申请人:Chisso Corporation
公开号:EP0416321A1
公开(公告)日:1991-03-13
A crystalline polyolefin composition which provides molded articles having improved stiffness characteristics is disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I):
wherein R represents an alkylidene group having from 1 to 4 carbon atoms or a sulfur atom; Ar1 and Ar2, which may be the same or different, each represents an alkylarylene group or a cycloalkylarylene group; and n represents 0 or 1, and (B) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with lithium or sodium, (2) a dithiocarbamic acid salt with lithium, sodium or potassium, (3) a 2-mercaptobenzothiazole salt with lithium, sodium or potassium, (4) a 2-mercaptobenzimidazole salt with lithium, sodium or potassium and (5) a benzotriazole salt with lithium, sodium or potassium.
A crystalline polyolefin composition which provides molded articles having improved stiffness charateristics is also disclosed, comprising 100 parts by weight of a crystalline polyolefin, (A) from 0.001 to 1 part by weight of a fluorophosphite compound represented by formula (I) shown above, (B ) from 0.001 to 1 part by weight of at least one compound selected from the group consisting of (1) an aliphatic monocarboxylic acid salt with potassium, strontium or barium, (2) a hydroxy-higher fatty acid salt with potassium, strontium or barium, (3) an aliphatic polycarboxylic acid salt with lithium, sodium, potassium, strontium or barium, (4) a salt of an aliphatic hydroxy acid having form 2 to 6 carbon atoms with lithium, sodium, potassium, magnesium, strontium or barium, (5) an aromatic carboxylic acid salt with lithium, sodium, strontium, barium or aluminum, (6) a glutamic acid salt with lithium, sodium, potassium, strontium or barium, (7) an aliphatic phosphoric acid salt with sodium, potassium, calcium, strontium or barium, (8) a lithium, sodium, potassium or barium salt of a cyclic phosphorus compound represented by formula (II):
wherein Ar3 and Ar4, which may be the same or different, each represents an arylene group, an alkylarylene group, a cycloalkylarylene group, an arylarylene group or an aralkylarylene group; M represents lithium, sodium, potassium or barium; and m represents an atomic valence of M, (9) magnesium or aluminum hydroxide, (10) magnesium oxide, (11) magnesium or calcium carbonate and (12) hydrotalcite, and (C) from 0.01 to 1 part by weight of an aliphatic amine.
本发明公开了一种结晶聚烯烃组合物,该组合物可提供具有改进的刚度特性的模塑制品,该组合物包括按重量计100份的结晶聚烯烃、(A)按重量计0.001至1份的由式(I)代表的亚磷酸氟化合物:
其中 R 代表具有 1 至 4 个碳原子的亚烷基或硫原子;Ar1 和 Ar2 可以相同或不同,各自代表烷基芳基或环烷基芳基;n 代表 0 或 1,以及 (B) 0.(1) 锂或钠的脂肪族一羧酸盐,(2) 锂、钠或钾的二硫代氨基甲酸盐、(3) 锂、钠或钾的 2-巯基苯并噻唑盐, (4) 锂、钠或钾的 2-巯基苯并咪唑盐, (5) 锂、钠或钾的苯并三唑盐。
本发明还公开了一种结晶聚烯烃组合物,该组合物可提供具有改进的刚度特性的模塑制品,其成分包括 100 份(重量)结晶聚烯烃、(A) 0.001 至 1 份(重量)由上文式(I)代表的亚磷酸氟化合物、(B ) 0.(1)钾、锶或钡的脂肪族一羧酸盐;(2)钾、锶或钡的羟基高级脂肪酸盐;(3)锂、钠、钾、锶或钡的脂肪族多羧酸盐;(4)锂、钠、钾、镁、锶或钡的具有 2 至 6 个碳原子的脂肪族羟基酸盐、(5) 锂、钠、锶、钡或铝的芳香族羧酸盐; (6) 锂、钠、钾、锶或钡的谷氨酸盐、(7) 含有钠、钾、钙、锶或钡的脂肪族磷酸盐, (8) 由式(II)代表的环磷化合物的锂、钠、钾或钡盐:
其中 Ar3 和 Ar4 可以相同或不同,各自代表芳基、烷芳基、环烷芳基、芳基芳基或芳基芳基;M 代表锂、钠、钾或钡;m 代表 M 的原子价,(9) 氢氧化镁或铝,(10) 氧化镁,(11) 碳酸镁或碳酸钙和 (12) 水滑石,以及 (C) 0.01至1份重量的脂肪族胺。