1-vinyloxy-4-oxatricyclo[4.3.1.13,8]undecan-5-one

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 1-vinyloxy-4-oxatricyclo[4.3.1.13,8]undecan-5-one
• 英文别名: 6-vinyloxy-3-oxatricyclo[4.3.1.14,8]undecan-2-one；1-vinyloxy-4-oxa-tricyclo[4.3.1.1 3,8]undecan-5-one；1-Ethenoxy-4-oxatricyclo[4.3.1.13,8]undecan-5-one
• 化学式: C₁₂H₁₆O₃
• 分子量: 208.257
• InChiKey: NGZBKHKFVNUESG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  5-oxo-4-oxa-5-homoadamantane-1-ol 、 乙酸乙烯酯 在 bis(1,5-cyclooctadiene)diiridium(I) dichloride 、 sodium carbonate 作用下， 以 甲苯 为溶剂， 反应 5.0h， 以72%的产率得到1-vinyloxy-4-oxatricyclo[4.3.1.13,8]undecan-5-one
  参考文献：
  名称：

  Vinyl ether compounds

  摘要：

  公开号：

  EP1826196B1

文献信息

• Process for producing vinyl ether compounds
  申请人：——

  公开号：US20030083529A1

  公开（公告）日：2003-05-01

  A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): 1 wherein R 1 , R 2 , R 3 and R 4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2): R 5 OH  (2) wherein R 5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): 2 wherein R 2 , R 3 , R 4 and R 5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements.

  该过程生产乙烯醚化合物，包括使得由以下化学式（1）表示的乙烯酯化合物发生反应：其中R1、R2、R3和R4相同或不同，每个都是氢原子或有机基团，与由以下化学式（2）表示的羟基化合物反应：其中R5是有机基团，在至少一种过渡元素化合物存在下，从而产生由以下化学式（3）表示的乙烯醚化合物：其中R2、R3、R4和R5的含义与上述定义相同。这样的过渡元素化合物包括铱化合物和其他含有第VIII族元素的化合物。
• Polymerizable monomer polymeric compound resin compositions for photoresist and method for producing semiconductor
  申请人：Koyama Hiroshi

  公开号：US20060058480A1

  公开（公告）日：2006-03-16

  A polymerizable monomer of the present invention is represented by the following formula (1); R 1 , R 2 and R 3 are each a hydrogen atom, a fluorine atom, an alkyl group or a fluoroalkyl group, W is a single bond or a linkage group and n is 0 or 1, where at least one of R 1 , R 2 and R 3 is a fluorine atom or a fluoroalkyl group when n= 1; and the ring in the formula may have a substituent. The polymerizable monomer of the present invention can provide an appropriate hydrophilicity or hydrophilicity and transparency to a photoresist polymer.

  本发明的可聚合单体由以下公式（1）表示；其中，R1、R2和R3分别为氢原子、氟原子、烷基或氟烷基，W为单键或连接基，n为0或1，当n=1时，R1、R2和R3中至少有一个为氟原子或氟烷基；公式中的环可能具有取代基。本发明的可聚合单体能够为光刻胶聚合物提供适当的亲水性或亲疏水性和透明度。
• Vinyl ether compounds and preparation process thereof
  申请人：Daicel Chemical Industries, Ltd.

  公开号：EP1288186A2

  公开（公告）日：2003-03-05

  A process produces vinyl ether compounds and includes allowing a vinyl ester compound represented by following Formula (1): wherein R1, R2, R3 and R4 are the same or different and are each a hydrogen atom or an organic group, to react with a hydroxy compound represented by following Formula (2):         R5OH     (2) wherein R5 is an organic group, in the presence of at least one transition element compound to thereby yield a vinyl ether compound represented by following Formula (3): wherein R2, R3, R4 and R5 have the same meanings as defined above. Such transition element compounds include iridium compounds and other compounds containing Group VIII elements. A vinyl ether compound represented by following Formula (4): wherein W is a divalent hydrocarbon; n is 0 or 1; m is an integer from 1 to 8; ring Z is any one of cyclic groups represented by following Formulae (5) through (12):

  一种生产乙烯基醚化合物的工艺，包括让下式（1）代表的乙烯基酯化合物与下式（2）代表的羟基化合物反应： 其中 R1、R2、R3 和 R4 相同或不同，且各自为氢原子或有机基团，与下式（2）所代表的羟基化合物反应： R5OH (2) 其中 R5 为有机基团，在至少一种过渡元素化合物存在的情况下，生成下式 (3) 所代表的乙烯基醚化合物： 其中 R2、R3、R4 和 R5 的含义与上述定义相同。此类过渡元素化合物包括铱化合物和其他含有第八族元素的化合物。 由下式（4）表示的乙烯基醚化合物： 其中 W 为二价烃；n 为 0 或 1；m 为 1 至 8 的整数；环 Z 为下式（5）至（12）所代表的任一环状基团：
• Method for producing antifouling film
  申请人：Sharp Kabushiki Kaisha

  公开号：US11142653B2

  公开（公告）日：2021-10-12

  The present invention provides a method for producing an antifouling film having excellent antifouling properties and rubbing resistance. The method for producing an antifouling film of the present invention includes Process (1) of applying a resin to a surface of a substrate; Process (2) of pushing the substrate to a die with the resin in between to form an uneven structure on a surface of the resin; and Process (3) of curing the resin including the uneven structure on the surface thereof to form a polymer layer. The resin contains an antifouling agent that contains a compound containing a perfluoro(poly)ether group. The die includes a surface having undergone release treatment using a release agent containing a compound that contains a perfluoro(poly)ether group, a hydrolyzable group, and a Si atom.

  本发明提供了一种生产具有优异防污性能和耐摩擦性的防污膜的方法。本发明的防污膜生产方法包括：工序(1)将树脂涂抹在基材表面；工序(2)将基材推向模具，中间夹入树脂，在树脂表面形成不均匀结构；工序(3)固化树脂，包括其表面的不均匀结构，形成聚合物层。树脂中含有一种防污剂，该防污剂含有一种含有全氟（聚）醚基团的化合物。模具包括使用脱模剂对表面进行脱模处理的表面，脱模剂含有一种含有全氟（聚）醚基、可水解基团和硅原子的化合物。
• FLUORINE-ATOM-CONTAINING POLYMERIZABLE UNSATURATED-MONOMER, FLUORINE-ATOM-CONTAINING POLYMERIC COMPOUND AND PHOTORESIST RESIN COMPOSITION
  申请人：Koyama Hiroshi

  公开号：US20050282985A1

  公开（公告）日：2005-12-22

  A fluorine-atom-containing polymerizable unsaturated-monomer of the present invention is represented by the following formula (1a) or (1b): wherein each of a ring Z 1 and a ring Z 2 is an alicyclic carbon ring; when the alicyclic carbon ring is multi-cyclic, a part of atoms constituting the ring may be substituted by an oxygen atom, a sulfur atom or a nitrogen atom; an atom constituting the ring Z 1 and the ring Z 2 may have a substituent; each of R 1 , R 2 and R 3 is an alkyl group or a fluoroalkyl group; R is an specific unsaturated acyl group; provided that at least one of R 1 and R 2 is a fluorine atom or a fluoroalkyl group in the formula (1a), and in the formula (1b) (i) the ring Z 2 is bonded by a fluorine atom or a fluoroalkyl group, or (ii) R 3 is a fluoroalkyl group.

  本发明的含氟原子可聚合不饱和单体由下式(1a)或(1b)表示： 其中每个环 Z 1 和环 Z 2 为脂环碳环；当脂环碳环为多环时，构成环的部分原子可被氧原子、硫原子或氮原子取代；构成环 Z 1 和环 Z 2 中的每个 R 1 , R 2 和 R 3 是烷基或氟烷基； R 是特定的不饱和酰基；条件是 R 1 和 R 2 在式(1a)中至少有一个是氟原子或氟烷基，在式(1b)中 (i) 环 Z 2 由氟原子或氟烷基键合，或 (ii) R 3 是氟烷基。