1,4-bis-(3,5-diphenylfuran-2-yl)benzene | 492436-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis-(3,5-diphenylfuran-2-yl)benzene
• 英文别名: 2-[4-(3,5-Diphenylfuran-2-yl)phenyl]-3,5-diphenylfuran
• CAS: 492436-14-3
• 化学式: C₃₈H₂₆O₂
• 分子量: 514.623
• InChiKey: VBICQXXAFQWBON-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10
• 重原子数：
  40
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-bis-(3,5-diphenylfuran-2-yl)benzene 在 tert-butylammonium hexafluorophosphate(V) 作用下， 以 四氢呋喃 为溶剂， 以90%的产率得到(Z)-1-[4-(3,5-diphenylfuran-2-yl)phenyl]-2,4-diphenylbut-2-ene-1,4-dione
  参考文献：
  名称：

  Sequential Electrochemical Oxidation of Alternating Benzene-Furan Oligomers

  摘要：

  Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.

  DOI：

  10.1021/jo070999+
• 作为产物：
  描述：

  对苯二甲醛 、 2-phenyl-2-(2-pehnylethynyl)-1,3-dithiolane 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 1.0h， 以58%的产率得到1,4-bis-(3,5-diphenylfuran-2-yl)benzene
  参考文献：
  名称：

  Non-amine-based furan-containing oligoaryls as efficient hole transporting materialsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b207489c/

  摘要：

  一类高度稳定的呋喃基空穴传输低聚物材料，由相应的丙炔基二硫代缩醛合成，在电致发光器件中用作高效的空穴传输材料。使用这些呋喃材料的器件性能与使用传统三芳基胺（如α-NPD）的器件相当，甚至更好。

  DOI：

  10.1039/b207489c

文献信息

• Sequential Electrochemical Oxidation of Alternating Benzene-Furan Oligomers
  作者：Cheng-Lan Lin、Yi-Lin Wu、Chang-Li Chen、Chih-Ming Chou、Tien-Yau Luh

  DOI：10.1021/jo070999+

  日期：2007.10.1

  Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.
• Non-amine-based furan-containing oligoaryls as efficient hole transporting materialsElectronic supplementary information (ESI) available: experimental details. See http://www.rsc.org/suppdata/cc/b2/b207489c/
  作者：Ling-Zhi Zhang、Chieh-Wei Chen、Chin-Fa Lee、Chung-Chih Wu、Tien-Yau Luh

  DOI：10.1039/b207489c

  日期：2002.10.11

  A new class of highly stable furan-based hole transporting oligomeric materials, synthesized from the corresponding propargylic dithioacetals, serve as efficient hole transporting materials in electroluminescent devices. The performance of the devices using these furan materials is comparable with or somewhat better than those employing the conventional triarylamines (e.g. α-NPD).

  一类高度稳定的呋喃基空穴传输低聚物材料，由相应的丙炔基二硫代缩醛合成，在电致发光器件中用作高效的空穴传输材料。使用这些呋喃材料的器件性能与使用传统三芳基胺（如α-NPD）的器件相当，甚至更好。