5-methyleneundeca-1,10-diene

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 5-methyleneundeca-1,10-diene
• 英文别名: 5-Methylideneundeca-1,10-diene
• 化学式: C₁₂H₂₀
• 分子量: 164.291
• InChiKey: ZLFJJQGQGCSFQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1,5-已二烯 在 [Ni{1-N(PMes2)-2-N(μ-PMes2)C6H4-κ³N,N',P,-κ¹P'}]2 Bis(dimethylaluminium)oxid 作用下， 以 甲苯 为溶剂， 反应 4.0h， 以50%的产率得到5-methyleneundeca-1,10-diene
  参考文献：
  名称：

  Oligomerization of α-olefins by the dimeric nickel bisamido complex [Ni{1-N(PMes2)-2-N(μ-PMes2)C6H4-κ3N,N′,P,-κ1P′}]2 activated by methylalumoxane (MAO)

  摘要：

  l The reaction of Li-2[1,2-{N(PMes(2))}(2)C6H4], formed in situ from n-BuLi and the corresponding amines, with 1 equiv. of [NiBr2(DME)] gives [Ni{1-N(PMes(2))-2-N(mu-PMes(2))C6H4-kappa N-3,N',P-kappa P-1'}](2) (1). After activation by methylalumoxane (MAO), 1 is a highly active catalyst in the oligomerization and isomerization of alpha-olefins such as ethene, propene, isobutene, 1-hexene and 1,5-hexadiene. For ethene oligomerization turnover frequencies (TOFs) range from 3000 to 79015 h (1), depending on the reaction conditions. The TOF for propene oligomerization reaches 1190730 h (1). To our knowledge, catalyst 1, activated by MAO, is the most active catalyst for the oligomerization of propene and outperforms the best known complexes for this reaction. In the reactions with 1-hexene, 1,5-hexadiene and isobutene dimerization and isomerization products were observed. (C) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.05.004

文献信息

• Oligomerization of α-olefins by the dimeric nickel bisamido complex [Ni{1-N(PMes2)-2-N(μ-PMes2)C6H4-κ3N,N′,P,-κ1P′}]2 activated by methylalumoxane (MAO)
  作者：Felicite Majoumo-Mbe、Peter Lönnecke、Victoria Volkis、Manab Sharma、Moris S. Eisen、Evamarie Hey-Hawkins

  DOI：10.1016/j.jorganchem.2008.05.004

  日期：2008.7

  l The reaction of Li-2[1,2-N(PMes(2))}(2)C6H4], formed in situ from n-BuLi and the corresponding amines, with 1 equiv. of [NiBr2(DME)] gives [Ni1-N(PMes(2))-2-N(mu-PMes(2))C6H4-kappa N-3,N',P-kappa P-1'}](2) (1). After activation by methylalumoxane (MAO), 1 is a highly active catalyst in the oligomerization and isomerization of alpha-olefins such as ethene, propene, isobutene, 1-hexene and 1,5-hexadiene. For ethene oligomerization turnover frequencies (TOFs) range from 3000 to 79015 h (1), depending on the reaction conditions. The TOF for propene oligomerization reaches 1190730 h (1). To our knowledge, catalyst 1, activated by MAO, is the most active catalyst for the oligomerization of propene and outperforms the best known complexes for this reaction. In the reactions with 1-hexene, 1,5-hexadiene and isobutene dimerization and isomerization products were observed. (C) 2008 Elsevier B.V. All rights reserved.