ethyl D-galactopyranosyl-β(1,4)-2-azido-2-deoxy-D-glucopyranoside

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: ethyl D-galactopyranosyl-β(1,4)-2-azido-2-deoxy-D-glucopyranoside
• 英文别名: (2S,3R,4S,5R,6R)-2-[(2R,3S,4R,5R)-5-azido-6-ethoxy-4-hydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol
• 化学式: C₁₄H₂₅N₃O₁₀
• 分子量: 395.367
• InChiKey: OGMCJKKVRPCMRS-RPHKZZMBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.3
• 重原子数：
  27
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  173
• 氢给体数：
  6
• 氢受体数：
  12

反应信息

• 作为产物：
  描述：

  D-吡喃葡萄糖 、 ethyl 2-azido-2-deoxy-D-glucopyranoside 以15%的产率得到ethyl D-galactopyranosyl-β(1,4)-2-azido-2-deoxy-D-glucopyranoside
  参考文献：
  名称：

  Regeneration of sugar nucleotide for enzymic oligosaccharide synthesis: use of Gal-1-phosphate uridyltransferase in the regeneration of UDP-galactose, UDP-2-deoxygalactose, and UDP-galactosamine

  摘要：

  A new multiple enzymatic system containing galactose-1-phosphate uridyltransferase suitable for the regeneration of UDP-Gal, UDP-2-deoxy-Gal, and UDP-galactosamine for the synthesis of N-acetyllactosamine and analogs has been developed.

  DOI：

  10.1021/jo00042a008

文献信息

• Ichikawa, Yoshitaka; Lin, Ying-Chih; Dumas, David P., Journal of the American Chemical Society, 1992, vol. 114, # 24, p. 9283 - 9298
  作者：Ichikawa, Yoshitaka、Lin, Ying-Chih、Dumas, David P.、Shen, Gwo-Jenn、Garcia-Junceda, Eduardo、Williams, Mark A.、Bayer, Robert、Ketcham, Catherine、Walker, Leslie E.、Paulson, James C.、Wong, Chi-Huey

  DOI：——

  日期：——