C5H5Co(1.3-C5H8)

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: C5H5Co(1.3-C5H8)
• 化学式: C₁₀H₁₃Co
• 分子量: 192.206
• InChiKey: QLMJAFVKDYOPKX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  C5H5Co(1.3-C5H8) 以 氘代苯 为溶剂， 以>99的产率得到(η4-1,2:3,4-(E-1,3-pentadiene))(η5-cyclopentadienyl)cobalt
  参考文献：
  名称：

  The thermally-induced prototropic isomerization of η4-1,3-, η4-1,4-, η4-1,5-dialkenes complexed to (η5-cyclopentadienyl)cobalt

  摘要：

  This study reports a series of facile, thermally-induced, prototropic isomerizations of eta4-1,4- and eta4-1,5-dienes of (eta5-cyclopentadienyl)cobalt to their corresponding eta4-1,3-complexes. The data indicate the E-isomers to be thermodynamically favored over the Z-isomers. Furthermore, in the case of eta4-hexadiene complexes, the eta4-2,4-EE-isomer is observed to be thermodynamically preferred relative to either the eta4-2,4-E,Z- or eta4-1,3-E-isomers.

  DOI：

  10.1016/0022-328x(93)80363-g
• 作为产物：
  描述：

  (η4-1,2:4,5-(1,4-pentadiene))(η5-cyclopentadienyl)cobalt 在 1,4-二氧六环 作用下， 以 1,4-二氧六环 、 氘代苯 为溶剂， 以79.4%的产率得到(η4-1,2:3,4-(E-1,3-pentadiene))(η5-cyclopentadienyl)cobalt
  参考文献：
  名称：

  The thermally-induced prototropic isomerization of η4-1,3-, η4-1,4-, η4-1,5-dialkenes complexed to (η5-cyclopentadienyl)cobalt

  摘要：

  This study reports a series of facile, thermally-induced, prototropic isomerizations of eta4-1,4- and eta4-1,5-dienes of (eta5-cyclopentadienyl)cobalt to their corresponding eta4-1,3-complexes. The data indicate the E-isomers to be thermodynamically favored over the Z-isomers. Furthermore, in the case of eta4-hexadiene complexes, the eta4-2,4-EE-isomer is observed to be thermodynamically preferred relative to either the eta4-2,4-E,Z- or eta4-1,3-E-isomers.

  DOI：

  10.1016/0022-328x(93)80363-g

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: Org.Verb.1, 1.5.1.1.6.3, page 323 - 340
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: Org.Verb.1, 1.5.1.1.6.1, page 314 - 315
  作者：

  DOI：——

  日期：——
• Cyclopentadienyl metal diene complexes
  申请人：UNION CARBIDE CORP

  公开号：US03159659A1

  公开（公告）日：1964-12-01
• The thermally-induced prototropic isomerization of η4-1,3-, η4-1,4-, η4-1,5-dialkenes complexed to (η5-cyclopentadienyl)cobalt
  作者：Joseph A. King、K. Peter、C. Vollhardt

  DOI：10.1016/0022-328x(93)80363-g

  日期：1993.11

  This study reports a series of facile, thermally-induced, prototropic isomerizations of eta4-1,4- and eta4-1,5-dienes of (eta5-cyclopentadienyl)cobalt to their corresponding eta4-1,3-complexes. The data indicate the E-isomers to be thermodynamically favored over the Z-isomers. Furthermore, in the case of eta4-hexadiene complexes, the eta4-2,4-EE-isomer is observed to be thermodynamically preferred relative to either the eta4-2,4-E,Z- or eta4-1,3-E-isomers.