2,4,6-tributyldodecene-1

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 2,4,6-tributyldodecene-1
• 英文别名: 7,9-Dibutyl-5-methylidenepentadecane
• 化学式: C₂₄H₄₈
• 分子量: 336.645
• InChiKey: RWOCQRIVMXTYLM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.1
• 重原子数：
  24
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  1-己烯 生成 2,4,6-tributyldodecene-1
  参考文献：
  名称：

  KAMINSKY, WALTER;MOLLER-LINDENHOF, NICO;AHLERS, AURELIA

  摘要：

  DOI：

文献信息

• Structurally uniform 1-hexene, 1-octene, and 1-decene oligomers: Zirconocene/MAO-catalyzed preparation, characterization, and prospects of their use as low-viscosity low-temperature oil base stocks
  作者：Ilya E. Nifant’ev、Alexander A. Vinogradov、Alexey A. Vinogradov、Igor V. Sedov、Viktor G. Dorokhov、Anton S. Lyadov、Pavel V. Ivchenko

  DOI：10.1016/j.apcata.2017.09.016

  日期：2018.1

  alkanes, and higher oligomers. Trimers, tetramers, and pentamers of 1-hexene, 1-octene, and 1-decene were isolated as individual compounds and were hydrogenated. Viscosity characteristics of the isolated saturated and unsaturated hydrocarbons have been studied at various temperatures. The isolated saturated oligomers of 1-octene and 1-decene outperform the traditional electrophilic oligomerization

  已经阐述了用于这种反应的原始的α-烯烃低聚方法以及新型的热稳定的锆茂催化剂。报告的方法可以实现轻质α-烯烃低聚物的馏分，产率高达90％，而不会大量形成副产物，如内部烯烃，烷烃和高级低聚物。分离出1-己烯，1-辛烯和1-癸烯的三聚体，四聚体和五聚体作为单独的化合物并进行氢化。已经在各种温度下研究了分离的饱和和不饱和烃的粘度特性。分离的1-辛烯和1-癸烯饱和低聚物在粘度指数，倾点和低温粘度方面优于传统的亲电子低聚产物。
• Catalytic oligomerization of α-olefins in the presence of two-stage activated zirconocene catalyst based on 6,6-dimethylfulvene ‘dimer’
  作者：Ilya E. Nifant’ev、Alexey A. Vinogradov、Alexander A. Vinogradov、Stanislav I. Bezzubov、Pavel V. Ivchenko

  DOI：10.1016/j.mencom.2017.01.010

  日期：2017.1

  Zirconocene obtained from 6,6-dimethylfulvene 'dimer', being activated subsequently with triisobutylaluminium and methylalumoxane, catalyzes transformation of alpha-olefins into a mixture of vinylidene oligomers with minimal losses to isomerization, which allows one to consider this catalyst perspective for the synthesis of branched hydrocarbons with uniform structure.