bis(diethylamido)-dichloridozirconium(lV)-bis(tetrahydrofurane) | 173862-78-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧唑烯
• 英文名称: bis(diethylamido)-dichloridozirconium(lV)-bis(tetrahydrofurane)
• 英文别名: dichlorobis(diethylamido)bis(tetrahydrofuran)zirconium；(Et2N)2ZrCl2(tetrahydrofuran)2 complex；dichlorobis(diethylamido)zirconium tetrahydrofuran complex；Zr(NEt2)2Cl2(tetrahydrofuran)2；Zr(NEt2)2Cl2(THF)2；ZrCl2(NEt2)(THF)2；dichlorozirconium(2+);diethylazanide;oxolane
• CAS: 173862-78-7
• 化学式: C₁₆H₃₆Cl₂N₂O₂Zr
• 分子量: 450.604
• InChiKey: QQHOXXXZTHRHNU-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  5.77
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.5
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bis(diethylamido)-dichloridozirconium(lV)-bis(tetrahydrofurane) 、 以 not given 为溶剂， 以66%的产率得到bis(diethylamido)[η5-1-[(tert-butylamido)methyl]-2,3,4,5-tetramethylcyclopentadienyl-κN]zirconium
  参考文献：
  名称：

  生成均相（sp（3）-C（1））-桥联的Cp /酰胺基和Cp /磷基4金属齐格勒-纳塔催化剂体系。

  摘要：

  DOI：

  10.1021/ja0029634
• 作为产物：
  描述：

  氯化锆(IV) 、 Zr(NEt2)4 以 四氢呋喃 、 乙醚 为溶剂， 以88%的产率得到bis(diethylamido)-dichloridozirconium(lV)-bis(tetrahydrofurane)
  参考文献：
  名称：

  Brenner, Simon; Kempe, Rhett; Arndt, Perdita, Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：

文献信息

• (Alkyliminomethyl)phenylamido and related complexes of zirconium and titanium
  作者：Robin M. Porter、Scott Winston、Andreas A. Danopoulos、Michael B. Hursthouse

  DOI：10.1039/b202471c

  日期：——

  A range of trialkylsilylamido complexes of zirconium in which the silylamido functional group is attached to an o-(alkyliminomethyl)- or an o-(alkyliminoethyl)-substituted aromatic ring have been synthesised by salt elimination or aminolysis reactions and characterised by spectroscopic and diffraction methods. The monoanionic ligands (L), formally isoelectronic to the cyclopentadienyl ligand, can be introduced to zirconium by reaction of LLi with ZrCl4 under a variety of conditions giving rise to complexes of type LZrCl3 and L2ZrCl2, by reaction of LLi with Zr(NMe2)2Cl2(THF)2, and Zr(NEt2)2Cl2(THF)2 giving rise to LZrCl(NMe2)2Cl and LZrCl(NEt2)2Cl, respectively, or by reaction of LH with Zr(NMe2)4 giving rise to LZr(NMe2)3. LZr(NMe2)2Cl and LZr(NEt2)2Cl can be transformed to LZrCl3 by reaction with Me3SiCl, while LZr(NMe2)3 on heating rearranges to dimeric imido complexes by elimination of amidosilanes. Aminolysis of Zr(NMe2)2Cl2(THF)2 with LH results in a formal insertion of the imino CN into the Zr-amido bond. The combination of enolisable imine and a bulky silyl amide gave rise to a new mixed donor ligand system comprising of one silylamido and one eneamido group. Finally aminolysis of Ti(NMe2)Cl2 with LH resulted in the isolation of a C3 symmetric triamido titanium complex.

  已合成一系列三烷基硅氨基锆配合物，其中硅氨基官能团连接到o-(烷基亚氨基甲基)或o-(烷基亚氨基乙基)取代芳香环上，并通过盐消除或氨解反应进行表征，采用光谱和衍射方法进行分析。这些单负离子配体(L)形式上等电子于环戊二烯配体，可以通过在各种条件下将LLi与ZrCl4反应引入锆，生成LZrCl3和L2ZrCl2类型的配合物，或者通过将LLi与Zr(NMe2)2Cl2(THF)2及Zr(NEt2)2Cl2(THF)2反应，分别得到LZrCl(NMe2)2Cl和LZrCl(NEt2)2Cl，或通过将LH与Zr(NMe2)4反应生成LZr(NMe2)3。LZr(NMe2)2Cl和LZr(NEt2)2Cl可以通过与Me3SiCl反应转化为LZrCl3，而LZr(NMe2)3在加热时通过消除氨基硅烷重排为二聚亚胺配合物。将Zr(NMe2)2Cl2(THF)2与LH进行氨解反应会导致亚胺CN正式嵌入Zr-氨基键中。可酮化的亚胺与庞大的硅氨基的组合产生了一种新的混合供体配体系统，包含一个硅氨基和一个烯氨基。最后，将Ti(NMe2)Cl2与LH进行氨解反应，成功分离出了一种C3对称的三氨基钛配合物。
• o-(Cyclohexyliminoethyl)(arylamido)benzene and related complexes of zirconium and titanium. The non-innocence of the ketimino functionality
  作者：Robin M. Porter、Andreas A. Danopoulos

  DOI：10.1039/b404173a

  日期：——

  N-Arylamido complexes of zirconium in which the amido functional group is attached to an o-(alkyliminoethyl) substituted aromatic ring, have been synthesised by salt elimination reactions and characterised by spectroscopic and diffraction methods; they are analogous to the N-silylamido species recently reported (Dalton Trans., 2002, 3290–3299). The ligands 2-[CyNC(CH3)]C6H4N(H)(xyl), LxylH, and 2-[CyNC(CH3)]C6H4N(H)(mes) LmesH, Cy = C6H11, xyl = 3,5-Me2C6H3 mes = 2,4,6-Me3C6H2, were prepared in good yields by Buchwald–Hartwig amination of the arylbromides with 2-[CyNC(CH3)]C6H4NH2. Reaction of LmesLi with Zr(NEt2)2Cl2(thf)2 gave after chloride substitution the arylamido ketimino complex LmesZr(NEt2)2Cl 1; variable amounts of the arylamido vinylamido complex 2 were also obtained. Interaction of LmesLi or LxylLi with Ti(NMe2)2Cl2 gave rise to the tripodal bis-amido amino complexes 5 and 6 possibly formed by ligand rearrangement involving migration of the dimethylamido group to the ketimino carbon.

  通过消盐反应合成了锆的 N-芳酰胺配合物，其中的酰胺官能团连接到邻(烷基亚氨基乙基)取代的芳香环上，并通过光谱和衍射方法对其进行了表征；它们类似于最近报道的 N-硅酰胺种类（Dalton Trans.）配体 2-[CyNC(CH3)]C6H4N(H)(xyl)、LxylH 和 2-[CyNC(CH3)]C6H4N(H)(mes) LmesH（Cy = C6H11，xyl = 3,5-Me2C6H3 mes = 2,4,6-Me3C6H2）是通过芳溴化物与 2-[CyNC(CH3)]C6H4NH2 的 Buchwald-Hartwig 酰胺化反应制备的，产率良好。将 LmesLi 与 Zr(NEt2)2Cl2(thf)2 反应，在氯取代后得到芳酰胺基酮亚氨基络合物 LmesZr(NEt2)2Cl 1；还得到了不同数量的芳酰胺基乙烯基氨基络合物 2。LmesLi 或 LxylLi 与 Ti(NMe2)2Cl2 相互作用产生了三元双氨基络合物 5 和 6，这可能是通过配体重排涉及二甲基氨基迁移到酮亚氨基碳而形成的。
• Method and system for forming a precursor compound for non-bridged unsymmetric polyolefin polymerization catalyst
  申请人：Chevron Phillips Chemical Company LP

  公开号：US08013177B2

  公开（公告）日：2011-09-06

  The present techniques relates generally to polyolefin catalysts and, more specifically, to preparing a precursor compound for an unsymmetric metallocene catalyst, for using the precursor compound to prepare catalysts, and for employing the precursor compounds to prepare catalysts for polyolefin polymerizations.

  这些技术通常与聚烯烃催化剂有关，更具体地说，涉及制备非对称茂金属催化剂的前体化合物，利用前体化合物制备催化剂，并利用前体化合物制备聚烯烃聚合物催化剂。
• STEREOSELECTIVE SYNTHESIS OF BRIDGED METALLOCENE COMPLEXES
  申请人：Buck Richard M.

  公开号：US20120088924A1

  公开（公告）日：2012-04-12

  The present invention provides methods of making stereo-enriched ansa-metallocene compounds using an unchelated amine compound. Generally, these methods result in a rac:meso isomer selectivity of the stereo-enriched ansa-metallocene compound of greater than 4:1.

  本发明提供使用未配位胺化合物制备立体富集的ansa-金属茂化合物的方法。通常，这些方法会导致立体富集的ansa-金属茂化合物的rac:meso异构体选择性大于4:1。
• [EN] PROCESS FOR THE OLIGOMERISATION OF OLEFINS BY COORDINATIVE CHAIN TRANSFER POLYMERISATION<br/>[FR] PROCÉDÉ D'OLIGOMÉRISATION D'OLÉFINES PAR POLYMÉRISATION PAR TRANSFERT DE CHAÎNE ET COORDINATION
  申请人：SASOL PERFORMANCE CHEMICALS GMBH

  公开号：WO2016180538A1

  公开（公告）日：2016-11-17

  The present invention relates to a process for the oligomerisation of olefins, in particular ethylene, via coordinative chain transfer polymerisation (CCTP) and alkyl elimation reaction. A preferred embodiment of the invention relates to CCTP of olefins, in particular ethylene, with the use of guanidinato, amidinato or hydrocarbyl -2- pyridyl amine complexes of titanium, zirconium or lanthanides, a nickel or cobalt compound as chain displacement catalyst (CDC) and one or more chain shuttling agents (CSA) such as a main group metal alkyl.

  本发明涉及一种通过协同链转移聚合（CCTP）和烷基消除反应进行烯烃寡聚的方法，特别是乙烯的寡聚。本发明的一种优选实施方式涉及使用钛、锆或镧系元素的鸟嘌呤铵、酰胺铵或羟基烷基-2-吡啶胺配合物，以及镍或钴化合物作为链位移催化剂（CDC），并使用一个或多个链穿梭剂（CSA），例如主族金属烷基进行烯烃CCTP，特别是乙烯CCTP。