菲<2,3-B>噻吩 | 224-07-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 中文名称: 菲<2,3-B>噻吩
• 英文名称: phenanthro<2,3-b>thiophene
• 英文别名: phenanthro[2,3-b]thiophene；naphtho[1,2-f][1]benzothiole
• CAS: 224-07-7
• 化学式: C₁₆H₁₀S
• 分子量: 234.321
• InChiKey: PUDWJHJHVOOWEE-UHFFFAOYSA-N

物化性质

• 沸点：
  440.7±14.0 °C(Predicted)
• 密度：
  1.292±0.06 g/cm3(Predicted)
• 熔点：
  161-161.5 °C(Solv: cyclohexane (110-82-7))
• 保留指数：
  399.9;400.8;400.8;402.13;402.19

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  17
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-(Naphthalen-2-ylmethyl)thiophene-3-carbaldehyde 在 PPA 作用下， 反应 0.25h， 以56%的产率得到菲<2,3-B>噻吩
  参考文献：
  名称：

  菲并[ b ]噻吩的合成

  摘要：

  母菲并[ b ]噻吩的所有异构体，即菲[1,2- b ]噻吩，菲-[2,1- b ]噻吩，菲[2,3- b ]噻吩，菲[3,4-]合成了b ]噻吩，菲[3,4- b ]噻吩，菲[4,3- b ]噻吩和菲[9,10- b ]噻吩。

  DOI：

  10.1002/jhet.5570170623

文献信息

• Process for production of vinyl chloride polymer
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP0172427A2

  公开（公告）日：1986-02-26

  This process is a process for production of a vinyl chloride polymer by suspension polymerization or emulsion polymerization of vinyl chloride monomer or a mixture of vinyl chloride monomer with a vinyl monomer copolymerizable with said vinyl chloride monomer in an aqueous medium, characterized in that the polymerization is carried out in a polymerizer, the inner wall surface and portions of the auxiliary equipment thereof which may come into contact with the monomer during polymerization being previously coated with a scaling preventive comprising at least one selected from dyes, pigments and aromatic or heterocyclic compounds having at least 5 conjugated π bonds, while controlling the chloride ion concentration in the reaction mixture to not higher than 100 ppm. According to said process, scaling onto the inner wall surface of a polymerizer, etc. during polymerization can be prevented effectively and surely.

  该工艺是通过氯乙烯单体或氯乙烯单体与可与所述氯乙烯单体共聚的乙烯基单体混合物在水介质中进行悬浮聚合或乳液聚合来生产氯乙烯聚合物的工艺，其特征在于聚合是在聚合器中进行的、内壁表面及其辅助设备中可能在聚合过程中与单体接触的部分事先涂上一层防垢剂，该防垢剂至少包括一种选自染料、颜料和至少有 5 个共轭 π 键的芳香族或杂环化合物的防垢剂，同时控制反应混合物中的氯离子浓度不高于 100 ppm。根据上述工艺，可有效、可靠地防止聚合过程中聚合器等内壁表面结垢。
• ORGANIC ELECTROLUMINESCENT DEVICE
  申请人：TDK Corporation

  公开号：EP0857007A1

  公开（公告）日：1998-08-05

  In an organic EL device, a light emitting layer contains a specific coumarin derivative, and a hole injecting and/or transporting layer contains a specific tetraaryldiamine derivative. Also a light emitting layer in the form of a mix layer contains a specific coumarin derivative, a specific quinacridone compound or a specific styryl amine compound. There are provided at least two light emitting layers including a light emitting layer of the mix layer type wherein at least two dopants are contained so that at least two luminescent species may emit light. There is obtained an organic EL device capable of high luminance and continuous light emission and ensuring reliability. Multi-color light emission becomes possible.

  在有机电致发光器件中，发光层含有特定的香豆素衍生物，空穴注入和/或传输层含有特定的四芳基二胺衍生物。此外，混合层形式的发光层包含特定的香豆素衍生物、特定的喹吖啶酮化合物或特定的苯乙烯胺化合物。本发明提供了至少两个发光层，包括混合层类型的发光层，其中包含至少两种掺杂剂，从而至少有两种发光物质可以发光。这样就得到了一种有机 EL 器件，它能够实现高亮度和连续发光，并确保可靠性。多色发光成为可能。
• ORGANIC ELECTROLUMINESCENCE DEVICE AND ORGANIC LUMINESCENT MEDIUM
  申请人：IDEMITSU KOSAN CO., LTD.

  公开号：EP1191822A1

  公开（公告）日：2002-03-27

  An electroluminescence device comprising a pair of electrodes and a layer of an organic light emitting medium disposed between the pair of electrodes, wherein the layer of an organic light emitting medium comprises (A) at least one electron transporting compound and (B) an anthracene derivative having a specific structure and an organic light emitting medium comprising the above components (A) and (B). The device exhibits excellent heat resistance, has a long life time and provides efficient light emission. The organic light emitting medium is advantageously used for the organic EL device

  一种电致发光装置，包括一对电极和置于这对电极之间的一层有机发光介质，其中有机发光介质层包括(A) 至少一种电子传输化合物和(B) 具有特定结构的蒽衍生物，以及由上述组分(A)和(B)组成的有机发光介质。该装置具有优异的耐热性、较长的使用寿命和高效的发光性能。有机发光介质用于有机 EL 器件的优点是
• Organic electroluminescent compounds and organic electroluminescent device comprising the same
  申请人：ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD.

  公开号：US11527728B2

  公开（公告）日：2022-12-13

  The present disclosure relates to organic electroluminescent compounds, and a host material, an electron buffer material, an electron transport material and an organic electroluminescent device comprising the same. By using the organic electroluminescent compounds of the present disclosure, the organic electroluminescent device secures fast electron current properties by intermolecular stacking and interaction, and thus, it is possible to provide the organic electroluminescent device having low driving voltage and/or excellent luminous efficiency and/or efficient lifespan properties.

  本公开涉及有机电致发光化合物，以及由其构成的宿主材料、电子缓冲材料、电子传输材料和有机电致发光器件。通过使用本公开的有机电致发光化合物，有机电致发光器件可通过分子间的堆叠和相互作用确保快速电子流特性，从而可提供具有低驱动电压和/或优异发光效率和/或高效寿命特性的有机电致发光器件。
• Organic EL device
  申请人：TDK CORPORATION

  公开号：US20020038867A1

  公开（公告）日：2002-04-04

  In an organic EL device, a light emitting layer contains a specific coumarin derivative, and a hole injecting and/or transporting layer contains a specific tetraaryldiamine derivative. Also a light emitting layer in the form of a mix layer contains a specific coumarin derivative, a specific quinacridone compound or a specific styryl amine compound. There are provided at least two light emitting layers including a light emitting layer of the mix layer type wherein at least two dopants are contained so that at least two luminescent species may emit light. There is obtained an organic EL device capable of high luminance and continuous light emission and ensuring reliability. Multi-color light emission becomes possible.

  在有机电致发光器件中，发光层含有特定的香豆素衍生物，空穴注入和/或传输层含有特定的四芳基二胺衍生物。此外，混合层形式的发光层包含特定的香豆素衍生物、特定的喹吖啶酮化合物或特定的苯乙烯胺化合物。本发明提供了至少两个发光层，包括混合层类型的发光层，其中包含至少两种掺杂剂，从而至少有两种发光物质可以发光。这样就得到了一种有机 EL 器件，它能够实现高亮度和连续发光，并确保可靠性。多色发光成为可能。