cis 3-methyl-3-heptene

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: cis 3-methyl-3-heptene
• 英文别名: cis-3-methyl-3-heptene；(Z)-3-Methylhept-3-ene
• 化学式: C₈H₁₆
• 分子量: 112.215
• InChiKey: AAUHUDBDDBJONC-FPLPWBNLSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  8
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  cis 3-methyl-3-heptene 生成 (S)-3-methyl-heptane
  参考文献：
  名称：

  COUTURIER S.; TANTURIER G.; GAUTHERON B., J. ORGANOMETAL. CHEM., 1980, 195, NO 3, 291-306

  摘要：

  DOI：
• 作为产物：
  描述：

  2-甲基-3-庚醇 生成 cis 3-methyl-3-heptene
  参考文献：
  名称：

  ZHANG, JINGWEN;XU, ZHILUO;HUANG, HUAMIN;LIU, FUAN;ZHU, SHAOXIAN, TSZILIN DASYUEH TSZYZHAN KEHSYUEH SYUEHBAO ,(1988) N, S. 83-86

  摘要：

  DOI：

文献信息

• Method for Producing Isononanoic Acid Esters, Starting from 2-Ethyl Hexanol
  申请人：Oxea GmbH

  公开号：US20150158805A1

  公开（公告）日：2015-06-11

  A Process for preparing carboxylic esters of a mixture of structurally branched C9 monocarboxylic acids proceeding from 2-ethylhexanol is characterized in that (a) 2-ethylhexanol is dehydrated to an octene mixture in the presence of a catalyst; (b) the octene mixture obtained in step a) is reacted in the presence of a transition metal compound of group VIII of the periodic table of the elements with carbon monoxide and hydrogen to give a mixture of isomeric isononanals; (c) the mixture of isomeric isononanals obtained in step b) is oxidized to a mixture of structurally branched C9 monocarboxylic acids; and (d) the mixture of structurally branched C9 monocarboxylic acids obtained in step c) is reacted with alcohols to give carboxylic esters.

  一种制备从2-乙基己醇出发的结构分支C9单羧酸酯混合物的方法，其特征在于 (a) 在催化剂存在下，将2-乙基己醇脱水成为辛烯混合物； (b) 在步骤a)中获得的辛烯混合物在元素周期表第VIII族的过渡金属化合物存在下与一氧化碳和氢反应，得到异辛醛的混合物； (c) 在步骤b)中获得的异辛醛混合物被氧化成结构分支的C9单羧酸的混合物；以及 (d) 在步骤c)中获得的结构分支C9单羧酸混合物与醇反应，得到羧酸酯。
• Isononylamines from 2-Ethylhexanol, Processes for Their Preparation, and Their Use
  申请人：Oxea GmbH

  公开号：US20150152023A1

  公开（公告）日：2015-06-04

  Process for preparing isononylamines starting out from 2-ethylhexanol, characterized in that (a) 2-ethylhexanol is dehydrated in the presence of a catalyst to form octene; (b) the octene obtained in step a) is reacted with carbon monoxide and hydrogen in the presence of a transition metal compound of group VIII of the Periodic Table of the Elements to form isononanal; and (c) the isononanal obtained in step b) is converted into isononylamines.

  从2-乙基己醇开始制备异壬胺的过程，其特征在于(a) 在催化剂的存在下将2-乙基己醇脱水形成辛烯；(b) 在步骤a)中获得的辛烯与一周期表第VIII族过渡金属化合物存在下与一氧化碳和氢反应形成异壬醛；(c) 在步骤b)中获得的异壬醛转化为异壬胺。
• Vinyl Esters of Isononanoic Acid Starting from 2-Ethyl Hexanol, Methods for the Production Thereof and Use Thereof
  申请人：Oxea Gmbh

  公开号：US20150166456A1

  公开（公告）日：2015-06-18

  Process for preparing the vinyl ester of isononanoic acid starting out from 2-ethylhexanol, characterized in that (a) 2-ethylhexanol is dehydrated in the presence of a catalyst to form octene; (b) the octene obtained in step a) is converted into an isononanoic acid having one more carbon atom; and (c) the isononanoic acid obtained in step b) is converted into the corresponding vinyl ester.

  从2-乙基己醇开始制备异壬酸乙烯酯的过程，其特征在于(a)在催化剂的存在下，将2-乙基己醇脱水形成辛烯；(b)将步骤(a)中获得的辛烯转化为具有一个碳原子的异壬酸；(c)将步骤(b)中获得的异壬酸转化为相应的乙烯酯。
• Method for Producing Isononanoic Acids from 2-Ethyl Hexanol
  申请人：Oxea GmbH

  公开号：US20150191410A1

  公开（公告）日：2015-07-09

  Process for preparing isononanoic acid proceeding from 2-ethylhexanol, characterized in that (a) 2-ethylhexanol is dehydrated to octene in the presence of a catalyst; (b) the octene obtained in step a) is reacted in the presence of a transition metal compound of group VIII of the periodic table of the elements with carbon monoxide and hydrogen to give isononanal; and (c) the isononanal obtained in step b) is oxidized to isononanoic acid.

  从2-乙基己醇制备异壬酸的过程，其特征在于：（a）在催化剂的存在下，将2-乙基己醇脱水成辛烯；（b）在步骤（a）中获得的辛烯在元素周期表第VIII族的过渡金属化合物存在下与一氧化碳和氢反应，生成异壬醛；（c）在步骤（b）中获得的异壬醛被氧化成异壬酸。
• [EN] TURBINE AND DIESEL FUELS AND METHODS FOR MAKING THE SAME<br/>[FR] CARBURANTS POUR TURBOMACHINE ET DIESEL ET LEURS PROCÉDÉS DE FABRICATION
  申请人：US GOV SEC NAVY

  公开号：WO2013162575A1

  公开（公告）日：2013-10-31

  A process for making diesel and turbine fuels includes providing an amount of one or more branched olefins and adding active heterogeneous acid catalyst(s) to the branched olefins to produce a mixture, which can be solvent-free. The process further includes heating the solvent-free mixture to a temperature greater than about 80°C for a sufficient time to produce a dimers/catalyst mixture, removing the catalysts from the dimers/catalyst mixture, and adding hydrogenation catalyst(s) to the dimers under hydrogen atmosphere to produce a mixture of stable fuels.

  制造柴油和涡轮燃料的过程包括提供一定量的一个或多个支链烯烃，并向支链烯烃中添加活性的异质酸催化剂，以产生一个可以无溶剂的混合物。该过程还包括将无溶剂的混合物加热到大约80°C以上的温度，持续一段足够的时间以产生二聚体/催化剂混合物，从二聚体/催化剂混合物中去除催化剂，并在氢气氛下向二聚体中添加加氢催化剂，以产生稳定燃料的混合物。