1,2-bis-(2-ethoxy-ethylsulfanyl)-ethane | 14440-87-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,2-bis-(2-ethoxy-ethylsulfanyl)-ethane
• 英文别名: Aethylen-bis-(β-aethoxy-aethylsulfid)；1,2-Bis-(2-aethoxy-aethylmercapto)-aethan；3,12-Dioxa-6,9-dithiatetradecane；1-ethoxy-2-[2-(2-ethoxyethylsulfanyl)ethylsulfanyl]ethane
• CAS: 14440-87-0
• 化学式: C₁₀H₂₂O₂S₂
• 分子量: 238.415
• InChiKey: ACCZOZLPVQHRMY-UHFFFAOYSA-N

物化性质

• 沸点：
  175-190 °C(Press: 10 Torr)
• 密度：
  1.0450 g/cm3(Temp: 4 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  14
• 可旋转键数：
  11
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  69.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,2-bis-(2-ethoxy-ethylsulfanyl)-ethane 在 双氧水 、 溶剂黄146 作用下， 生成 1,2-bis-(2-ethoxy-ethanesulfonyl)-ethane
  参考文献：
  名称：

  Kretow, Zhurnal Russkago Fiziko-Khimicheskago Obshchestva, 1929, vol. 61, p. 2364

  摘要：

  DOI：
• 作为产物：
  描述：

  Disodium;ethane-1,2-dithiolate 、 2-乙氧基氯乙烷 生成 1,2-bis-(2-ethoxy-ethylsulfanyl)-ethane
  参考文献：
  名称：

  BELLAART A. C., PHOSPH. AND SULFUR, 1979, 6, NO 1-2, 33-34

  摘要：

  DOI：

文献信息

• Technetium and rhenium complexes with thioether ligands—IV. Synthesis and structural characterization of binuclear oxorhenium(V) complexes with bidentate thioether coordination
  作者：Hans-Juergen Pietzsch、Hartmut Spies、Peter Leibnitz、Guenter Reck

  DOI：10.1016/0277-5387(94)00470-y

  日期：1995.7

  prepared by reduction of ReO4− with SnCl2 in strongly acidic solution and in the presence of aliphatic thioethers of the general formula RCH2CH2SCH2CH2SCH2CH2R′ (“S2”; R, R′ = H, Et; R = S—Bu, R′ = Et; R = O—Et, R′ = H; R, R′ = O—Et). Alternatively the compounds can be obtained by ligand exchange reactions starting from [ReOCl4]− in methanolic solution. A representative derived from 5,8-dithiadodecane

  摘要在强酸溶液中，在通式RCH2CH2S的脂肪族硫醚存在下，通过用SnCl2还原ReO4-制备了双核氧（V）络合物[ReO（“ S2”）Cl2] 2O。 CH2CH2SCH2CH2R'（“ S2”; R，R'= H，Et; R = S-Bu，R'= Et; R = O-Et，R'= H; R，R'= O —等等）。或者，可以通过在甲醇溶液中从[ReOCl4]-开始的配体交换反应获得化合物。已经通过X射线衍射研究了衍生自5，8-二二十二烷（R，R'＝ Et）的代表。该络合物由两个独立的[ReO（“ S2”）Cl2]单元桥接，该单元由氧原子桥接。每个rh原子都集中在一个扭曲的八面体中，赤道面由S2Cl2供体组形成。单元中的硫和氯原子相对于桥连氧处于反位置。
• Resin composition for laser engraving, image forming material, relief printing plate precursor for laser engraving. relief printing plate, and method of producing relief printing plate
  申请人：FUJIFILM Corporation

  公开号：EP2145765A1

  公开（公告）日：2010-01-20

  A resin composition for laser engraving, including: a binder polymer; and a metal compound containing a metal selected from the group consisting of metals in Group 1 to Group 15 in the periodic table.

  一种用于激光雕刻的树脂组合物，包括：一种粘合剂聚合物；以及一种金属化合物，其中含有一种选自元素周期表中第 1 族至第 15 族金属的金属。
• RESIN COMPOSITION FOR LASER ENGRAVING, IMAGE FORMING MATERIAL, RELIEF PRINTING PLATE PRECURSOR FOR LASER ENGRAVING, RELIEF PRINTING PLATE, AND METHOD OF MANUFACTURING RELIEF PRINTING PLATE
  申请人：KAWASHIMA Takashi

  公开号：US20090246469A1

  公开（公告）日：2009-10-01

  The invention provides a resin composition for laser engraving, containing at least (A) a polymerizable compound having two or more ethylenic unsaturated bonds, a carbon-sulfur bond being contained at the site where two among the two or more ethylenic unsaturated bonds are connected and (B) a binder polymer. The invention further provides an image forming material containing the resin composition, a relief printing plate precursor having a relief forming layer which contains the resin composition, a relief printing plate precursor having a relief forming layer which contains a product formed by subjecting the resin composition to cross-linking, a method for manufacturing a relief printing plate including subjecting the relief printing plate precursor having the relief forming layer which contains the resin composition to cross-linking, and a relief printing plate manufactured by the manufacturing method.
• RESIN COMPOSITION FOR LASER ENGRAVING, IMAGE FORMING MATERIAL, RELIEF PRINTING PLATE PRECURSOR FOR LASER ENGRAVING, RELIEF PRINTING PLATE, AND METHOD OF PRODUCING RELIEF PRINTING PLATE
  申请人：KAWASHIMA Takashi

  公开号：US20100015416A1

  公开（公告）日：2010-01-21

  A resin composition for laser engraving, including: a binder polymer; and a metal compound containing a metal selected from the group consisting of metals in Group 1 to Group 15 in the periodic table.
• US8278387B2
  申请人：——

  公开号：US8278387B2

  公开（公告）日：2012-10-02