1-(4-allylthiophenyl)-2-methyl-2-morpholinopropan-1-one | 88324-60-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(4-allylthiophenyl)-2-methyl-2-morpholinopropan-1-one
• 英文别名: 2-Methyl-2-(morpholin-4-yl)-1-{4-[(prop-2-en-1-yl)sulfanyl]phenyl}propan-1-one；2-methyl-2-morpholin-4-yl-1-(4-prop-2-enylsulfanylphenyl)propan-1-one
• CAS: 88324-60-1
• 化学式: C₁₇H₂₃NO₂S
• 分子量: 305.441
• InChiKey: LGVQGVKHYKYLSP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  21
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  54.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-methyl-2-(4-morpholinyl)-1-(4-mercaptophenyl)-1-propanone 、 3-溴丙烯 、 potassium carbonate 在 水 、 乙醚 、 sodium hydroxide 、 magnesium sulfate 作用下， 以 丙酮 为溶剂， 180.0~200.0 ℃ 、1.73 kPa 条件下， 反应 16.0h， 生成 1-(4-allylthiophenyl)-2-methyl-2-morpholinopropan-1-one
  参考文献：
  名称：

  Ketone with morpholino and s-phenyl groups as photoinitiator in

  摘要：

  式I、II或III的化合物##STR1##中，Ar是含硫芳基，R.sup.1和R.sup.2是单价的碳氢基团，可以被取代或未取代，或者R.sup.1和R.sup.2一起形成烷基，氧杂烷基或氮杂烷基，R.sup.3是直接键或双价的碳氢基团，X是单价氨基团，X'是双价氨基或二氨基团。这些化合物是优秀的光引发剂，适用于光固化着色的，特别是含有烯丙基不饱和光聚合物的颜料组合物。

  公开号：

  US04582862A1

文献信息

• Coatable compositions, abrasive articles made therefrom, and methods of making and using same
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0654323A1

  公开（公告）日：1995-05-24

  Coatable compositions suitable for use in producing abrasive articles are presented. The inventive coatable compositions characterized by a combination of a free radically polymerizable composition, abrasive particles, and a photoinitiator system. The photoinitiator system characterized by a compound which cleaves via α-cleavage and has a molar absorptivity in dilute methanol solution ranging from about 4 to about 400 liter/mole-cm in at least some portion of the UV/visible spectrum ranging from about 395 and about 500 nanometers. Abrasive articles incorporating cured versions of the compositions are presented, as well as methods of making and using the articles.

  本发明提出了适用于生产研磨制品的可涂覆组合物。本发明的可涂覆组合物由自由基可聚合组合物、磨料颗粒和光引发剂系统组合而成。光引发剂体系的特征是通过 α 裂解的化合物，其在稀甲醇溶液中的摩尔吸收率在约 4 到约 400 升/摩尔-厘米之间，至少在约 395 纳米到约 500 纳米的紫外线/可见光谱的某些部分具有吸收率。本文介绍了含有固化版组合物的研磨制品，以及制造和使用这些制品的方法。
• Photo-curing of thermoplastic coatings
  申请人：Coloplast A/S

  公开号：US10252291B2

  公开（公告）日：2019-04-09

  The present invention relates to a method for the preparation of a medical device element by means of extrusion or injection molding and to medical devices comprising such extruded or injection molded medical device elements. The medical device elements (e.g. tubes, wires, lines, stents, catheters, guides, endodontic instruments, needles, trocars for e.g. laparoscopic surgery, laparoscopic accessories, surgical instruments, guide wires) are characterized by a prefabricated shaped article or a thermoplastic substrate polymer having thereon a layer of a covalently cross-linked coating composition of a thermoplastic matrix polymer and a hydrophilic polymer. The method involves a coating composition comprising a thermoplastic matrix polymer, a hydrophilic polymer, and one or more photo-initiator(s), e.g. covalently linked to molecules of the thermoplastic matrix polymer and/or to molecules of the hydrophilic polymer. The coating composition is irradiated with UV or visible light so as to covalently cross-link said coating composition.

  本发明涉及一种通过挤压或注射成型制备医疗器械元件的方法，以及由这种挤压或注射成型医疗器械元件组成的医疗器械。这些医疗器械元件（如管、线、管路、支架、导管、导引器、根管器械、针、腹腔镜手术用套管、腹腔镜附件、手术器械、导丝）的特征是预制成型品或热塑性基质聚合物上有一层由热塑性基质聚合物和亲水性聚合物组成的共价交联涂层组合物。该方法涉及一种涂层组合物，该组合物包括热塑性基质聚合物、亲水性聚合物和一种或多种光引发剂，例如与热塑性基质聚合物分子和/或亲水性聚合物分子共价连接的光引发剂。用紫外线或可见光照射涂层组合物，使其共价交联。
• Coatable composition and methods of making abrasive articles
  申请人：MINNESOTA MINING AND MANUFACTURING COMPANY

  公开号：EP0654323B1

  公开（公告）日：2005-04-20
• PHOTO-CURING OF THERMOPLASTIC COATINGS
  申请人：Coloplast A/S

  公开号：EP2049172B1

  公开（公告）日：2014-12-31
• COATINGS PREPARED FROM POLY(ETHYLENE OXIDE) AND PHOTO-INITATOR-CONTAINING SCAFFOLDS
  申请人：Coloplast A/S

  公开号：EP2104523B1

  公开（公告）日：2015-08-26