol、Wolfgang K. Seifert、S. Barney Soloway

  DOI：10.1021/ja01494a060

  日期：1960.5