1-(4-diphenylamino-phenyl)-3-(9-ethyl-9H-carbazol-3-yl)-propane-1,3-dione

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 直链 1,3-二芳基丙烷
• 英文名称: 1-(4-diphenylamino-phenyl)-3-(9-ethyl-9H-carbazol-3-yl)-propane-1,3-dione
• 英文别名: 1-(9-ethylcarbazol-3-yl)-3-[4-(N-phenylanilino)phenyl]propane-1,3-dione
• 化学式: C₃₅H₂₈N₂O₂
• 分子量: 508.62
• InChiKey: AAAUBWSKRPHGPX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.1
• 重原子数：
  39
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  42.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,10-菲罗啉 、 europium(III) chloride hexahydrate 、 1-(4-diphenylamino-phenyl)-3-(9-ethyl-9H-carbazol-3-yl)-propane-1,3-dione 在 sodium hydroxide 作用下， 以 乙醇 、 异戊醇 为溶剂， 反应 10.0h， 以65%的产率得到[Eu(1-(4-diphenylamino-phenyl)-3-(9-ethyl-9H-carbazol-3-yl)-propane-1,3-dione(-H))3(1,10-phenantholine)]
  参考文献：
  名称：

  Synthesis and characterization a novel europium(III)-β-diketonate complex with carbazole and triphenylamine moieties

  摘要：

  A novel beta-diketonate ligand with triphenylamine and carbazole moieties named: 1-(4-diphenylamino-phenyl)-3-(9-ethyl-9H-carbazol-3-yl)-propane-1,3-dione (HL), was synthesized by the Claisen condensation reaction and its corresponding europium complex Eu(L)(3)phen was prepared. The structures of the ligand and complex were characterized by IR spectra, H-1 NMR, elemental analysis (EA), UV-Vis spectra and ESI-MS. The photoluminescence (PL) spectra shows that the ligand has an excellent antenna effect to sensitize the Eu3+ and the complex has good quantum efficiency which indicates that the complex is a good candidate as emitter in fabricating organic light-emitting diodes (OLEDs). Thermogravimetric (TG) analysis shows that the complex possesses high thermal stability and good film-forming ability to generate the OLEDs. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.03.020
• 作为产物：
  描述：

  3-乙酰基-N-乙基咔唑 、 4-(二苯基氨基)苯甲酸甲酯 在 sodium hydride 作用下， 以 四氢呋喃 为溶剂， 反应 12.0h， 以56%的产率得到1-(4-diphenylamino-phenyl)-3-(9-ethyl-9H-carbazol-3-yl)-propane-1,3-dione
  参考文献：
  名称：

  Synthesis and characterization a novel europium(III)-β-diketonate complex with carbazole and triphenylamine moieties

  摘要：

  A novel beta-diketonate ligand with triphenylamine and carbazole moieties named: 1-(4-diphenylamino-phenyl)-3-(9-ethyl-9H-carbazol-3-yl)-propane-1,3-dione (HL), was synthesized by the Claisen condensation reaction and its corresponding europium complex Eu(L)(3)phen was prepared. The structures of the ligand and complex were characterized by IR spectra, H-1 NMR, elemental analysis (EA), UV-Vis spectra and ESI-MS. The photoluminescence (PL) spectra shows that the ligand has an excellent antenna effect to sensitize the Eu3+ and the complex has good quantum efficiency which indicates that the complex is a good candidate as emitter in fabricating organic light-emitting diodes (OLEDs). Thermogravimetric (TG) analysis shows that the complex possesses high thermal stability and good film-forming ability to generate the OLEDs. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2013.03.020