10,10'-bis[3,5-bis(trifluoromethyl)phenyl]-9,9'-bianthracene | 1505456-00-7

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 10,10'-bis[3,5-bis(trifluoromethyl)phenyl]-9,9'-bianthracene
• 英文别名: 9-[3,5-Bis(trifluoromethyl)phenyl]-10-[10-[3,5-bis(trifluoromethyl)phenyl]anthracen-9-yl]anthracene；9-[3,5-bis(trifluoromethyl)phenyl]-10-[10-[3,5-bis(trifluoromethyl)phenyl]anthracen-9-yl]anthracene
• CAS: 1505456-00-7
• 化学式: C₄₄H₂₂F₁₂
• 分子量: 778.64
• InChiKey: YZWROXJAUGASPI-UHFFFAOYSA-N

物化性质

• 沸点：
  631.1±55.0 °C(Predicted)
• 密度：
  1.400±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  15.3
• 重原子数：
  56
• 可旋转键数：
  3
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  蒽醌 在 盐酸 、 四(三苯基膦)钯 、 水 、 溴 、 potassium carbonate 、 溶剂黄146 、 锌 作用下， 以 四氢呋喃 、 1,2-二氯乙烷 为溶剂， 反应 24.0h， 生成 10,10'-bis[3,5-bis(trifluoromethyl)phenyl]-9,9'-bianthracene
  参考文献：
  名称：

  高效深蓝色有机电致发光器件（CIE ý掺杂有氟化9,9'-联蒽衍生物≈0.08）（荧光团）

  摘要：

  已经设计并合成了一系列新的氟化9,9'-联蒽衍生物（BAnFs），用作有机电致发光（EL）器件中的深蓝色掺杂剂。通过对吸电子基团的不同取代模式（例如F和CF 3），对这些BAnF的光物理性质，能级和热稳定性进行了调整，并通过对其几何形状和电子结构的密度泛函研究加以支持。在薄膜状态下，BAnFs的荧光发射在448 nm至439 nm范围内进行了微调，并在9,9'-联蒽核心上连接了不同的氟化苯环。所有的BAnF都显示出相当高的热稳定性，并具有较高的T g值，高于150°C。在纯蓝色发射委员会国际照明委员会（CIE）坐标（0.156，0.083），已经使用主机4,4'-双（实现Ñ掺杂有10,10'-咔唑基）联苯（CBP）双（3,5-双（三氟甲基）苯基）-9,9'-联蒽（BAn-（3,5）-CF 3）。掺杂BAn-（3,5）-CF 3的器件的最大电流效率和功率效率为3.05 cd A -1和2.62

  DOI：

  10.1039/c3tc31743a

文献信息

• ORGANIC ELECTROLUMINESCENCE ELEMENT
  申请人：Kyushu University, National University Corporation

  公开号：EP3843167A1

  公开（公告）日：2021-06-30

  An organic electroluminescent device having an anode, a cathode, and a light-emitting layer between the anode and the cathode, wherein the light-emitting layer contains at least a first organic compound, a second organic compound and a third organic compound satisfying the following formula (A), the second organic compound is a delayed fluorescent material, and the third organic compound is a light-emitting material, has a high light emission efficiency. Formula (A): ES1(A) > ES1(B) > ES1(C) wherein ES1(A), ES1(B) and ES1(C) each represent a lowest excited singlet energy level of the first organic compound, the second organic compound and the third organic compound, respectively.

  一种有机电致发光器件，具有阳极、阴极和位于阳极与阴极之间的发光层，其中发光层至少含有满足下式（A）的第一有机化合物、第二有机化合物和第三有机化合物，第二有机化合物是一种延迟荧光材料，第三有机化合物是一种发光材料，具有较高的发光效率。式（A）：ES1(A)>ES1(B)>ES1(C) 其中 ES1(A)、ES1(B) 和 ES1(C) 分别代表第一种有机化合物、第二种有机化合物和第三种有机化合物的最低激发单线能级。
• Luminescent film, organic electroluminescent element, organic material composition and method for producing organic electroluminescent element
  申请人：Konica Minolta, Inc.

  公开号：US11302882B2

  公开（公告）日：2022-04-12

  A luminescent film includes a host compound, a blue phosphorescent compound, and a blue fluorescent compound, in which an emission spectrum of the blue phosphorescent compound and an absorption spectrum of the blue fluorescent compound have portions overlapping with each other; shortest wavelength-side maximum emission wavelengths of the blue phosphorescent compound (abbreviated as “BPM” in the expression) and the blue fluorescent compound (abbreviated as “BFM” in the expression) satisfy the following expression (1): λBFM≥λBPM: expression (1) in which λBFM represents the shortest wavelength-side maximum emission wavelength of the blue fluorescent compound and λBPM represents the shortest wavelength-side maximum emission wavelength of the blue phosphorescent compound; and light emission derived from the blue fluorescent compound is detected.

  一种发光膜包括主化合物、蓝色磷光化合物和蓝色荧光化合物，其中蓝色磷光化合物的发射光谱和蓝色荧光化合物的吸收光谱具有重叠部分；蓝色磷光化合物和蓝色荧光化合物分别在短波长端的最高发射波长（分别简称为“BPM”和“BFM”）满足以下表达式（1）：λBFM≥λBPM；其中，λBFM代表蓝色荧光化合物的短波长端最高发射波长，λBPM代表蓝色磷光化合物的短波长端最高发射波长；并且检测到由蓝色荧光化合物发出的光。
• QUANTUM DOT ARCHITECTURES FOR FLUORESCENCE DONOR-ASSISTED OLED DEVICES
  申请人：Nanoco Technologies, Ltd.

  公开号：EP3762469A1

  公开（公告）日：2021-01-13
• ORGANIC ELECTROLUMINESCENT ELEMENT AND COMPOSITION FOR ORGANIC MATERIALS
  申请人：Konica Minolta, Inc.

  公开号：US20190319210A1

  公开（公告）日：2019-10-17

  The present invention addresses the problem of providing: an organic electroluminescent element which is capable of emitting light with high luminous efficiency, while having a long service life; and a composition for organic materials. An organic electroluminescent element according to the present invention comprises a positive electrode, a negative electrode and one or more organic functional layers arranged between the positive electrode and the negative electrode, and is characterized in that: the organic functional layers contain a phosphorescent metal complex and a fluorescent compound; the phosphorescent metal complex is a compound having a structure that is represented by a specific general formula; and the phosphorescent metal complex is a core-shell type dopant that satisfies a specific formula.
• LUMINESCENT FILM, ORGANIC ELECTROLUMINESCENT ELEMENT, ORGANIC MATERIAL COMPOSITION AND METHOD FOR PRODUCING ORGANIC ELECTROLUMINESCENT ELEMENT
  申请人：Konica Minolta, Inc.

  公开号：US20190280236A1

  公开（公告）日：2019-09-12

  A luminescent film includes a host compound, a blue phosphorescent compound, and a blue fluorescent compound, in which an emission spectrum of the blue phosphorescent compound and an absorption spectrum of the blue fluorescent compound have portions overlapping with each other; shortest wavelength-side maximum emission wavelengths of the blue phosphorescent compound (abbreviated as “BPM” in the expression) and the blue fluorescent compound (abbreviated as “BFM” in the expression) satisfy the following expression (1): λ BFM ≥λ BPM : expression (1) in which λ BFM represents the shortest wavelength-side maximum emission wavelength of the blue fluorescent compound and λ BPM represents the shortest wavelength-side maximum emission wavelength of the blue phosphorescent compound; and light emission derived from the blue fluorescent compound is detected.