1H,1H,2H,2H-perfluoro-3,5-tetradecadiynol | 691388-22-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1H,1H,2H,2H-perfluoro-3,5-tetradecadiynol
• 英文别名: 7,7,8,8,9,9,10,10,11,11,12,12,13,13,14,14,14-Heptadecafluorotetradeca-3,5-diyn-1-ol
• CAS: 691388-22-4
• 化学式: C₁₄H₅F₁₇O
• 分子量: 512.166
• InChiKey: USZKFYADNLCHGH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  32
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  18

反应信息

• 作为反应物：
  描述：

  丙烯酰氯 、 1H,1H,2H,2H-perfluoro-3,5-tetradecadiynol 在 三乙胺 作用下， 以 二氯甲烷 为溶剂， 反应 3.0h， 以76%的产率得到1H,1H,2H,2H-perfluoro-3,5-tetradecadiynyl acrylate
  参考文献：
  名称：

  Synthesis of two new families of fluorinated compounds: 1H,1H,2H,2H-perfluoro-3,5-alkyldiynols and 1H,1H-perfluoro-2,4-alkyldiynols and their acrylates and methacrylates

  摘要：

  The synthesis of two new families of compounds, 1H,1H,2H,2H-perfluoro-3,5-alkyldiynols and 1H,1H-perfluoro-2,4-alkyldiynols, and their acrylates and methacrylates, precursors of polymeric systems with important physical properties, is described. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.03.053
• 作为产物：
  描述：

  ((E)-3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluoro-1-iodo-dec-1-enyl)-trimethyl-silane 在 copper(l) iodide 、 potassium tert-butylate 、 碘 、 二异丙胺 作用下， 以 乙醚 为溶剂， 反应 10.0h， 生成 1H,1H,2H,2H-perfluoro-3,5-tetradecadiynol
  参考文献：
  名称：

  Synthesis of two new families of fluorinated compounds: 1H,1H,2H,2H-perfluoro-3,5-alkyldiynols and 1H,1H-perfluoro-2,4-alkyldiynols and their acrylates and methacrylates

  摘要：

  The synthesis of two new families of compounds, 1H,1H,2H,2H-perfluoro-3,5-alkyldiynols and 1H,1H-perfluoro-2,4-alkyldiynols, and their acrylates and methacrylates, precursors of polymeric systems with important physical properties, is described. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2004.03.053

文献信息

• Synthesis of two new families of fluorinated compounds: 1H,1H,2H,2H-perfluoro-3,5-alkyldiynols and 1H,1H-perfluoro-2,4-alkyldiynols and their acrylates and methacrylates
  作者：Ana Robert-Estelrich、Mercè Castella-Martı́nez、Francisco López-Calahorra

  DOI：10.1016/j.tet.2004.03.053

  日期：2004.5

  The synthesis of two new families of compounds, 1H,1H,2H,2H-perfluoro-3,5-alkyldiynols and 1H,1H-perfluoro-2,4-alkyldiynols, and their acrylates and methacrylates, precursors of polymeric systems with important physical properties, is described. (C) 2004 Elsevier Ltd. All rights reserved.