5'-trimethylsilylfuran-2'-yloxoacetaldehyde | 17881-62-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5'-trimethylsilylfuran-2'-yloxoacetaldehyde
• 英文别名: (5-trimethylsilanyl-[2]furyl)-glyoxal；(5-Trimethylsilyl-[2]furyl)-glyoxal；2-oxo-2-(5-trimethylsilylfuran-2-yl)acetaldehyde
• CAS: 17881-62-8
• 化学式: C₉H₁₂O₃Si
• 分子量: 196.278
• InChiKey: XWINUYBYGNDDKN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.21
• 重原子数：
  13.0
• 可旋转键数：
  3.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  47.28
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  5'-trimethylsilylfuran-2'-yloxoacetaldehyde 在 sodium tetrahydroborate 作用下， 生成 2-(1,2-dihydroxyethyl)-5-trimethylsilylfuran
  参考文献：
  名称：

  Photocatalytic Degradation of 4-Chlorophenol. 1. The Hydroquinone Pathway

  摘要：

  Complete mineralization of 4-chlorophenol in water can be achieved by photocatalytic degradation of oxygenated solutions containing suspended TiO2. The chemical pathways of this degradation are complex, and in this paper, that which begins with hydroquinone is examined. Hydroxylation to form 1,2,4-benzenetriol is the first step, though a very small amount of cleavage of the C1-C2 bond is observed. The first major group of acyclic compounds derives from oxidative cleavage of either the C1-C2 or C3-C4 bond of 1,2,4-benzenetriol. It is argued that this results from single electron oxidation and capture by superoxide. Many smaller compounds have also been identified, and routes to various ones of them are proposed. Nearly all of the compounds are verified by use of authentic samples.

  DOI：

  10.1021/jo990820y
• 作为产物：
  描述：

  2-三甲基硅基呋喃 在 (CH₃CO)2O 、 I₂ 作用下， 以 not given 为溶剂， 生成 5'-trimethylsilylfuran-2'-yloxoacetaldehyde
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 30, page 94 - 96

  摘要：

  DOI：

文献信息

• The Oxidation of Organosilanes with Selenium Dioxide
  作者：Robert A. Benkeser、Herbert. Landesman

  DOI：10.1021/ja01175a074

  日期：1949.7