2,9-di(n-dodecyl)-1,3,8,10-tetrahydro-2,9-diazadibenzo[cd,lm]perylene

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 2,9-di(n-dodecyl)-1,3,8,10-tetrahydro-2,9-diazadibenzo[cd,lm]perylene
• 英文别名: 7,18-Didodecyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene；7,18-didodecyl-7,18-diazaheptacyclo[14.6.2.22,5.03,12.04,9.013,23.020,24]hexacosa-1(23),2,4,9,11,13,15,20(24),21,25-decaene
• 化学式: C₄₈H₆₆N₂
• 分子量: 671.065
• InChiKey: WNVMNONQIOFBNB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.7
• 重原子数：
  50
• 可旋转键数：
  22
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.58
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  tetrabenzyl perylene-3,4,9,10-tetracarboxylate 在 盐酸 、 二异丁基氢化铝 、 三乙胺 作用下， 以 四氢呋喃 、 二氯甲烷 、 溶剂黄146 、 甲苯 为溶剂， 反应 26.0h， 生成 2,9-di(n-dodecyl)-1,3,8,10-tetrahydro-2,9-diazadibenzo[cd,lm]perylene
  参考文献：
  名称：

  1,3,8,10-Tetrahydro-2,9-diazadibenzo[cd,lm]perylenes: synthesis of reduced perylene bisimide analogues

  摘要：

  A unique family of 1,3,8,10-tetrahydro-2,9-diazadibenzo[cd,lm]perylenes (THDAP) was prepared through a new synthetic strategy. Completion of the synthesis was achieved in several steps from commercially available perylene-3,4,9,10-tetracarboxylic dianhydride via reactions between 3,4,9, 10-tetra(chloromethyl)perylene and primary amines. The successful use of a variety of primary amines in the reauions indicated that the synthetic approach provides a rich opportunity to produce new functionalized perylene derivatives. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.11.100

文献信息

• 1,3,8,10-Tetrahydro-2,9-diazadibenzo[cd,lm]perylenes: synthesis of reduced perylene bisimide analogues
  作者：Masaki Takahashi、Yousuke Suzuki、Yasunori Ichihashi、Mitsuji Yamashita、Hideki Kawai

  DOI：10.1016/j.tetlet.2006.11.100

  日期：2007.1

  A unique family of 1,3,8,10-tetrahydro-2,9-diazadibenzo[cd,lm]perylenes (THDAP) was prepared through a new synthetic strategy. Completion of the synthesis was achieved in several steps from commercially available perylene-3,4,9,10-tetracarboxylic dianhydride via reactions between 3,4,9, 10-tetra(chloromethyl)perylene and primary amines. The successful use of a variety of primary amines in the reauions indicated that the synthetic approach provides a rich opportunity to produce new functionalized perylene derivatives. (c) 2006 Elsevier Ltd. All rights reserved.