3,4,5-tris(nonyloxy)benzaldehyde

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 英文名称: 3,4,5-tris(nonyloxy)benzaldehyde
• 英文别名: 3,4,5-trinonyloxybenzaldehyde；3,4,5-tri(nonoxy)benzaldehyde
• 化学式: C₃₄H₆₀O₄
• 分子量: 532.848
• InChiKey: QZCNHCCWALUCCK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.2
• 重原子数：
  38
• 可旋转键数：
  28
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3,4,5-tris(nonyloxy)benzaldehyde 在 palladium diacetate potassium tert-butylate 、 三乙胺 作用下， 以 乙二醇二甲醚 、 甲苯 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  Electroluminescent Liquid Crystals

  摘要：

  DOI：

  10.1080/10587250108029956
• 作为产物：
  描述：

  1-溴壬烷 在 manganese(IV) oxide 、 lithium aluminium tetrahydride 、 potassium carbonate 、 potassium hydroxide 作用下， 以 四氢呋喃 、 甲醇 、 氯仿 、 水 、 N,N-二甲基甲酰胺 为溶剂， 生成 3,4,5-tris(nonyloxy)benzaldehyde
  参考文献：
  名称：

  Room Temperature Liquid Porphyrins

  摘要：

  报道了5,10,15,20-四(3,4,5-三烷氧基苯基)卟啉的合成，这些化合物在室温下表现出流态行为。热物性和流变学测量表明，它们在25°C（298 K）时表现得像液体。

  DOI：

  10.1246/cl.2010.714

文献信息

• <i>s</i>-Triazine-Based Functional Discotic Liquid Crystals: Synthesis, Mesomorphism and Photoluminescence
  作者：B. N. Veerabhadraswamy、Hashambi K. Dambal、D. S. Shankar Rao、C. V. Yelamaggad

  DOI：10.1002/cphc.201600280

  日期：2016.7.18

  Examination of the phase transitional properties by several complementary techniques evidenced self‐assembly into a hexagonal columnar phase, occurring over wide and reasonable thermal ranges. The photophysical properties were studied both in solution and in the fluid/frozen columnar states by UV/Vis absorption and photoluminescence spectroscopy. The emission spectra obtained as a function of the temperature

  设计，合成和表征了一系列新的C 3对称，π共轭分子。将所述材料从电子接受衍生小号嗪，共价附加到供电子苯乙烯基苯臂，并通过与三膦酸酯的三倍缩合的方法在以高纯度优异的产率容易地制备ÑHorner-Wadsworth-Emmons反应条件下的链烷氧基苯甲醛。通过几种补充技术对相变性质的研究证明了自组装成六方柱状相的过程，发生在较宽且合理的温度范围内。通过UV / Vis吸收和光致发光光谱学研究了溶液和流体/冻结柱状状态下的光物理性质。根据温度获得的发射光谱排除了较大色谱柱的破裂和无辐射的热活化过程。在原子力显微镜（AFM）图像的帮助下，对玻璃态柱状薄膜进行了研究，该薄膜解释了保守的荧光，无缺陷的取向和冻结的离子种类，提出包括纤维状结构的均质颗粒形态。拉曼光谱清楚地表明了固态和冷冻柱状薄膜的表面形态和双折射的差异。电化学研究表明，LUMO能量为-4.0 eV。因此，本文提出的盘状图案满足有机材料的
• <i>Meso</i>-Substituted Liquid Porphyrins
  作者：Agnieszka Nowak-Król、Dorota Gryko、Daniel T. Gryko

  DOI：10.1002/asia.200900693

  日期：2010.4.1

  Meso‐substituted A4‐porphyrins bearing 3,4,5‐trialkoxyphenyl substituents are efficiently synthesized and characterized. Porphyrins bearing twelve C10 and C11 alkyl chains turned out to be liquid at room temperature. The remaining porphyrins, bearing C8, C9, C12, and C18 alkyl chains, have low melting points and high solubility in nonpolar solvents. Their differential scanning calorimetry distinctly

  高效合成并表征了带有3,4,5-三烷氧基苯基取代基的内消旋A 4卟啉。带有十二个C10和C11烷基链的卟啉在室温下变成液态。其余带有C8，C9，C12和C18烷基链的卟啉具有低熔点和在非极性溶剂中的高溶解度。在大多数情况下，它们的差示扫描量热法清楚地显示出只有一个相变。
• LIQUID PORPHYRIN DERIVATIVE, AND METHOD FOR PRODUCING THE SAME
  申请人：Maruyama Sumio

  公开号：US20110046366A1

  公开（公告）日：2011-02-24

  The present invention is to provide a liquid porphyrin derivative at 25° C. and at temperatures from 26 to 40° C., and a method for producing the same. The liquid porphyrin derivative of the present invention is represented by the following formula (1): wherein M represents 2H (hydrogen atoms) or an atom or compound capable of binding covalently or coordinately to tetraphenylporphyrin; each of R 1 , R 2 , and R 3 independently represents a hydrogen atom, or an alkoxy group having 7 to 14 or 15 carbon atoms represented by OR 4 ; R 4 represents a substituted or unsubstituted alkyl group having 7 to 14 or 15 carbon atoms; and all the R 1 s, all the R 2 s, and all the R 3 s are respectively the same; and there are cases where the R 2 s and the R 3 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 , and the R 1 s are hydrogen atoms, where the R 1 s and the R 3 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 , and the R 2 s are hydrogen atoms, where the R 1 s and the R 2 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 , and the R 3 s are hydrogen atoms, and where the R 1 s, the R 2 s and the R 3 s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR 4 .

  本发明提供了一种在25℃和26℃至40℃温度下的液态卟吩衍生物以及其制备方法。本发明的液态卟吩衍生物由以下式子（1）表示：其中M代表2H（氢原子）或能够共价或配位地结合四苯基卟吩的原子或化合物；每个R1、R2和R3独立地表示氢原子，或由OR4表示的具有7至14或15个碳原子的烷氧基；R4表示具有7至14或15个碳原子的取代或未取代的烷基基团；所有的R1、所有的R2和所有的R3分别相同；有时R2和R3是由OR4表示的具有7至14或15个碳原子的烷氧基，而R1是氢原子；或者R1和R3是由OR4表示的具有7至14或15个碳原子的烷氧基，而R2是氢原子；或者R1和R2是由OR4表示的具有7至14或15个碳原子的烷氧基，而R3是氢原子；或者R1、R2和R3均为由OR4表示的具有7至14或15个碳原子的烷氧基。
• CHALCONE DERIVATIVE COMPOUNDS
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0328669A1

  公开（公告）日：1989-08-23

  Chalcone derivative compounds represented by general formula (I) or (II), wherein R₁ and R₂ each represents a ha­logen atom, a hydroxy group, an amino group, a dimethylamino group, a nitro group, a cyano group, a phenyl group, an acetyl group, an alkyl group containing 1 to 18 carbon atoms or an alkyloxy group containing 1 to 22 carbon atoms, n₁ and n₂ each represents an integer of 0 to 21, and m₁ and m₂ each represents an integer of 0 to 5.

  通式(I)或(II)代表的查耳酮衍生物化合物，其中 R₁ 和 R₂ 各自代表卤素原子、羟基、氨基、二甲基氨基、硝基、氰基、苯基、乙酰基、含 1 至 18 个碳原子的烷基或含 1 至 22 个碳原子的烷氧基，n₁ 和 n₂ 各自代表整数、乙酰基、含 1 至 18 个碳原子的烷基或含 1 至 22 个碳原子的烷氧基，n₁ 和 n₂ 各自代表 0 至 21 的整数，m₁ 和 m₂ 各自代表 0 至 5 的整数。
• LIQUID PORPHYRIN DERIVATIVE AND METHOD FOR PRODUCING THE SAME
  申请人：Dai Nippon Printing Co., Ltd.

  公开号：EP2253634A1

  公开（公告）日：2010-11-24

  The present invention is to provide a liquid porphyrin derivative at 25 °C and at temperatures from 26 to 40 °C, and a method for producing the same. The liquid porphyrin derivative of the present invention is represented by the following formula (1): wherein M represents 2H (hydrogen atoms) or an atom or compound capable of binding covalently or coordinately to tetraphenylporphyrin; each of R1, R2, and R3 independently represents a hydrogen atom, or an alkoxy group having 7 to 14 or 15 carbon atoms represented by OR4; R4 represents a substituted or unsubstituted alkyl group having 7 to 14 or 15 carbon atoms; and all the R1s, all the R2s, and all the R3s are respectively the same; and there are cases where the R2s and the R3s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4, and the R1s are hydrogen atoms, where the R1s and the R3s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4, and the R2s are hydrogen atoms, where the R1s and the R2s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4, and the R3s are hydrogen atoms, and where the R1s, the R2s and the R3s are the alkoxy groups having 7 to 14 or 15 carbon atoms represented by OR4.

  本发明旨在提供一种在 25℃和 26 至 40℃温度下的液态卟啉衍生物及其生产方法。本发明的液态卟啉衍生物由下式（1）表示： 其中 M 代表 2H（氢原子）或能与四苯基卟啉共价结合或配位结合的原子或化合物； R1、R2 和 R3 各自独立地代表氢原子或由 OR4 代表的具有 7 至 14 或 15 个碳原子的烷氧基； R4 代表具有 7 至 14 或 15 个碳原子的取代或未取代的烷基；且所有 R1、所有 R2 和所有 R3 分别相同；在某些情况下，R2s 和 R3s 是由 OR4 表示的具有 7 至 14 或 15 个碳原子的烷氧基，而 R1s 是氢原子，其中 R1s 和 R3s 是由 OR4 表示的具有 7 至 14 或 15 个碳原子的烷氧基、R2s 为氢原子，其中 R1s 和 R2s 为具有 7 至 14 或 15 个碳原子的烷氧基，由 OR4 表示，R3s 为氢原子，其中 R1s、R2s 和 R3s 为具有 7 至 14 或 15 个碳原子的烷氧基，由 OR4 表示。