3-tert-butylperoxy-3-methylbutanal

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-tert-butylperoxy-3-methylbutanal
• 英文别名: 3-(tert-butylperoxy)-3-methylbutyraldehyde；3-t-Butylperoxy-3-methylbutanal
• 化学式: C₉H₁₈O₃
• 分子量: 174.24
• InChiKey: AUZHIOCJZWSHTC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-tert-butylperoxy-3-methylbutanal 在 氧气 作用下， 以0.56 g的产率得到3-tert-butylperoxy-3-methylbutanoic acid
  参考文献：
  名称：

  Synthesis of 4-tert-butylperoxy-4-methylpentan-2-one and 3-tert-butylperoxy-3-methylbutanoic acid

  摘要：

  Alkylation of tert-butyl hydroperoxide with 1,3-diols gave the corresponding hydroxy-containing ditertiary peroxides which were oxidized with pyridinium chlorochromate to carbonyl-containing peroxides. 3-tert-Butylperoxy-3-methylbutanal was oxidized with oxygen at room temperature to obtain 3-tert-butylperoxy-3-methylbutanoic acid.

  DOI：

  10.1134/s1070428013090042
• 作为产物：
  描述：

  异戊二醇 在 高氯酸 、 sodium acetate 、 pyridinium chlorochromate 作用下， 以 二氯甲烷 为溶剂， 反应 16.0h， 生成 3-tert-butylperoxy-3-methylbutanal
  参考文献：
  名称：

  Synthesis of 4-tert-butylperoxy-4-methylpentan-2-one and 3-tert-butylperoxy-3-methylbutanoic acid

  摘要：

  Alkylation of tert-butyl hydroperoxide with 1,3-diols gave the corresponding hydroxy-containing ditertiary peroxides which were oxidized with pyridinium chlorochromate to carbonyl-containing peroxides. 3-tert-Butylperoxy-3-methylbutanal was oxidized with oxygen at room temperature to obtain 3-tert-butylperoxy-3-methylbutanoic acid.

  DOI：

  10.1134/s1070428013090042

文献信息

• US4115455A
  申请人：——

  公开号：US4115455A

  公开（公告）日：1978-09-19
• Synthesis of 4-tert-butylperoxy-4-methylpentan-2-one and 3-tert-butylperoxy-3-methylbutanoic acid
  作者：V. B. Vostres、R. I. Fleichuk、S. A. Voronov、O. I. Gevus’

  DOI：10.1134/s1070428013090042

  日期：2013.9

  Alkylation of tert-butyl hydroperoxide with 1,3-diols gave the corresponding hydroxy-containing ditertiary peroxides which were oxidized with pyridinium chlorochromate to carbonyl-containing peroxides. 3-tert-Butylperoxy-3-methylbutanal was oxidized with oxygen at room temperature to obtain 3-tert-butylperoxy-3-methylbutanoic acid.