(η(5)-C5Me5)(CO)2FeP=C(SiMe3)2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: (η(5)-C5Me5)(CO)2FeP=C(SiMe3)2
• 英文别名: (η5-C5Me5)(CO)2FeP=C(SiMe3)2
• 化学式: C₁₉H₃₃FeO₂PSi₂
• 分子量: 436.462
• InChiKey: LPOHXWYMCJAQSH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (η(5)-C5Me5)(CO)2FeP=C(SiMe3)2 、 1-异苯甲腈 以 苯 为溶剂， 以56%的产率得到
  参考文献：
  名称：

  Weber, Lothar; Rühlicke, Annette; Stammler, Hans-Georg, Organometallics, 1993, vol. 12, # 11, p. 4653 - 4656

  摘要：

  DOI：
• 作为产物：
  描述：

  {(bis(trimethylsilyl)methylene)(pentamethylcyclopentadienyl)phosphane}tetracarbonyliron 以 not given 为溶剂， 生成 (η(5)-C5Me5)(CO)2FeP=C(SiMe3)2
  参考文献：
  名称：

  Niecke, E.; Gudat, D.; Leuer, M., Phosphorus and Sulfur and the Related Elements, 1987, vol. 30, p. 467 - 470

  摘要：

  DOI：

文献信息

• Transition Metal Substituted Acyl Phosphanes and Phosphaalkenes. 28.¹ Reactivity of Metallophosphaalkenes (η⁵-C₅Me₅)(CO)₂FePCR¹₂ (R¹ = SiMe₃, NMe₂) toward Methyl and Ethyl Propiolate
  作者：Lothar Weber、Olaf Kaminski、Beate Quasdorff、Annette Rühlicke、Hans-Georg Stammler、Beate Neumann

  DOI：10.1021/om950517x

  日期：1996.1.9

  metallophosphaalkene (η5-C5Me5)(CO)2FePC (SiMe3)2 (1) undergoes reaction with 2 equiv of alkyl propiolates HC⋮CCO2R2 (R2 = Me, Et) to afford the novel bicyclic P-metalloylides η5-C5Me4CH2CHC(CHCHCO2R2)C(CO2R2)OP[C(SiMe3)2]Fe(CO)2 [R2 = Me (8c), Et (8d)]. In contrast to this, metallophosphaalkene (η5-C5Me5)(CO)2FePC(NMe2)2 (2) smoothly adds 3 equiv of the propiolates with formation of the spirobicyclic compounds

  所述metallophosphaalkene（η 5 -C 5我5）（CO）2 FEP C（森达3）2（1与2当量的烷基的丙炔酸酯HC⋮CCO）经历反应2 - [R 2（R 2 =甲基，乙基），得到新的双环P -metalloylidesη 5 -C 5我4 CH 2 CHC（CH CHCO 2 - [R 2）C（CO 2 - [R 2）OP [ C（森达3）2 ]的Fe（CO）2[R 2＝ Me（8c），Et（8d）]。与此相反，metallophosphaalkene（η 5 -C 5我5）（CO）2 FEP C（NME 2）2（2）增加了顺利3当量的丙炔酸酯的与形成螺双环化合物的（η 5 -C 5我5）（CO）FEP [CH C（CO 2 R 2）C（NMe 2）2 C（CO 2 R 2）CH] CH C（CO 2 R 2）CO [R 2 = Me（10c），Et（10d）]。丙炔酸甲酯和等量的治疗2，得到的混合物P
• Weber, Lothar, Phosphorus, Sulfur and Silicon and the Related Elements, 1993, vol. 77, # 1-4, p. 21 - 24
  作者：Weber, Lothar

  DOI：——

  日期：——
• Niecke, Edgar; Metternich, Hans-Juergen; Nieger, Martin, Chemische Berichte, 1993, vol. 126, # 6, p. 1299 - 1310
  作者：Niecke, Edgar、Metternich, Hans-Juergen、Nieger, Martin、Gudat, Dietrich、Wenderoth, Peter、et al.

  DOI：——

  日期：——
• Metallophosphaalkenes—from Exotics to Versatile Building Blocks in Preparative Chemistry
  作者：Lothar Weber

  DOI：10.1002/anie.199602711

  日期：1996.2.16

  AbstractThe chemistry of low‐valent organophosphorus compounds such as phosphaalkenes and phosphaalkynes has undergone rapid development in the last two decades. This development also includes the coordination chemistry of these species, which can act as versatile ligands in metal complexes. Metallophosphaalkenes are compounds in which one or more of the organic substituents on the PC unit is replaced by a transition metal complex fragment. Metallophosphaalkenes have emerged from an existence as laboratory curiosities to become a link between main group and organometallic complex chemistry. The great richness of their chemistry not only mirrors the specific properties of the individual building block, but also shows novel and individual traits. Particular examples are cycloadditions of these electron‐rich heteroalkenes with electron‐deficient alkenes, alkynes, azo, and diazo compounds. These often lead to novel types of reaction and compounds. Metallophosphaalkenes are also important as intermediates in all metal‐assisted cyclooligomerizations of phosphaalkynes.
• Gudat, Dietrich; Niecke, Edgar; Arlf, Atta M., Organometallics, 1986, vol. 5, # 3, p. 593 - 595
  作者：Gudat, Dietrich、Niecke, Edgar、Arlf, Atta M.、Cowley, Alan H.、Quashie, Sapé

  DOI：——

  日期：——