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十六碳烯-1-醇 | 83808-53-1

中文名称
十六碳烯-1-醇
中文别名
——
英文名称
hexadecen-1-ol
英文别名
hexadecenol;7Z-hexadecenol;1-hexadecenol;(E)-hexadec-1-en-1-ol
十六碳烯-1-醇化学式
CAS
83808-53-1
化学式
C16H32O
mdl
——
分子量
240.429
InChiKey
GWSURTDMLUFMJH-FOCLMDBBSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

物化性质

  • 沸点:
    334.7±15.0 °C(Predicted)
  • 密度:
    0.847±0.06 g/cm3(Predicted)

计算性质

  • 辛醇/水分配系数(LogP):
    7.7
  • 重原子数:
    17
  • 可旋转键数:
    13
  • 环数:
    0.0
  • sp3杂化的碳原子比例:
    0.88
  • 拓扑面积:
    20.2
  • 氢给体数:
    1
  • 氢受体数:
    1

反应信息

  • 作为反应物:
    参考文献:
    名称:
    Azeotropic purification of Z-11-hexadecenal
    摘要:
    本文介绍了通过共沸蒸馏生产基本纯净的Z-11-十六烯醛的方法。将Z-11-十六烯醛、十六烯和十六二烯混合物与二甲基亚砜接触,并将混合物置于共沸蒸馏条件下,可以去除醛中的碳氢杂质。将Z-11-十六烯醛和十六烯醇混合物与C.sub.2-C.sub.4 乙二醇接触,并将混合物置于共沸蒸馏条件下,可以从中回收乙二醇-醛共沸物,从中可以轻松地回收基本纯净的醛。可以按照上述共沸蒸馏步骤依次处理包含Z-11-十六烯醛、十六烯、十六二烯和十六烯醇的混合物,以提供基本纯净的Z-11-十六烯醛。
    公开号:
    US04559111A1
  • 作为产物:
    参考文献:
    名称:
    Attractant termiticidal compounds, compositions and methods of use
    摘要:
    Alpha - fluoro - omega - hydroxy直链碳氢化合物被用于形成吸引性杀白蚁组合物,这些组合物对于对抗白蚁和相关害虫是安全且经济的。
    公开号:
    US04455441A1
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文献信息

  • Use of metal complex compounds as catalysts for oxidation using molecular oxygen or air
    申请人:Wieprecht Torsten
    公开号:US20060019853A1
    公开(公告)日:2006-01-26
    Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge of Y), and L is a ligand of formula (2) wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 9 , R 10 and R 11 are each independently of the others hydrogen; unsubstituted or substituted C 1 -C 18 alkyl or aryl; cyano; halogen; nitro; —COOR 12 or —SO 3 R 12 wherein R 12 is in each case hydrogen, a cation or unsubstituted or substituted C 1 -C 18 alkyl or aryl; —SR 13 , —SO 2 R 13 or —OR 13 wherein R 13 is in each case hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl; —NR 14 R 15 ; —(C 1 -C 6 alkylene)-NR 14 R 15 ; —N (+) R 14 R 15 R 16 ; —(C 1 -C 6 alkylene)-N (+) R 14 R 15 R 16 ; —N(R 13 )—(C 1 -C 6 alkylene)-NR 14 R 15 ; —N[(C 1 -C 6 alkylene)-NR 14 R 15 ] 2 ; —N(R 13 )—(C 1 -C 6 alkylene)-N (+) R 14 R 15 R 16 ; —N[(C 1 -C 6 alkylene)-N (+) R 14 R 15 R 16]2 ; —N(R 13 )—N—R 14 R 15 or —N(R 13 )N″R 14 R 15 R 16 , wherein R 13 is as defined above and R 14 , R 15 and R 16 are each independently of the other(s) hydrogen or unsubstituted or substituted C 1 -C 18 alkyl or aryl, or R 14 and R 15 , together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms. [L n Me m X p ] z Y q (1)
    使用至少一种具有以下式(1)的属配合物化合物作为氧化反应的催化剂,其中Me为,X为配位或桥联基团,n和m分别独立地为1至8之间的整数,p为0至32之间的整数,z为属配合物的电荷,Y为对离子,q=z/(Y的电荷),L为具有以下式(2)的配体,其中R1、R2、R3、R4、R5、R6、R7、R8、R9、R10和R11各自独立地为氢;未取代或取代的C1-C18烷基或芳基;基;卤素;硝基;—COOR12或—SO3R12,其中R12在每种情况下为氢、阳离子或未取代或取代的C1-C18烷基或芳基;—SR13、—SO2R13或—OR13,其中R13在每种情况下为氢或未取代或取代的C1-C18烷基或芳基;—NR14R15;—(C1-C6烷基)-NR14R15;—N(+)R14R15R16;—(C1-C6烷基)-N(+)R14R15R16;—N(R13)—(C1-C6烷基)-NR14R15;—N[(C1-C6烷基)-NR14R15]2;—N(R13)—(C1-C6烷基)-N(+)R14R15R16;—N[(C1-C6烷基)-N(+)R14R15R16]2;—N(R13)—N—R14R15或—N(R13)N″R14R15R16,其中R13如上定义,R14、R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基,或R14和R15与连接它们的氮原子一起形成未取代或取代的5、6或7成员环,该环可能含有进一步的杂原子。[LnMemXp]zYq(1)
  • [EN] SYNTHESIS OF STRAIGHT-CHAIN LEPIDOPTERAN PHEROMONES THROUGH ONE- OR TWO- CARBON HOMOLOGATION OF FATTY ALKENES<br/>[FR] SYNTHÈSE DE PHÉROMONES DE LÉPIDOPTÈRES À CHAÎNE DROITE PAR HOMOLOGATION D'UN OU DEUX ATOMES DE CARBONE D'ALCÈNES GRAS
    申请人:PROVIVI INC
    公开号:WO2020018581A1
    公开(公告)日:2020-01-23
    Methods for the preparation of alkenes including insect pheromones are described. The methods include homologation reactions employing reagents such as 1,3-diesters, epoxides, cyanoacetates, and cyanide salts for elongation of starting materials and intermediates by one or two carbon atoms. The alkenes include insect pheromones useful in a number of agricultural applications.
    描述了制备烯烃(包括昆虫信息素)的方法。这些方法包括使用1,3-二酯、环氧化物氰乙酸盐和化物等试剂进行同系反应,通过增加一到两个碳原子来延长起始物质和中间体。这些烯烃包括在许多农业应用中有用的昆虫信息素。
  • METHODS AND COMPOSITIONS FOR PRODUCING HYDROCARBONS
    申请人:SCHIRMER ANDREAS
    公开号:US20100221798A1
    公开(公告)日:2010-09-02
    Compositions and methods for producing hydrocarbons such as aldehydes, alkanes, and alkenes are described herein. Certain hydrocarbons can be used in biofuels.
    本文描述了用于生产醛、烷烃和烯烃等烃类化合物的组合物和方法。某些烃类化合物可以用于生物燃料。
  • PRODUCTION OF FATTY OLEFIN DERIVATIVES VIA OLEFIN METATHESIS
    申请人:PROVIVI, INC.
    公开号:US20170137365A1
    公开(公告)日:2017-05-18
    In one aspect, the invention provides a method for synthesizing a fatty olefin derivative. The method includes: a) contacting an olefin according to Formula I with a metathesis reaction partner according to Formula IIb in the presence of a metathesis catalyst under conditions sufficient to form a metathesis product according to Formula IIIb: and b) converting the metathesis product to the fatty olefin derivative. Each R 1 is independently selected from H, C 1-18 alkyl, and C 2-18 alkenyl; R 2b is C 1-8 alkyl; subscript y is an integer ranging from 0 to 17; and subscript z is an integer ranging from 0 to 17. In certain embodiments, the metathesis catalyst is a tungsten catalyst or a molybdenum catalyst. In various embodiments, the fatty olefin derivative is a pheromone. Pheromone compositions and methods of using them are also described.
    在一个方面,该发明提供了一种合成脂肪烯衍生物的方法。该方法包括:a)在存在一种烯烃催化剂的条件下,将符合式I的烯烃与符合式IIb的交换反应伙伴接触,以形成符合式IIIb的交换产物;并b)将交换产物转化为脂肪烯衍生物。每个R1独立地选择自H、C1-18烷基和C2-18烯基;R2为C1-8烷基;下标y为0至17之间的整数;下标z为0至17之间的整数。在某些实施方式中,交换催化剂为催化剂或催化剂。在各种实施方式中,脂肪烯衍生物为信息素。还描述了信息素组合物及其使用方法。
  • [EN] SYNTHESIS OF OLEFINIC ALCOHOLS VIA ENZYMATIC TERMINAL HYDROXYLATION<br/>[FR] SYNTHÈSE D'ALCOOLS OLÉFINIQUES PAR L'INTERMÉDIAIRE DE L'HYDROXYLATION TERMINALE ENZYMATIQUE
    申请人:PROVIVI INC
    公开号:WO2015176020A1
    公开(公告)日:2015-11-19
    In certain aspects, the present invention provides methods for producing terminally hydroxylated alkenes and alkynes by contacting an unsaturated or saturated hydrocarbon substrate with a hydroxylase enzyme. Exemplary terminal hydroxylases useful for carrying out the methods of the invention exhibit strong selectivity towards one terminal carbon of a hydrocarbon substrate and include, but are not limited to, non-heme diiron alkane monooxygenases, cytochromes P450 (e.g., cytochromes P450 of the CYP52 and CYP153 family), as well as long chain alkane hydroxylases. In some embodiments, the terminally hydroxylated alkene or alkyne is further converted to a terminal alkenal. In certain embodiments, terminally hydroxylated alkenes and alkynes are useful as insect pheromones which modify insect behavior. In other embodiments, terminally hydroxylated alkenes and alkynes are useful intermediates for producing pheromones via acetylation or oxidation of the alcohol moiety.
    在某些方面,本发明提供了一种通过将不饱和或饱和碳氢基质与羟化酶酶接触来生产末端羟基化烯烃和炔烃的方法。用于执行本发明方法的示例末端羟化酶对碳氢基质的一个末端碳具有很强的选择性,包括但不限于非血红素双脂烷单氧酶、细胞色素P450(例如,CYP52和CYP153家族的细胞色素P450)以及长链烷烃羟化酶。在某些实施例中,末端羟基化的烯烃或炔烃进一步转化为末端烯醛。在某些实施例中,末端羟基化的烯烃和炔烃可用作改变昆虫行为的昆虫信息素。在其他实施例中,末端羟基化的烯烃和炔烃是通过乙酰化或氧化醇基团来生产信息素的有用中间体。
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