bUndBdA-bisEpoxide

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 环氧化物
• 英文名称: bUndBdA-bisEpoxide
• 英文别名: UndBdA-bisEpoxide；9-(oxiran-2-yl)-N-[4-[9-(oxiran-2-yl)nonanoylamino]butyl]nonanamide
• 化学式: C₂₆H₄₈N₂O₄
• 分子量: 452.678
• InChiKey: XKEIOQMEENIDBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  32
• 可旋转键数：
  23
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  83.3
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  二氧化碳 、 bUndBdA-bisEpoxide 在 四丁基溴化铵 作用下， 140.0 ℃ 、6.0 MPa 条件下， 反应 24.0h， 以95%的产率得到UndBdA-b5CC
  参考文献：
  名称：

  Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

  摘要：

  新型基于脂肪酸的双五元碳酸酯，用于非异氰酸酯路线制备聚氨酯。

  DOI：

  10.1039/c4ra03675a
• 作为产物：
  描述：

  10-烯酸甲酯 在 1,5,7-三氮杂双环[4.4.0]癸-5-烯 、 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 反应 30.0h， 生成 bUndBdA-bisEpoxide
  参考文献：
  名称：

  Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s

  摘要：

  新型基于脂肪酸的双五元碳酸酯，用于非异氰酸酯路线制备聚氨酯。

  DOI：

  10.1039/c4ra03675a

文献信息

• Five-membered cyclic biscarbonates bearing amide linkages, their preparation and their uses for the preparation of polyhydroxyurethanes
  申请人：UNIVERSITE DE BORDEAUX I

  公开号：EP2883872A1

  公开（公告）日：2015-06-17

  The invention relates to a compound of formula (I): wherein A1 and A1' are independently from each other a linear or branched alkylene radical comprising from 1 to 20 carbon atom(s); A2 is in particular a linear or branched alkylene radical comprising from 1 to 200 carbon atom(s); A3 is H or a linear or branched alkyl radical comprising from 1 to 15 carbon atom(s) and R1 and R1' are independently from each other H or a linear or branched alkyl radical comprising from 1 to 20 carbon atom(s). The present invention concerns the compounds of formula (I), their preparation and their uses, in particular for the preparation of poly(hydroxyurethane)s.

  本发明涉及一种公式（I）的化合物： 其中A1和A1'独立地彼此为含有1至20个碳原子的线性或支链烷基；A2特别是含有1至200个碳原子的线性或支链烷基；A3是H或含有1至15个碳原子的线性或支链烷基，而R1和R1'独立地彼此为H或含有1至20个碳原子的线性或支链烷基。 本发明涉及公式（I）的化合物，它们的制备以及它们的使用，特别是用于制备聚（羟基聚氨酯）。
• [EN] FIVE-MEMBERED CYCLIC BISCARBONATES BEARING AMIDE LINKAGES, THEIR PREPARATION AND THEIR USES FOR THE PREPARATION OF POLYMERS<br/>[FR] BICARBONATES CYCLIQUES À CINQ CHAÎNONS PORTANT DES LIAISONS AMIDE, LEUR PRÉPARATION ET LEURS UTILISATIONS EN VUE DE LA PRÉPARATION DE POLYMÈRES
  申请人：UNIV BORDEAUX

  公开号：WO2015091494A1

  公开（公告）日：2015-06-25

  The invention relates to a compound of formula (I) wherein and A1 and A1' are independently from each other a linear or branched alkylene radical comprising from 1 to 20 carbon atom(s); A2 is in particular a linear or branched alkylene radical comprising from 1 to 200 carbon atom(s); A3 is H or a linear or branched alkyl radical comprising from 1 to 15 carbon atom(s) and R1 and R1' are independently from each other H or a linear or branched alkyl radical comprising from 1 to 20 carbon atom(s). The present invention concerns the compounds of formula (I), their preparation and their uses, in particular for the preparation of poly(hydroxyurethane)s and epoxy resins.

  本发明涉及一种公式（I）的化合物，其中A1和A1'独立地彼此为含有1至20个碳原子的线性或支链烷基自由基；A2特别是含有1至200个碳原子的线性或支链烷基自由基；A3是H或含有1至15个碳原子的线性或支链烷基自由基，以及R1和R1'独立地彼此为H或含有1至20个碳原子的线性或支链烷基自由基。本发明涉及公式（I）的化合物、它们的制备及其用途，特别是用于制备聚（羟基聚氨酯）和环氧树脂。
• FIVE-MEMBERED CYCLIC BISCARBONATES BEARING AMIDE LINKAGES, THEIR PREPARATION AND THEIR USES FOR THE PREPARATION OF POLYMERS
  申请人：UNIVERSITÉ DE BORDEAUX

  公开号：US20160326132A1

  公开（公告）日：2016-11-10

  A compound is of formula (I): in which A 1 and A 1 ′ are independently from each other a linear or branched alkylene radical including from 1 to 20 carbon atom(s); A 2 is in particular a linear or branched alkylene radical including from 1 to 200 carbon atom(s); A 3 is H or a linear or branched alkyl radical including from 1 to 15 carbon atom(s) and R 1 and R 1 ′ are independently from each other H or a linear or branched alkyl radical comprising from 1 to 20 carbon atom(s). The compounds of formula (I) can be used in particular for the preparation of poly(hydroxyurethane)s and epoxy resins.
• US9926288B2
  申请人：——

  公开号：US9926288B2

  公开（公告）日：2018-03-27
• Novel green fatty acid-based bis-cyclic carbonates for the synthesis of isocyanate-free poly(hydroxyurethane amide)s
  作者：Lise Maisonneuve、Arvind S. More、Stéphanie Foltran、Carine Alfos、Fréderic Robert、Yannick Landais、Thierry Tassaing、Etienne Grau、Henri Cramail

  DOI：10.1039/c4ra03675a

  日期：——

  Novel fatty acid-based bis 5-membered carbonates for a non-isocyante route to polyurethanes.

  新型基于脂肪酸的双五元碳酸酯，用于非异氰酸酯路线制备聚氨酯。