n-butyl 2-methyl-3-(1'-imidazole)propionate | 887375-52-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: n-butyl 2-methyl-3-(1'-imidazole)propionate
• 英文别名: Butyl 3-imidazol-1-yl-2-methylpropanoate
• CAS: 887375-52-2
• 化学式: C₁₁H₁₈N₂O₂
• 分子量: 210.276
• InChiKey: QSCSKIKKEKWGFE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  15
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.64
• 拓扑面积：
  44.1
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  咪唑 、 甲基丙烯酸丁酯 在 polystyrene-supported CuI-imidazole complex catalyst 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 4.0h， 以91%的产率得到n-butyl 2-methyl-3-(1'-imidazole)propionate
  参考文献：
  名称：

  Polystyrene-supported CuI–imidazole complex catalyst for aza-Michael reaction of imidazoles with α,β-unsaturated compounds

  摘要：

  The polystyrene-supported CuI-imidazole complex catalyst was prepared and characterized by IR spectroscopy, elemental analysis, SEM/TEM and TG/DSC. The complex catalyst was globular with the size of 400-500 nm and showed a good thermal stability at high temperature. The immobilized Cu metal in the complex catalyst was about 0.85 mmol/g. By using the catalyst, aza-Michael reaction of imidazoles to alpha,beta-unsaturated compounds was performed with good yields in 4-8 h. The catalyst showed an excellent recycling efficiency over five cycles without distinct leaching of metal from the polymer support. (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molcata.2011.11.023

文献信息

• POLYMERIZABLE IONIC LIQUID COMPOSITIONS
  申请人：3M Innovative Properties Company

  公开号：EP2571908B1

  公开（公告）日：2017-04-26
• US8383721B2
  申请人：——

  公开号：US8383721B2

  公开（公告）日：2013-02-26
• [EN] POLYMERIZABLE IONIC LIQUID COMPOSITIONS<br/>[FR] COMPOSITIONS LIQUIDES IONIQUES POLYMÉRISABLES
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2011146326A1

  公开（公告）日：2011-11-24

  The compositions comprise an acid functional monomer or acid-functional copolymer (or conjugate base thereof), and an imidazole compound (or conjugate acid theref).