tectochrysin 5-glucoside | 128508-07-6

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 黄酮类化合物
• 英文名称: tectochrysin 5-glucoside
• 英文别名: tectochrysin 5-O-glucoside；7-methoxy-2-phenyl-5-[(2S,3R,4S,5S,6R)-3,4,5-trihydroxy-6-(hydroxymethyl)oxan-2-yl]oxychromen-4-one
• CAS: 128508-07-6
• 化学式: C₂₂H₂₂O₉
• 分子量: 430.411
• InChiKey: SFKYGNQGJSKDTB-MIUGBVLSSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  31
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  135
• 氢给体数：
  4
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  tectochrysin 5-glucoside 在 苹果酸 作用下， 生成 杨芽黄素
  参考文献：
  名称：

  Flavonoid 5-glucosides from Prunus cerasus bark and their characteristic weak glycosidic bonding

  摘要：

  Pinostrobin 5-glucoside, a novel flavanone glycoside, was isolated from the bark of Prunus cerasus. As it was not found in P. avium, the substance is useful to distinguish these two species. Apigenin 5-glucoside genkwanin 5-glucoside and neosakuranin were also isolated from the bark of P. cerasus. They occur in both species as minor components. These 5-glucosides together with genistein 5-glucoside, prunetin 5-glucoside, sakuranin, tectochrysin 5-glucoside and luteolin 5-glucoside were hydrolysed in malic acid. The isoflavone and flavone 5-glucosides were shown to be hydrolysed more rapidly than the flavanone 5-glucosides, whereas no hydrolysis was observed with the corresponding 7-glucosides under the same conditions. The chalcone 2'-glucoside neosakuranin was transformed at first to the corresponding flavanone 5-glucoside, which was hydrolysed thereafter.

  DOI：

  10.1016/0031-9422(91)84200-c
• 作为产物：
  描述：

  杨芽黄素 在 喹啉 、 甲醇 、 氨 、 silver(l) oxide 作用下， 生成 tectochrysin 5-glucoside
  参考文献：
  名称：

  Hattori; Simokoriyama, Acta Phytochimica, 1942, vol. 13, p. 109,110, 115

  摘要：

  DOI：