10-methylene-9-azaanthracene | 139266-02-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10-methylene-9-azaanthracene
• 英文别名: 9-Methylidene-9,10-dihydroacridine；9-methylidene-10H-acridine
• CAS: 139266-02-7
• 化学式: C₁₄H₁₁N
• 分子量: 193.248
• InChiKey: UTPHKOKOBDRNNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  10-methylene-9-azaanthracene 在 N-溴代丁二酰亚胺(NBS) 作用下， 以 氯仿 为溶剂， 生成 10-bromomethylene-9-azaanthracene
  参考文献：
  名称：

  CN116947758

  摘要：

  公开号：
• 作为产物：
  描述：

  甲基溴化镁 、 吖啶酮 在 盐酸 作用下， 以 四氢呋喃 、 甲苯 、 乙醇 、 水 为溶剂， 生成 10-methylene-9-azaanthracene
  参考文献：
  名称：

  CN116947758

  摘要：

  公开号：

文献信息

• Use of polymeric reaction product
  申请人：——

  公开号：US20030170306A1

  公开（公告）日：2003-09-11

  A reaction product (A) which can be prepared by reaction, under free radical conditions, of at least one monomer (a) capable of free radical reaction, in the presence of at least one free radical initiator and of a radical of the formula (III) 1 where R 1 to R 3 , in each case independently of one another, are hydrogen, methyl or a radical-stabilizing and/or bulky group selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, cycloalkyl, alcohol, ether, polyether, amine, aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another in each case, are defined in the same way as R 1 to R 5 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and, if required, may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 3 are a radical-stabilizing and/or bulky group as defined above, has various uses.

  一种反应产物（A），可以通过在自由基条件下，在至少一种自由基反应能力的单体（a）存在下，在至少一种自由基引发剂和式（III）的自由基存在下反应制备，其中R1至R3分别独立地为氢，甲基或选择自未取代或取代的，线性或支链的2个或多个碳原子的烷基，环烷基，醇，醚，聚醚，胺，芳基烷基，取代或未取代的芳香族，杂环或烯烃烃基，卤素原子，取代或未取代的，线性或支链的烯丙基或炔基，-C（O）R5，-C（O）OR5，-CR5R6-O-R7，-O-C（O）R5，-CN，-O-CN，-S-CN，-O-C═NR5，-S-C═NR5，-O-CR5R6-CR7R8NR9R10，-N═C═O，-C═NR5，-CR5R6-Hal，-C（S）R5，-CR5R6-P（O）R7R8，-CR5R6-PR7R8，-CR5R6-NR7R8，-CR5R6（OR7）（OR8），-CR5R6（OR7）（NR8），-CR5R6（NR7）（NR8），酸酐，缩醛或缩酮基，-SO2R5，酰胺基，-NR5C（S）NR6，-NR5C（S）-OR6，-N═C═S，-NO2，-C═N-OH，-N（R5）═NR6，-PR5R6R7，-OSiR5R6R7或-SiR5R6R7，其中R5至R10在每种情况下独立地定义为R1至R5的定义方式，或R1至R4中的两个形成一个C4到C7环，该环可以被取代或未取代，并且如果需要，可以包含一个或多个杂原子，但至少两个R1至R3是如上所定义的稳定/笨重基团，具有各种用途。
• Method for the production of a polymerisation reaction product
  申请人：——

  公开号：US20040034182A1

  公开（公告）日：2004-02-19

  A process for the preparation of a reaction product (A) comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction, in the presence of at least one compound of the formula (I) 1 where R 1 to R 4 , independently of one another, are each hydrogen, methyl or a group which stabilizes radicals and/or is bulky and which is selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, a cycloalkyl, alcohol, ether, polyether, amine or aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another, are each defined in the same way as R 1 to R 4 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 4 are a group which stabilizes radicals and/or is bulky, as defined above, and diphenylethylene, dinaphthylethylene, 4,4′-vinylidenebis(N,N′-dimethylaniline), 4,4′-vinylidenebis(aminobenzene), cis- and trans-stilbene and mixtures of two or more thereof are excluded as compounds of the formula (I), and a process for the preparation of a reaction product (A′) comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction, in the presence of at least one compound of the formula (II) 2 where R 1 to R 4 and R 11 and R 12 , independently of one another, are each hydrogen, methyl or a group which stabilizes radicals and/or is bulky and which is selected from an unsubstituted or substituted, linear or branched alkyl of two or more carbon atoms, a cycloalkyl, alcohol, ether, polyether, amine or aralkyl radical, a substituted or unsubstituted aromatic, heterocyclic or olefinic hydrocarbon, a halogen atom, a substituted or unsubstituted, linear or branched alkenyl or alkynyl group, —C(O)R 5 , —C(O)OR 5 , —CR 5 R 6 —O—R 7 , —O—C(O)R 5 , —CN, —O—CN, —S—CN, —O—C═NR 5 , —S—C═NR 5 , —O—CR 5 R 6 —CR 7 R 8 NR 9 R 10 , —N═C═O, —C═NR 5 , —CR 5 R 6 -Hal, —C(S)R 5 , —CR 5 R 6 —P(O)R 7 R 8 , —CR 5 R 6 —PR 7 R 8 , —CR 5 R 6 —NR 7 R 8 , —CR 5 R 6 (OR 7 )(OR 8 ), —CR 5 R 6 (OR 7 )(NR 8 ), —CR 5 R 6 (NR 7 )(NR 8 ), an anhydride, acetal or ketal group, —SO 2 R 5 , an amidine group, —NR 5 C(S)NR 6 , —NR 5 C(S)—OR 6 , —N═C═S, —NO 2 , —C═N—OH, —N(R 5 )═NR 6 , —PR 5 R 6 R 7 , —OSiR 5 R 6 R 7 or —SiR 5 R 6 R 7 , where R 5 to R 10 , independently of one another, are each defined in the same way as R 1 to R 4 , or two of the radicals R 1 to R 4 form a C 4 - to C 7 -ring which in turn may be substituted or unsubstituted and may contain one or more heteroatoms, with the proviso that at least two of the radicals R 1 to R 4 are a group which stabilizes radicals and/or is bulky, as defined above.

  一种制备反应产物（A）的方法包括以下步骤（i）：（i）在自由基条件下，反应混合物至少包括一种自由基反应的单体（a），在至少一种化合物（I）1的存在下反应，其中R1至R4独立地是氢、甲基或稳定自由基和/或是笨重的基团，选择自未取代或取代的、线性或支链的含有两个或更多碳原子的烷基、环烷基、醇、醚、聚醚、胺或芳基烷基、取代或未取代的芳香、杂环或烯烃烃基、卤素原子、取代或未取代的、线性或支链的烯基或炔基、—C（O）R5、—C（O）OR5、—CR5R6—O—R7、—O—C（O）R5、—CN、—O—CN、—S—CN、—O—C═NR5、—S—C═NR5、—O—CR5R6—CR7R8NR9R10、—N═C═O、—C═NR5、—CR5R6-Hal、—C（S）R5、—CR5R6—P（O）R7R8、—CR5R6—PR7R8、—CR5R6—NR7R8、—CR5R6（OR7）（OR8）、—CR5R6（OR7）（NR8）、—CR5R6（NR7）（NR8）、酐、缩醛或缩酮基团、—SO2R5、酰胺基团、—NR5C（S）NR6、—NR5C（S）—OR6、—N═C═S、—NO2、—C═N—OH、—N（R5）═NR6、—PR5R6R7、—OSiR5R6R7或—SiR5R6R7，其中R5至R10独立地与R1至R4的定义相同，或者R1至R4中的两个基团形成一个C4-C7环，该环可以被取代或未取代，并且可能含有一个或多个杂原子，但需注意至少有两个基团R1至R4是稳定自由基和/或笨重的基团，如上所定义，而联苯乙烯、二萘乙烯、4,4′-乙烯基双（N,N′-二甲基苯胺）、4,4′-乙烯基双（氨基苯）和顺式和反式的蒽烯及其混合物被排除在化合物（I）的定义之外，以及一种制备反应产物（A′）的方法包括以下步骤（i）：（i）在自由基条件下，反应混合物至少包括一种自由基反应的单体（a），在至少一种化合物（II）2的存在下反应，其中R1至R4和R11和R12独立地是氢、甲基或稳定自由基和/或是笨重的基团，选择自未取代或取代的、线性或支链的含有两个或更多碳原子的烷基、环烷基、醇、醚、聚醚、胺或芳基烷基、取代或未取代的芳香、杂环或烯烃烃基、卤素原子、取代或未取代的、线性或支链的烯基或炔基、—C（O）R5、—C（O）OR5、—CR5R6—O—R7、—O—C（O）R5、—CN、—O—CN、—S—CN、—O—C═NR5、—S—C═NR5、—O—CR5R6—CR7R8NR9R10、—N═C═O、—C═NR5、—CR5R6-Hal、—C（S）R5、—CR5R6—P（O）R7R8、—CR5R6—PR7R8、—CR5R6—NR7R8、—CR5R6（OR7）（OR8）、—CR5R6（OR7）（NR8）、—CR5R6（NR7）（NR8）、酐、缩醛或缩酮基团、—SO2R5、酰胺基团、—NR5C（S）NR6、—NR5C（S）—OR6、—N═C═S、—NO2、—C═N—OH、—N（R5）═NR6、—PR5R6R7、—OSiR5R6R7或—SiR5R6R7，其中R5至R10独立地与R1至R4的定义相同，或者R1至R4中的两个基团形成一个C4-C7环，该环可以被取代或未取代，并且可能含有一个或多个杂原子，但需注意至少有两个基团R1至R4是稳定自由基和/或笨重的基团，如上所定义。
• Washing active preparation
  申请人：BASF Aktiengesellschaft

  公开号：US06710024B2

  公开（公告）日：2004-03-23

  Disclosed are a detersive composition comprising a water-soluble or water-dispersible block copolymer preparable by controlled free-radical polymerization, a process for preparing such a detersive composition and the use of water-soluble or water-dispersible block copolymers preparable by controlled free-radical polymerization for preparing detersive compositions.

  本发明涉及一种可通过控制自由基聚合制备的水溶性或水分散性嵌段共聚物制备的洗涤剂组合物、制备该洗涤剂组合物的方法以及利用可通过控制自由基聚合制备的水溶性或水分散性嵌段共聚物制备洗涤剂组合物的用途。
• FLUORESCENT DYES BASED ON ACRIDINE AND ACRIDINIUM DERIVATIVES
  申请人：Almac Sciences (Scotland) Limited

  公开号：US20140349297A1

  公开（公告）日：2014-11-27

  The present invention relates to fluorescent dyes based on acridine and acridinium derivatives and use of such dyes in for example, biochemical and/or cell-based assays.

  本发明涉及基于吖啶和吖啶盐衍生物的荧光染料及其在生物化学和/或基于细胞的分析中的应用。
• CHEMICALLY AMPLIFIED RESIST MATERIAL, PATTERN-FORMING METHOD, COMPOUND, AND PRODUCTION METHOD OF COMPOUND
  申请人：OSAKA UNIVERSITY

  公开号：EP3133444A1

  公开（公告）日：2017-02-22

  A chemically amplified resist material of the present invention is used in a process including: patternwise exposing a predetermined region of resist material film to ionizing radiation or nonionizing radiation; floodwise exposing the resist material film patternwise exposed to nonionizing radiation; baking the resist material film floodwise exposed; and developing resist material film to form a resist pattern, the chemically amplified resist material containing: (1) base component; and (2) a component that is capable of generating a radiation-sensitive sensitizer and an acid upon an exposure, wherein the component (2) contains, among (a) a radiation-sensitive acid-and-sensitizer generating agent, (b) a radiation-sensitive sensitizer generating agent, and (c) a radiation-sensitive acid generating agent: the components (a) and (b); the components (b) and (c); or all of the components (a) to (c), and wherein the component (b) contains a compound represented by formula (A).

  本发明的一种化学放大抗蚀剂材料用于一种工艺中，该工艺包括：将抗蚀剂材料薄膜的预定区域图案化暴露于电离辐射或非电离辐射中；将抗蚀剂材料薄膜图案化暴露于非电离辐射中；烘烤被图案化暴露的抗蚀剂材料薄膜；显影抗蚀剂材料薄膜以形成抗蚀剂图案，该化学放大抗蚀剂材料包含：(1)碱成分；和(2)能在曝光时生成辐射敏感敏化剂和酸的成分，其中成分(2)包含(a)辐射敏感酸和敏化剂生成剂，(b)辐射敏感敏化剂生成剂，和(c)辐射敏感酸生成剂：组分 (a) 和 (b)；组分 (b) 和 (c)；或组分 (a) 至 (c) 的全部，其中组分 (b) 包含式 (A) 所代表的化合物。