3-(diallylamino)-1,1-bis(ethylthio)-1-propene

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3-(diallylamino)-1,1-bis(ethylthio)-1-propene
• 英文别名: 3,3-bis(ethylsulfanyl)-N,N-bis(prop-2-enyl)prop-2-en-1-amine
• 化学式: C₁₃H₂₃NS₂
• 分子量: 257.464
• InChiKey: JPUCTRYOWCPMSX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  53.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  聚合甲醛 、 二烯丙基胺 、 1,1-bis(ethylthio)-2-trimethylsilylethene 在 对甲苯磺酸 作用下， 以 乙腈 为溶剂， 反应 1.5h， 以67%的产率得到3-(diallylamino)-1,1-bis(ethylthio)-1-propene
  参考文献：
  名称：

  Acid-Promoted Reaction of Trimethylsilylketene Bis(ethylthio)acetal with Imines. Synthesis of γ,γ-Bis(ethylthio)allylamines

  摘要：

  Pestalotiopsis microspora (top right), an endophytic fungus commonly found in tropical plants, was cultured from the lesions in a pandanus leaf (top left). The bioactive ambuic acid (lower right), produced by P. microspora, provides an ideal illustration for the recently developed solid-state NMR FIREMAT technique (see representative spectra lower left), from which the stereochemistry and other structural features may be obtained when single-crystal X-ray results are unavailable. See Grant and co-workers, p 4609.

  DOI：

  10.1021/jo020748v

文献信息

• Acid-Promoted Reaction of Trimethylsilylketene Bis(ethylthio)acetal with Imines. Synthesis of γ,γ-Bis(ethylthio)allylamines
  作者：Shuhei Yahiro、Keisuke Shibata、Takeshi Saito、Tatsuo Okauchi、Toru Minami

  DOI：10.1021/jo020748v

  日期：2003.6.1

  Pestalotiopsis microspora (top right), an endophytic fungus commonly found in tropical plants, was cultured from the lesions in a pandanus leaf (top left). The bioactive ambuic acid (lower right), produced by P. microspora, provides an ideal illustration for the recently developed solid-state NMR FIREMAT technique (see representative spectra lower left), from which the stereochemistry and other structural features may be obtained when single-crystal X-ray results are unavailable. See Grant and co-workers, p 4609.