1-methoxycarbonyl-2-methyl-6-isopropylazulene | 114622-43-4

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1-methoxycarbonyl-2-methyl-6-isopropylazulene
• 英文别名: Methyl 2-methyl-6-(propan-2-yl)azulene-1-carboxylate；methyl 2-methyl-6-propan-2-ylazulene-1-carboxylate
• CAS: 114622-43-4
• 化学式: C₁₆H₁₈O₂
• 分子量: 242.318
• InChiKey: HGZZHABSWJXDNL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.31
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-methoxycarbonyl-2-methyl-6-isopropylazulene 在 sodium hydroxide 、 磷酸 作用下， 以75%的产率得到2-methyl-6-isopropylazulene
  参考文献：
  名称：

  Transition metal compounds

  摘要：

  本发明涉及一种用于α-烯烃聚合的催化剂，包括：必需组分(A)为过渡金属化合物，必需组分(B)为除硅酸盐以外的可离子交换层化合物，或者是无机硅酸盐，以及可选组分(C)为有机铝化合物，所述的组分(A)用一般式(I)表示：

  公开号：

  US06252097B1

文献信息

• Process for producing alpha-olefin polymers
  申请人：Mitsubishi Chemical Corporation

  公开号：US20010034425A1

  公开（公告）日：2001-10-25

  The present invention relates to a catalyst for polymerization of &agr;-olefin, which comprises: an essential component (A) of a transition metal compound, an essential component (B) of an ion exchangeable layer compound except for silicate, or an inorganic silicate, and an optional component (C) of an organoaluminum compound, said component (A) being represented by the general formula (I): 1

  本发明涉及一种用于α-烯烃聚合的催化剂，包括：必要组分(A)的过渡金属化合物、必要组分(B)的离子交换层化合物（除硅酸盐外）或无机硅酸盐、以及可选组分(C)的有机铝化合物，其中组分(A)由通式(I)表示：1
• Catalysts for polymerization of alpha-olefins, process for producing alpha-olefin polymers, novel transition metal compounds and catalyst components for polymerization of alpha-olefin
  申请人：Mitsubishi Chemical Corporation.

  公开号：US20020045535A1

  公开（公告）日：2002-04-18

  Catalysts for polymerization of &agr;-olefin, composed of a transition metal compound, an inorganic silicate or an ion exchangeable layer compound other than silicate, and optionally an organoaluminum compound, are described. The transition metal compound is represented by formula (I): 1 where A 1 and A 2 are each independently a conjugated 5-membered ring ligand provided that A 1 and A 2 may be the same or different in a molecule, and at least one of A 1 and A 2 forms a 7- to 10-membered condensed ring including two adjacent carbon atoms of the conjugated 5-membered ring, which condensed ring is formed by joining two adjacent substitutent groups on the conjugated 5-membered ring; Q is a bridging group of the two conjugated 5-membered rings of A 1 and A 2 at optional positions of the 5-membered rings; M is a metal atom selected from elements of Group 4-6 of the Periodic Table; and X and Z are each independently a hydrogen atom, a halogen atom, a hydrocarbon group, and amino group, a halogenated hydrocarbon group, an oxygen-containing hydrocarbon group, a nitrogen-containing hydrocarbon group, a phosphorus-containing hydrocarbon group or a silicon-containing hydrocarbon group.

  本文描述了用于α-烯烃聚合的催化剂，由过渡金属化合物、无机硅酸盐或除硅酸盐以外的可离子交换层化合物以及可选的有机铝化合物组成。过渡金属化合物由式(I)表示：其中A1和A2分别是共轭的5元环配体，前提是在分子中A1和A2可以相同或不同，并且A1和A2中至少有一个形成由连接共轭的5元环上的两个相邻碳原子而形成的7-10元环。Q是A1和A2的两个共轭的5元环的桥接基团，位于5元环的可选位置；M是从周期表第4-6族元素中选择的金属原子；X和Z分别是氢原子、卤素原子、碳氢基团、氨基、卤代碳氢基团、含氧碳氢基团、含氮碳氢基团、含磷碳氢基团或含硅碳氢基团。
• Catalysts for polymerization of &agr;-olefins, process for producing &agr;-olefin polymers, novel transition metal compounds and catalyst components for polymerization of &agr;-olefin
  申请人：Mitsubishi Chemical Corporation

  公开号：US06825371B2

  公开（公告）日：2004-11-30

  The present invention relates to a catalyst for polymerization of &agr;-olefin, which comprises: an essential component (A) of a transition metal compound, an essential component (B) of an ion exchangeable layer compound except for silicate, or an inorganic silicate, and an optional component (C) of an organoaluminum compound, said component (A) being represented by the general formula (I):

  本发明涉及一种用于&agr;-烯烃聚合的催化剂，包括：必要组分(A)的过渡金属化合物，必要组分(B)的可离子交换层化合物除硅酸盐或无机硅酸盐，以及可选组分(C)的有机铝化合物，其中组分(A)由通式(I)表示：
• Process for producing &agr;-olefin polymers
  申请人：Mitsubishi Chemical Corporation

  公开号：US06344530B2

  公开（公告）日：2002-02-05

  The present invention relates to a catalyst for polymerization of &agr;-olefin, which comprises: an essential component (A) of a transition metal compound, an essential component (B) of an ion exchangeable layer compound except for silicate, or an inorganic silicate, and an optional component (C) of an organoaluminum compound, said component (A) being represented by the general formula (I):

  本发明涉及一种用于α-烯烃聚合的催化剂，包括：必要组分（A）的过渡金属化合物，必要组分（B）的可离子交换层化合物（除硅酸盐外），或者无机硅酸盐，以及可选组分（C）的有机铝化合物，其中所述组分（A）由通式（I）表示：
• Catalyst for polymerization of alpha-olefins
  申请人：Mitsubishi Chemical Corporation

  公开号：EP0846696A1

  公开（公告）日：1998-06-10

  The present invention relates to a catalyst for polymerization of α-olefin, which comprises: an essential component (A) of a transition metal compound, an essential component (B) of an ion exchangeable layer compound except for silicate, or an inorganic silicate, and an optional component (C) of an organoaluminum compound, said component (A) being represented by the general formula (I):

  本发明涉及一种用于α-烯烃聚合的催化剂，它包括 过渡金属化合物的基本成分 (A) 离子交换层化合物（硅酸盐除外）或无机硅酸盐的基本组分（B），以及 有机铝化合物的可选成分 (C)、 所述组分（A）由通式（I）表示：